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Abstract

In this article, there were presented results of research on influence of reclamation process on the ecological quality of reclaim sand with furan resin used in nonferrous foundry. The quality of reclaimed sand is mainly define by two group of chemical substances from elution of reclaimed sand: Dissolves Organic Carbon (DOC) and Total Dissolves Solids (TDS). Reclaimed sand used in test was prepared in experimental thermal reclaimer and mechanical vibration reclaimer REGMAS installed in Faculty of Foundry Engineering at University of Science and Technology in Krakow. The reference point is molding sand shaking out and crumble in jaw crusher. Test of elution was made in acreditation laboratory in Center For Research and Environmental Control in Katowice up to the standard with Dissolves Organic Carbon (DOC) - PN-EN 1484:1999; Total Dissolves Solids (TDS) - PN-EN 15216:2010. The standard for elution test is PN-EN 12457- 4:2006. Except that we were made loss of ignition test, to check how many resin was rest on sand grains.

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Authors and Affiliations

M. Dereń
M. Łucarz
A. Roczniak
A. Kmita
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Abstract

The effects of silica additive (Poraver) on selected properties of BioCo3 binder in form of an aqueous poly(sodium acrylate) and dextrin (PAANa/D) binder were determined. Based on the results of the thermoanalytical studies (TG-DTG, FTIR, Py-GC/MS), it was found that the silica additive results in the increase of the thermostability of the BioCo3 binder and its contribution does not affect the increase in the level of emissions of organic destruction products. Compounds from group of aromatic hydrocarbons are only generated in the third set temperature range (420-838°C). The addition of silicate into the moulding sand with BioCo3 causes also the formation of a hydrogen bonds network with its share in the microwave radiation field and they are mainly responsible for maintaining the cross-linked structures in the mineral matrix system. As a consequence, the microwave curing process in the presence of Poraver leads to improved strength properties of the moulding sand (���� �� ). The addition of Poraver's silica to moulding sand did not alter the permeability of the moulding sand samples, and consequently reduced their friability. Microstructure investigations (SEM) of microwave-cured samples have confirmed that heterogeneous sand grains are bonded to one another through a binder film (bridges).

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Authors and Affiliations

S. Cukrowicz
S. Żymankowska-Kumon
B. Grabowska
A. Bobrowski
D. Drożyński
K. Kaczmarska

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