In this study, BaFe12-2xCoxTixO19 (X : 0 to 2.0, 0.2) powders were synthesized by sol-gel process. TG-DTA, XRD, SEM, VSM, and Network analyzer were measured in order to influence easy magnetization axis change on the wave absorption frequency range change. The easy magnetization axis change of the annealed powder at 900°C and 1200°C was confirmed by the coercive force decreased 4,800 and 3,870 Oe to 260 and 269 Oe, respectively, at the substitution ratio of 0.8 and 1.0. And it was confirmed that the change of the easy magnetization axis affected the change of the wave absorption frequency. The wave absorption frequency of substituted Barium Ferrite was less than 10 GHz range after the easy magnetization axis of Barium ferrite changed to a-b plan direction. It was confirmed the BaFe12-2xCoxTixO19(x = 0.8 to 1.6) was synthesized by the sol-gel process and it was annealed at 900°C and 1200°C, which could be used as a wave absorber in the X-band region of 10 GHz less.