Hydrogen as a raw material finds its main use and application on the Polish market in the chemical industry. Its potential applications for the production of energy in fuel cell systems or as a fuel for automobiles are widely analyzed and commented upon ever more frequently. At present, hydrogen is produced worldwide mainly from natural gas, using the SMR technology or via the electrolysis of water. Countries with high levels of coal resources are exceptional in that respect, as there the production of hydrogen is increasingly based on gasification processes. China is such an example. There some 68% of hydrogen is generated from coal. The paper discusses the economic efficiency of hydrogen production technologies employing lignite gasification, comparing it with steam reforming of natural gas technology (SMR). In present Polish conditions, this technology seems to be the most probable alternative for natural gas substitution.

For the purpose of evaluating the economic efficiency, a model has been developed, in which a sensitivity analysis has been carried out. An example of the technological process of energy-chemical processing of lignite has been presented, based on the gasification process rooted in disperse systems, characteristics of the fuel has been discussed, as well as carbon dioxide emission issues. Subsequently, the assumed methodology of economic assessment has been described in detail, together with its key assumptions. Successively, based on the method of discounted cash flows, the unit of hydrogen generation has been determined, which was followed by a detailed sensitivity analysis, taking the main risk factors connected with lignite/coal and natural gas price relations, as well as the price of carbon credits (allowances for emission of CO2) into account.

Hydrogen-based power engineering has great potential for upgrading present and future structures of heat and electricity generation and for decarbonizing industrial technologies. The production of hydrogen and its optimal utilization in the economy and transport for the achievement of ecological and economic goals requires a wide discussion of many technological and operational – related issues as well as intensive scientific research. The introductory section of the paper indicates the main functions of hydrogen in the decarbonization of power energy generation and industrial processes, and discusses selected assumptions and conditions for the implementation of development scenarios outlined by the Hydrogen Council, 2017 and IEA, 2019. The first scenario assumes an 18% share of hydrogen in final energy consumption in 2050 and the elimination 6 Gt of carbon dioxide emissions per year. The second document was prepared in connection with the G20 summit in Japan. It presents the current state of hydrogen technology development and outlines the scenario of their development and significance, in particular until 2030. The second part of the paper presents a description of main hybrid Power-to-Power, Power-to-Gas and Power-to-Liquid technological structures with the electrolytic production of hydrogen from renewable sources. General technological diagrams of the use of water and carbon dioxide coelectrolysis in the production of fuels using F-T synthesis and the methanol production scheme are presented. Methods of integration of renewable energy with electrolytic hydrogen production technologies are indicated, and reliability indicators used in the selection of the principal modules of hybrid systems are discussed. A more detailed description is presented of the optimal method of obtaining a direct coupling of photovoltaic (PV) panels with electrolyzers.

The offshore Oil & Gas Industry is very important to the European Union economy. Therefore it must be properly monitored and protected, and legal regulations must be in place. Directive 2013/30/EU implemented on July 18, 2018 obliged EU Member States as well as operators and owners of oil and gas related activities in sea areas to implement solutions reducing the risk of major accidents, minor accidents and dangerous situations.

The purpose of the article is to identify all the possible hazards that may occur during oil and gas operations in marine areas and attempt to assess the risk along with providing effective responses in the event of its occurrence by preparing appropriate plans for responding to the situation. For the completion of the main purpose of the work the provisions of Directive 2013/30/EU of the European Parliament and of the Council of 12 June 2013 on safety of offshore oil and gas operations were presented and analyzed using the Hazard Identification method, the analysis of available reports prepared by the European Commission, classification bodies and own experience obtained while working in the offshore industry during searching, drilling and oil and gas production located under the seabed at the Polish Economic Executive Zone. The study presents numerous analyses and comments, which were presented in the form of graphs and tables, based on international reports and own experience gained while working in an offshore company.

The paper analyzed the natural gas sector in Ukraine for the period 2000 to 2018. This sector was affected by external factors, such as the crisis which began in late 2008/2009, as well as internal factors, including the situation in Ukraine after 2013 (the Annexation of Crimea). A comparative analysis was also conducted of the natural gas sector in European Union countries and Ukraine – compared the specificity of natural gas consumption in 2018. The analysis (I) examined the demand for natural gas in Ukraine between 2000 and 2018; (II) described changes in sources to cover Ukraine’s gas needs with a particular emphasis on its own production; (III) pointed to the fundamental changes that have occurred in the natural gas supply routes to the Ukrainian sector in recent years; (IV) stressed the growing role of own production in balancing Ukraine’s gas needs; (V) described the role of Ukraine as a transit country for Russian gas to be delivered to EU countries (in recent years, the volume of natural gas transmitted via the Ukrainian transmission system has been around 90 bcm annually); and (VI) looked at the structure of natural gas consumption in the Ukrainian gas sector and how it has changed in recent years. Unlike EU countries, the growing role of own production in balancing Ukraine’s natural gas needs was emphasized, which is consistent with the strategy of the Ukrainian government. Also, attention was drawn to the threats that may significantly reduce the role of Ukraine as an important transit country. The paper also puts forward the most important parameters concerning the underground natural gas storage facilities in Ukraine which is one of the largest in Europe.

The condition of the Polish energy sector does not inspire any trust of its customers. Outdated machinery and the lack of investment in new technologies make it necessary to take action to ensure the stability and continuity of electricity supplies to the end-user. In Poland, the industrial power sector is based on the use of coal and despite the Government’s announcements to resign from this raw material, more and more power investments are being made to generate energy from coal (Ostrołęka power plant). The solution which compensates for the current state of the Polish power industry is the development of distributed generation. The article presents a description of dispersed sources, power market, its organization and problems arising from its implementation. Distributed energy sources in the form of micro installations, energy clusters and virtual power plants have been described and characterized as well. It also assesses the impact of power market introduction on the development of distributed energy sources. The impact of the power market on the development of distributed sources is very hard to predict and determine. The functioning and further development of the energy sector, including the capacity market, strongly depends on the laws, regulations, as well as the economic and political situation in Poland and Europe. The social factor will also play an important role as the introduction of the capacity market will burden the financial side of each energy consumer. On the basis of the data presented on particular sources and distributed systems, one can only make predictions related to the possible effects of introducing the capacity market for the development of distributed sources.

The annexation of Crimea and military operations that began in eastern Ukraine in April 2014 were the cause of the growing threat to Ukraine’s energy security. In terms of coal supplies, Donbass is of key importance for the country’s economy. Despite military operations on the east, illegal trade with the occupied territories was flourishing. This situation led to an increase in dissatisfaction amid certain social strata, as well as among volunteer battalions participants who took part in the military operations in Donbass and were the initiators of the Donbass blockade. The main purpose of the study to analyse the specific of the development of coal industry in Ukraine and the main reasons of the blockade of Donbass and its consequences.

The aim of this study is to examine the importance of the decision in Engelhart CTP (US) LLC v Lloyd’s Syndicate 1221 with regard to the insurance of economic losses and non-existent goods in the context of all-risks cover. It also strives to analyse to what extent the principles of construction described in this decision are applicable to the interpretation of all risks cover in marine insurance disputes subject to Polish law. Assureds and beneficiaries of cargo policies are defrauded into taking up false documents for non-existent goods yet Polish law fails to address the questions which arise in such situations. It is thus important not only to investigate and evaluate the answers provided by English law but also to explore if and how Polish law may employ them. It follows from this study that Engelhart may be used in construction of all-risks policies subject to Polish law in most scenarios.

In this study the current legal and market conditions of waste management in Poland are analyzed. The main legal basis for changes in the national municipal waste management system and their impact on the market situation in the last few years have been determined. Additionally, the important function of the selective collection and the key role of the separation of raw material fractions in waste sorting plants constituting the basis for the operation of Regional Municipal Waste Processing (RMWP) plants was underlined. Furthermore, the possibilities of developing electricity production technology in low and medium power modules using waste gasification techniques were emphasized. The stream of plastic mixture from municipal waste sorting was identified as problematic in the context of effective material recovery. Tests were conducted on the morphology of this waste stream from two sorting plants. In line with the literature data and as part of the analytical work, the properties of the plastic waste stream designated for recycling and the energy properties of the post-recycling plastic mixture were estimated. Tests results showed that the calorific value of this mixture reached 31.8 MJ/kg, whereas, ash and chlorine content equaled 2.7% and 1.1% of dry mass, respectively. These parameters indicate that the mixture as a high-calorific fuel component may be a valuable addition to refuse-derived fuel (RDF) produced from the over-sieve fraction of municipal waste. Concurrently, as a result of the development of waste gasification technologies with a high share of electricity production in low-medium power range plants, it is possible to integrate them with plastic recycling and RMWP plants in the Polish national waste management system.

The problem of the migration of metal ions in the environment remains a current problem in light of the quality of obtained crops. The necessity of more and more frequent use of alternative sources of biogens in the form of waste substances, poses a threat of loading significant amounts of metals into the soil – including heavy metals harmful to human health and life. The article discusses a significant problem, namely the comparison of the results of the environmental impact of waste, obtained on the basis of legally authorized leaching tests (three-stage leaching test according to PN-EN 12457:2006), with results obtained from sequential chemical extraction (performed in 4-step chemical extraction developed and recommended in European Union countries by Communities Bureau of References – BCR). The study covered an investigation of industry fly ash from the combustion of lignite, in which Cu, Zn, Cd, Ni, Pb, Cr, Na, K, Li concentrations and loads were calculated. A mobility of analyzed elements was established on this basis. From heavy metals, the highest values in fraction I were noted for nickel and copper and zinc as well as nickel were noted for fraction IV . Peaking values of electrolytic conductivity in eluates was created by high concentrations of macroelements (Na and K). These tests confirm that the leaching tests used for their application in the natural environment indicate such concentrations at the highest levels that can be obtained at the first or second stage of sequential chemical extraction, and thus their proper full environmental impact is not known.

In the world-class Cu-Ag deposits of the Legnica-Głogów Copper District (LGCD), constant bulk density values are adopted to estimate the ore and metal resources within them based on the results of previous studies of the LGCD deposits carried out at the stage of their exploration and documentation: 2.6 Mg/m3 for the carbonate series, 2.5 Mg/m3 for the shale series, and 2.3 Mg/m3 for the sandstone series. The main purpose of research was to analyze the range of possible differences at local scale of observation between constant values of bulk densities (hereinafter referred to as reference values) assigned during deposit documentation to the main lithological units and bulk densities of these units determined based on the results of experimental sampling of individual lithological units within the exploited copper and silver deposits (Lubin, Polkowice-Sieroszowice and Rudna). In general, when it comes to Cu-Ag LGCD deposits (or their large parts), the relative diversity of estimates of average bulk densities of ores based on the results of experimental sampling (more than 1,600 samples from different individual lithological units were collected at 500 sampling points in mining excavations) and reference values is low (with a median not exceeding 3%). The results of studies indicate, however, that the application of reference bulk densities at the local observation scale may result in significant underestimation (up to nearly 20%) or overestimation (up to 11%) of real bulk densities of the main lithological units. This may have a noticeable impact on the correct estimation of ore and metal resources in small parts of deposits and, as a consequence, hinder the reconciliation of the planned and actual ore mining production.

The occurrence of gas confined in shales allows us to consider it as a component of the host rock. During drilling wells, the gas is released into the drilling fluid from finely ground gas-bearing rock particles. The amount of gas released can be determined on the basis of mud-gas logging; in addition, it is possible to determine the gas-content in shales expressed by the volume of gas released per mass unit of rock [m3/ton]. The gas content in the Ordovician and Silurian shales (Sasin formation and Jantar member respectively) in two selected wells in northern Poland was determined using this method. It has been found that clearly distinguishable, highly gas-bearing sections, which are separated by very poorly gas-bearing ones, can be determined in the well log. The increased gas content in shales can be observed in zones generally enriched in TOC. No direct correlation between TOC and gas-bearing capacity was found however, but the structure of TOC variability and the gas-bearing capacity described using variograms is identical. Correlations of the distinguished gas-bearing layers in the wells under consideration suggest a multi-lens or multi-layered reservoir model. The lack of natural boundaries in the shale gas reservoir means that they must be determined arbitrarily based on the assumed marginal gas-bearing capacity. In the case of several gas-bearing zones, numerous variants of interpretation are possible. In any case the low, best and high estimated resources may be evaluated, assigned to each borehole in the area with radii equal to the range of variogram of gas content in horizontal part of the well.

There are a huge number of objects constituting a storage place of coal mining waste in the coal basins in Poland and around the world. The article is a continuation of the study on the possibilities of using raw materials deposited on the coal mining waste dumping grounds on the example of the Przezchlebie dumping ground. The possibility of coal recovery from mining waste located on the dumping ground was analyzed. Tests on the quality parameters of waste were carried out, i.e. moisture and ash content, as well as the calorific value of raw waste. The relatively high calorific value and low ash content in the waste served as the basis for further tests related to the separation of coal. Tests on the mining waste enrichment using the complex based on the K-102 Komag pulse separator were carried out. As a result of coal separation, 7.66% of concentrate was obtained (in relation to feed) with the calorific value of 26.16 MJ/kg and ash content of 19.96%. Apart from mining waste, power plant waste (fly ash) can also be found on the dumping ground. They were subjected to tests for the possibility of using them in the production of construction materials, especially concrete and cement. Fly ash from the Przezchlebie dumping ground was classified as silica ash and it was found that it meets the requirements of Polish standard, except for the fineness of 42%. The separation of coal will eliminate the fire hazard on the dumping ground. A possible scenario of managing waste material on a dumping ground, which can be implemented in similar facilities, has been presented.

The article analyzes the present state of the phosphate raw material base to meet Ukrainian chemical enterprises’ needs. In Ukraine, a number of complex apatite and phosphorite deposits have been explored. Their exploitation can lead to a complete supply of Ukrainian chemical enterprises with raw materials and can partly reduce the amount of expensive imported phosphate mineral fertilizers. At present, the following deposits, where apatite is connected with other useful components, are prepared for exploitation: Stremyhorod, Fedorivka, Novopoltavka, Kropyvna and others. The advantage of the development of these deposits is the possibility to extract apatite along with the production of rare earth concentrates, ilmenite, titanomagnetite, as well as feldspars, olivine, pyroxenes, mica and others which will significantly increase the profitability of the deposits development.

The alternative to apatite-containing deposits in Ukraine can be sedimentary deposits of nodule, granular and mixed type phosphorites. Phosphorite deposits can be used mainly for the production of phosphorite and limestone flour. Considerable resources of granular phosphorites have been discovered in Volyn-Podillia and Dnieper-Donetsk which are considered to have a various agricultural effect. They are environmentally friendly ores without impurity which prevents plants from cesium, strontium and reduces nitrates in the soil. Arranging the exploration of phosphorite ores in certain parts of Volyn-Podillia basin and Dnieper-Donets Rift is recommended.

The new boreholes drilled between 2009 and 2012 enabled a detailed exploration of the profile of the Kraków sandstone series in the Dąb area between the “Sobieski” and “Janina” mining plants, USCB (Upper Silesian Coal Basin). The core from the No. 111. bituminous coal seam was selected for further analysis. 30 intervals corresponding to the defined lithotypes were separated in the seam with a thickness of 116.8 cm. The thickness of lithotypes ranges from 10 mm to 89 mm. A microprofile of the examined seam was made using the modified method of determining microlithotypes. A quantitative determination of the maceral composition was performed for each interval corresponding to the separated lithotypes. This allowed petrographic and facies characteristics of the seam to be determined. Its lower part is dominated by lithotypes with a large share of bright coal – vitrain coal. This section of the profile was formed under conditions of a strongly flooded wet forest swamp. In the upper section of the seam, a higher macroscopic share of dull coal – durain was observed. The microscopic analysis has shown that the conditions dominant during the formation of this section were typical for swamp forest peats. New technologies also require expanding knowledge about the structure of coal seams. This is only possible with a detailed profiling of the coal seam on a macro scale combined with micro-profiling and a detailed petrographic description of the isolated lithotypes. This methodology is also useful in the facies analysis of bituminous coal seams.

The geochemistry of sedimentary rocks is increasingly being used in palaeoenvironmental studies, in the identification of marine versus continental stratigraphy and in chemostratigraphic correlation. The selection of an appropriate research methodology, particularly in terms of sample digestion, can have a significant impact on the accuracy of the results obtained. Depending on the type of rock being studied and the aim of the analysis, a suitable mixture of acids should be used. The most commonly used sample digestion methods are based on a mixture of four acids (multi-acid), aqua regia and inverse aqua regia. As opposed to multi-acid whole-rock digestion, the use of aqua regia and inverse aqua regia result in only the partial digestion of sedimentary rocks. Geochemical analyses using these two different methods were carried out on Carboniferous sedimentary rocks from the Lublin Coal Basin from Poland.The elemental concentrations obtained showed essentially different results for some of the elements. A comparison of the elemental concentrations allowed the distinction of three groups of elements:

 - those that showed small differences between the results from the preparation methods (Co, Mn, Bi, Cu, Zn and Fe),

- those where the elemental concentrations were 20–50% lower using aqua regia digestion (i.e. Ni, P, Pb, Mg, Cd, Th, Mo, Sr),

 - elemental concentrations that were significantly lower (by up to 80%) following aqua regia digestion (U, Cr, Ba, Na, V, Al, Rb, K, Zr).

Among the elements that compose steel slags and blast furnace slags, metallic precipitates occur alongside the dominant glass and crystalline phases. Their main component is metallic iron, the content of which varies from about 90% to 99% in steel slags, while in blast furnace slags the presence of precipitates was identified with the proportion of metallic iron amounting to 100%. During observations using scanning electron microscopy and X-ray spectral microanalysis it has been found that the form of occurrence of metallic precipitates is varied. There were fine drops of metal among them, surrounded by glass, larger, single precipitates in a regular, spherical shape, and metallic aggregates filling the open spaces between the crystalline phases. Tests carried out for: slags resulting from the open-hearth process, slags that are a by-product of smelting in electric arc furnaces, blast furnace slags and waste resulting from the production of ductile cast iron showed that depending on the type of slag, the proportion and form of metallic precipitates is variable and the amount of Fe in the precipitates is also varied. Research shows that in terms of quality, steel and blast furnace slag can be a potential source of iron recovery. However, further quantitative analyses are required regarding the percentage of precipitates in the composition of slags in order to determine the viability of iron recovery. This paper is the first part of a series of publications aimed at understanding the functional properties of steel and blast furnace slags in the aspect of their destructive impact on the components of devices involved in the process of their processing, which is a significant operational problem.

This article presents a concept method which aids the forecasting of the reclamation cost in post- rock mining areas. The method may also prove useful in estimating the investment profitability of a mining operation at its planning stage as well as managing a potential Reserve Fund to cover future activities, such as land reclamation. The development of the method consisted in defining a set of basic/typical land reclamation directions and the typical structure of reclamation operations/works, which are based on “statistically stable” values. The estimations included the distribution of the probable cost of these works with respect to the reclamation direction and were calculated on the basis of the analyzed current price lists and historical land reclamation projects. The article proposes a method for estimating the cost structure of multi-directional projects by combining the basic directions. The changeability and predictability of various land reclamation solutions was analyzed in terms of fuzzy logic. A price list was developed, which included unit costs for separate types of reclamation works, independent of their type and scale. The assumed optimal measure involved comparing the cost of individual types of operations to the surface of the reclamation area. As an example, the method was also applied to hypothetical data from a clastic rock mine with a surface of 20 ha, and for the forest, agricultural and forest-agricultural reclamation directions. The forest-agricultural reclamation directions was presented in the proportions of 0.3:0.7.

The inevitability and successive implementation of the elements of the European Union (EU) energy policy and the freedom of achieving the goals left in this regard for the member states should translate into actions taking the specificity of local markets into account, in order to carry out liberalization processes in a harmonious manner. In 2016, the European Commission published a package of guidance documents “Clean Energy for All Europeans” in the perspective of 2030, also known as the Winter Package. The recommendations contained in some of the documents assume the continuation of integration of markets in the national and regional dimension, setting ambitious targets in the field of decarbonization, the increase of energy efficiency and the increase of Renewable Energy Sources (RES) share in the energy balance of EU countries. The short time to carry out a thorough reconstruction of the energy-generating sector forces to seek solutions that are in line with the European Community recommendations and, at the same time, do not constitute an excessive burden for the national economy and legal order. One of the activities is to use the potential of micro-networks of local communities striving for energy independence based on their own energy sources and to create regulations enabling the neighborly exchange of energy. This mechanism works in the form of pilot projects in many locations around the world (Sonnen Group; Power Ledger). The paper presents the concept of functional and analytical assumptions for an exemplary structure of neighboring prosumers along with the presentation of simulation results based on real generation and consumption profiles and the presentation of investment profitability indicators for the proposed functional model.

Ensuring the security of power generation systems is a pillar of the proper functioning of each state. Energy security is fundamental to ensure both economic growth and social welfare. As energy storage has not developed in an efficient extent, covering the current and prospective power demand is a major challenge for transmission system operators. Moreover, the activities that are to be taken should be technically and economically justified and need to meet the requirements of environmental protection. Cooperation between neighboring countries in the field of electricity exchange is among the activities undertaken to ensure the safety of the power generation systems. The integration of electricity markets is one of the key challenges of the European Union’s energy policy. The European Commission issued a directive on interconnection, according to which the capacity of interconnections should total 10% of installed capacity until 2020 (and 15% until 2030) in each Member State. The main objective of this study is to assess the changes in electricity imports and exports in 2003–2018 and to investigate the current level of cross-border exchanges between Poland and the neighboring countries. This paper also answers the question of whether Poland will fulfil the obligations set by the European Commission. In addition, the paper presents the risks and the challenges related to fulfilling the mentioned commitments. The results of the study indicate that the development and modernization of network infrastructure in the field of cross-border exchange are necessary because, in the context of the forecasted increase in electricity demand, Polish generation units will not be able to meet the demand.

Exergy analysis is a powerful thermodynamic tool and it helps in computing the actual output of a system. It helps the researchers to optimize the roughened solar air heater design to compensate the present and also the future needs. In this study, investigation on exergetic performance evaluation of a solar air heater with W-shaped roughened absorber surface analytically by employing mathematical model and the results obtained are compared with smooth plate solar air heater under same operating conditions. The exergetic efficiency curves has been plotted as a function of different values of Reynolds number and temperature rise parameter for different roughness parameters. The maximum augmentation in the exergetic efficiency of the solar air heater with W-shaped roughened surface as compared to solar air heater with smooth surface has been obtained as 51% corresponding to the relative roughness height of 0.03375 and the rib angle of attack about 60◦. Based on the exergetic efficiency the suitable design parameters of solar air heater with W-shaped roughened are determined.