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Abstract

The suspension of copper droplets in the slag is considered. The copper/slug suspension is delivered as the product from the direct-toblister

process which is applied in the KGHM – Polska Miedź (Polish Copper) S.A. factory. The droplets / slag suspension was treated by

a special set of reagents (patented by the authors) to improve the coagulation process. On the other hand, the observations are made to

estimate if the melting / reduction process in the furnace is sufficiently effective to avoid a remaining of carbon in the copper droplets.

The coagulation process was carried out in the crucible (laboratory scale). However, conditions imposed to the coagulation / solidification

process in the laboratory scale were to some extent similar to those applied usually in the industry when the suspension is subjected to the

analogous treatment in the electric arc-furnace. Some suggestions are formulated how to improve the industrial direct-to-blister process.

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Authors and Affiliations

W. Wołczyński
A.W. Bydałek
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Abstract

The scope of work included the launch of the process of refining slag suspension in a gas oven using a variety of technological additives.

After the refining process (in the context of copper recovery), an assessment of the effect of selected reagents at the level of the slag

refining suspension (in terms of copper recovery). Method sieve separated from the slag waste fraction of metallic, iron - silicate and

powdery waste. Comparison of these photographs macroscopic allowed us to evaluate the most advantageous method of separating

metallic fraction from the slag. After applying the sample A (with KF2 + NaCl) we note that in some parts of the slag are still large

amounts of metallic fraction. The fraction of slag in a large majority of the elements has the same size of 1 mm, and a larger portion of the

slag, the size of which is from 2 to 6 mm. Definitely the best way is to remove the copper by means of the component B (with NaCl ) and

D (with KF2

). However, as a result of removing the copper by means of component C (with CaO) were also obtained a relatively large

number of tiny droplets of copper, which was problematic during segregation. In both cases we were able to separate the two fractions in a

fast and simple manner.

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Authors and Affiliations

P. Migas
S. Biernat
P. Kwapisiński
W. Wołczyński
A.W. Bydałek
A. Bydałek
K. Jasińska

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