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Abstract

Secondary or multiple remelted alloys are common materials used in foundries. For secondary (recycled) Al-Si-Cu alloys, the major problem is the increased iron presence. Iron is the most common impurity and with presence of other elements in alloy creates the intermetallic compounds, which may negatively affect the structure. The paper deals with effect of multiple remelting on the microstructure of the AlS9iCu3 alloy with increased iron content to about 1.4 wt. %. The evaluation of the microstructure is focused on the morphology of iron-base intermetallic phases in caste state, after the heat treatment (T5) and after natural aging. The occurrence of the sludge phases was also observed. From the obtained results can be concluded that the multiple remelting leads to change of chemical composition, changes in the final microstructure and also increases sludge phases formation. The use of heat treatment T5 led to a positive change of microstructure, while the effect of natural aging is beneficial only to the 3rd remelting.

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Authors and Affiliations

M. Matejka
D. Bolibruchová
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Abstract

The paper deals with problems related to application of aluminum-silicon alloys for combustion engine cylinder liners

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Authors and Affiliations

A. Trytek
M. Tupaj
M. Mróz
A.W. Orłowicz
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Abstract

The paper presents results of a study concerning an AlSi7Mg alloy and the effect of subjecting the liquid metal to four different processes: conventional refining with hexachloroethane; the same refining followed by modification with titanium, boron, and sodium; refining by purging with argon carried out in parallel with modification with titanium and boron salts and strontium; and parallel refining with argon and modification with titanium, boron, and sodium salts. The effect of these four processes on compactness of the material, parameters of microstructure, and fatigue strength of AlSi7Mg alloy after heat treatment. It has been found that the highest compactness (the lowest porosity ratio value) and the most favorable values of the examined parameters of microstructure were demonstrated by the alloy obtained with the use of the process including parallel purging with argon and modification with salts of titanium, boron, and sodium. It has been found that in the fatigue cracking process observed in all the four variants of the liquid metal treatment, the crucial role in initiation of fatigue cracks was played by porosity. Application of the process consisting in refining by purging with argon parallel to modification with Ti, B, and Na salts allowed to refine the microstructure and reduce significantly porosity of the alloy extending thus the time of initiation and propagation of fatigue cracks. The ultimate effect consisted in a distinct increase of the fatigue limit value.

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Authors and Affiliations

M. Tupaj
ORCID: ORCID
A.W. Orłowicz
ORCID: ORCID
A. Trytek
ORCID: ORCID
Marek Mróz
ORCID: ORCID
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Abstract

Plasma oxidation, similarly to anodic oxidation (anodizing), are classified as electrochemical surface treatment of metals such as Al, Mg, Ti and their alloys. This type of treatment is used to make surface of castings, plastically processed products, shaped with incremental methods to suitable for certain requirements. The most important role of the micro plasma coating is to protect the metal surface against corrosion. It is well known that coating of aluminium alloys containing silicon using anodic oxidation causes significant difficulties. They are linked to the eutectic nature of this alloy and result in a lack of coverage in silicon-related areas. The coating structure in these areas is discontinuous. In order to eliminate this phenomenon, it is required to apply oxidation coatings using the PEO (Plasma Electrolytic Oxidation) method. It allows a consistent, crystalline coating to be formed. This study presents the mechanical properties of the coatings applied to Al-Si alloy using the PEO method. As part of the testing, the coating thickness, microhardness and scratch resistance were determined. On the basis of the results obtained, it was concluded that the thickness of the coatings complies with the requirements of conventional anodizing. Additionally, microhardness values exceeded the results obtained with standard methods.
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Bibliography

[1] Famiyeh, L. & Huang, H. (2019). Plasma electrolytic oxidation coatings on aluminum alloys: microstructures, properties, and applications. Modern Concepts in Material Science. 2(1), 1-13. DOI: 10.33552/MCMS.2019.02.000526.
[2] Sieber, M., Simchen, F., Morgenstern, R., Scharf, I. & Lampke, T. (2018). Plasma electrolytic oxidation of high-strength aluminium alloys-substrate effect on wear and corrosion performance. Metals. 8(5), 356. DOI: 10.3390/met8050356.
[3] Matykina, E., Arrabal, R., Mohedano, M., Mingo, B., Gonzalez, J., Pardo, A. & Merino, M.C. (2017). Recent advances in energy efficient PEO processing of aluminium alloys. Transactions of Nonferrous Metals Society of China. 27(7) 1439-1454. DOI: 10.1016/S1003-6326(17)60166-3.
[4] Agureev, L., Savushkina, S., Ashmarin, A., Borisov, A., Apelfeld, A., Anikin, K., Tkachenko, N., Gerasimov, M., Shcherbakov, A., Ignatenko, V. & Bogdashkina, N. (2018). Study of plasma electrolytic oxidation coatings on aluminum composites. Metals. 8(6), 459. DOI: 10.3390/met8060459.
[5] Lakshmikanthan, A., Bontha, S., Krishna, M., Praveennath, G.K. & Ramprabhu, T. (2019). Microstructure, mechanical and wear properties of the A357 composites reinforced with dual sized SiC particles. Journal of Alloys and Compounds. 786, 570-580. DOI: 10.1016/j.jallcom.2019.01.382.
[6] Lakshmikanthan, A., Prabhu, T.R., Babu, U.S., Koppad, P.G., Gupta, M., Krishna, M. & Bontha, S. (2020). The effect of heat treatment on the mechanical and tribological properties of dual size SiC reinforced A357 matrix composites. Journal of Materials Research and Technology. 9(3), 6434-6452. DOI: 10.1016/j.jmrt.2020.04.027.
[7] Rogov, A., Lyu, H., Matthews, A. & Yerokhin, A. (2020). AC plasma electrolytic oxidation of additively manufactured and cast AlSi12 alloys. Surface and Coatings Technology, 399, 126116. DOI: 10.1016/j.surfcoat.2020.126116.
[8] Li, K., Li, W., Zhang, G., Zhu, W., Zheng, F., Zhang, D. & Wang, M. (2019). Effects of Si phase refinement on the plasma electrolytic oxidation of eutectic Al-Si alloy. Journal of Alloys and Compounds. 790, 650-656. DOI: 10.1016/j.jallcom.2019.03.217.
[9] Gencer, Y., Tarakci, M., Gule, A.E. & Oter C.Z. (2014). Plasma Electrolytic Oxidation of Binary Al-Sn Alloys. Acta Physica Polonica A. 125(2), 659-663. DOI: 10.12693/APhysPolA.125.659.
[10] Moszczyński, P. & Trzaska, M. (2011). Shaping of oxide layers on the aluminum surface by plasma electrochemical oxidation. Elektronika: konstrukcje, technologie, zastosowania. 52(12), 96-99. (in Polish).
[11] He, J., Cai, Q.Z., Luo, H.H., Yu, L. & Wei, B.K. (2009). Influence of silicon on growth process of plasma electrolytic oxidation coating on Al–Si alloy. Journal of Alloys and Compounds. 471(1-2), 395-399. DOI: 10.1016/ j.jallcom.2008.03.114.
[12] Blawert, C., Karpushenkov, S.A., Serdechnovaa, M., Karpushenkava, L.S. & Zheludkevicha, M.L. (2020). Plasma electrolytic oxidation of zinc alloy in a phosphate-aluminate electrolyte. Applied Surface Science. 505, 144552, DOI: 10.1016/j.apsusc.2019.144552.
[13] Dehnavi, V. (2014). Surface Modification of Aluminum Alloys by Plasma Electrolytic Oxidation. A thesis submitted in partial fulfillment of the requirements for the degree in Doctor of Philosophy The School of Graduate and Postdoctoral Studies, The University of Western Ontario London, Ontario, Canada.
[14] Zhang, Y., Xu, H., Yang, Y. (2007). Study on the optimization of pulse frequency in the micro arc oxidation of aluminum alloys. Proceedings of Vacuum Metallurgy and Surface Engineering. Beijing: Electronics Industry Press. 33−40.
[15] Habazaki, H., Onodera, T., Fushimi, K., Konno, H. & Toyotake, K. (2007). Spark anodizing of β-Ti alloy for wear resistant coating. Surface and Coatings Technology. 201(21), 8730-8737. DOI: 10.1016/j.surfcoat.2006.05.041.
[16] Kurze, P., Krysmann, W. & Schneider, H.G. (2006). Application fields of ANOF layers and composites. Crystal Research and Technology. 21(12), 1603-1609. DOI: 10.1002/crat.2170211224.
[17] Butyagin, P.I., Khorkhryakov, Y.V. & Mamaev, A.I. (2003). Microplasma systems for creating coatings on aluminium alloys. Materials Letters. 57(11), 1748-1751. DOI: 10.1016/S0167-577X(02)01062-5.
[18] Sonova, A.I. & Terleeva, O.P. (2008). Morphology, structure, and phase composition of microplasma coatings formed on Al−Cu−Mg alloy. Protection of Metals. 44(1), 65-75. DOI: 10.1134/S0033173208010098.
[19] Shihai, C., Jiunmin, H., Weijing, L., Suk-Bong, K. & Jung-Moo, L. (2006). Study on wear behavior of plasma electrolytic oxidation coatings on aluminum alloy. Rare Metals. 25(6), 141-145. DOI: 10.1016/S1001-0521(08)60069-8.
[20] Dai, L., Li, W., Zhang, G., Fu, N. & Duan, Q. (2017). Anti-corrosion and wear properties of plasma electrolytic oxidation coating formed on high Si content Al alloy by sectionalized oxidation mode. In IOP Conf. Series: Materials Science and Engineering, 19–21 November 2016 (167, 012063), Sanya, China: IOP Publishing Ltd. DOI: 10.1088/1757-899X/167/1/012063.
[21] Li, Q.B., Liu, C.C., Yang, W.B. & Liang, J. (2017). Growth mechanism and adhesion of PEO coatings on 2024Al alloy. Surface Engineering. 33(10), 760-766. DOI: 10.1080/02670844.2016.1200860.
[22] Ayday, A. & Durman, M. (2015). Growth characteristics of plasma electrolytic oxidation coatings on aluminum alloys. Acta Physica Polonica A. 127(4), 886-887, DOI: 10.12693/APhysPolA.127.886.
[23] Dehnavi, V., Shoesmith, D.W., Luan, B.L., Yari, M. & Liu, X.Y. & Rohani, S. (2015). Corrosion properties of plasma electrolytic oxidation coatings on an aluminium alloy – The effect of the PEO process stage. Materials Chemistry and Physics. 161, 49-58. DOI: 10.1016/j.matechemphys.2015.04.058.
[24] Gębarowski, W. & Pietrzyk, S. (2012). Plasma electrolytic oxidation of aluminum process technology outline. Rudy i Metale Nieżelazne. 57(4), 237-242. (in Polish).
[25] Duanjie, L. (2014). Scratch hardness measurement using mechanical tester. Retrieved February 12, 2020, from http://nanovea.com/app-notes/scratch-hardness-measurement.pl
[26] Hussein, R.O. & Northwood, D.O. (2014). Production of anti-corrosion coatings on light alloys (Al, Mg, Ti) by plasma-electrolytic oxidation (PEO). In Mahmood Aliofkhazraei (Eds.), Developments in Corrosion Protection (pp. 201-238). London, UK: IntechOpen Limited. DOI: 10.5772/57171.
[27] Wredenberg, F. & Larsson, P.-L. (2009). Scratch testing of metals and polymers: Experiments and numerics. Wear. 266(1-2), 76-83. DOI: 10.1016/j.wear.2008.05.014.
[28] Hussein, R.O., Northwood, D.O. & Nie, X. (2012). The influence of pulse timing and current mode on the microstructure and corrosion behaviour of a plasma electrolytic oxidation (PEO) coated AM60B magnesium alloy. Journal of Alloys and Compounds. 541, 41-48, DOI: 10.1016/j.jallcom.2012.07.003.
[29] Matykina, E., Arrabal, R., Skeldon, P. & Thompson, G.E. (2009). Investigation of the growth processes of coatings by AC plasma electrolytic oxidation of aluminum. Electrochimica Acta. 54(27), 6767-6778.
[30] Sharift, H., Aliofkhazraei, M. & Darband, G.B. (2018). A review on adhesion strength of PEO coatings by scratch test method. Surface Review and Letters. 25(3), 1830004. DOI: 10.1142/S0218625X18300046.
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Authors and Affiliations

P. Długosz
1
ORCID: ORCID
A. Garbacz-Klempka
2
ORCID: ORCID
J. Piwowońska
1
P. Darłak
3
ORCID: ORCID
M. Młynarczyk
3

  1. Lukasiewicz Research Network - Krakow Institute of Technology, 73 Zakopiańska Str. 30-418 Cracow, Poland
  2. AGH University of Science and Technology, Faculty of Foundry Engineering, Reymonta 23 Str., 30-059 Kraków, Poland
  3. AGH University of Science and Technology, Faculty of Foundry Engineering, 23 Reymonta Str., 30-059 Kraków, Poland
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Abstract

The paper deals with squeeze casting technology. For this research a direct squeeze casting method has been chosen. The influence of process parameters variation (casting temperature, mold temperature, pressure) on mechanical properties and structure will be observed. The thicknesses of the individual walls were selected based on the use of preferred numbers and series of preferred numbers (STN ISO 17) with the sequence of 3.15, 4.00, 5.00, 6.00 and 8.00 mm. The width of each wall was 22 mm with a length of 100 mm. As an experimental material was chosen the AlSi12 and AlSi7Mg0.3 alloys. The mechanical properties (UTS, E) for individual casting parameters and their individual areas of different thicknesses were evaluated. In the structure the influence of pressure on the change of the eutectic morphology, the change of the volume of eutectic and the primary alpha phase, the effect of the pressure on the more fine-grain and the regularization of the structure were evaluated.

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Authors and Affiliations

R. Pastirčák
J. Ščury
M. Brůna
D. Bolibruchová
J. Jakubski
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Abstract

This article presents a study of the crystallization and microstructure of the AlSi9 alloy (EN AC-AlSi9) used for the alfin processing of iron ring supports in castings of silumin pistons. Alfin processing in brief is based on submerging an iron casting in an Al-Si bath, maintaining it there for a defined time period, placing it in a chill mould casting machine and immersing it in the alloy. This technology is used for iron ring supports in the pistons of internal combustion engines, among others. Thermal analysis shows that when the AlSi9 alloy contains a minimal content of iron, nucleation and increase in the triple (Al)+Fe+(Si) eutectic containing the -Al8Fe2Si phase takes place at the end of the crystallization of the double (Al)+(Si) eutectic. Due to the morphology of the ”Chinese script” the -Al8Fe2Si phase is beneficial and does not reduce the alloy’s brittleness. After approx. 5 hours of alfin processing, the -Al5FeSi phase crystallizes as a component of the +Al5FeSi+(Si) eutectic. Its disadvantageous morphology is ”platelike” with sharp corners, and in a microsection of the surface, ”needles” with pointed corners are visible, with increases the fragility of the AlSi9 alloys.

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Authors and Affiliations

J. Piątkowski
ORCID: ORCID
M. Czerepak
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Abstract

In this study, metal matrix composite materials containing melt-spun Al-20Si-5Fe alloys and boron carbide was produced by high energy ball milling and then hot pressing at 200 MPa pressure and 450°C. Mechanical and microstructural characterizations were performed by using an optical microscopy, X-Ray diffractometer, and dynamic microhardness tester. It was observed that boron carbide particles were homogenously distributed in the microstructure and values of microhardness and elastic modules were averagely 830 MPa and 42 GPa, respectively.
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Authors and Affiliations

Fatih Kilicaslan M.
Uzun A.
E. Karakose
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Abstract

The chosen, typical causes of quality defects of cast-iron „alphin” rings embedded in aluminum cast are being presented in this paper.

Diffusive joint of those inserts with the pistons casts is being used, due to extreme work conditions of destructive influence of the fuel mix

and variable thermo-mechanical loads, which reign in the combustion motor working chamber.

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Authors and Affiliations

J. Piątkowski
P. Kamiński
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Abstract

The paper presents an analysis of the effect of shape of primary silicon crystals on the sizes of stresses and deformations in a surface layer

of A390.0 alloy by Finite Elements Method (FEM). Analysis of stereological characteristics of the studied alloy, performed based on a

quantitative metallographic analysis in combination with a statistical analysis, was used for this purpose. The presented simulation tests

showed not only the deposition depth of maximum stresses and strains, but also allowed for determining the aforementioned values

depending on the shape of the silicon crystals. The studied material is intended for pistons of internal combustion engines, therefore the

analysis of the surface layer corresponded to conditions during friction in a piston-cylinder system of an internal combustion engine having

power of up to 100 kW. The obtained results showed important differences in the values of stresses and strains up to 15% between various

shape of the silicon crystals. Crystals with sharp edges caused higher stresses and deformation locally than those with rounded shapes.

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Authors and Affiliations

R. Wieszała
J. Piątkowski
H. Bąkowski
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Abstract

In the dissertation it has been shown, that so called “time-thermal treatment” (TTT) of the alloy in liquid state as overheating the metal

with around 250o

C above Tliq. and detailing it in temperature for 30 to 40 minutes has the influence on changing the crystallization

parameters (Tliq., TEmin.

, TEmax., TE(Me), TSol.). It was ascertained, that overheating the AlSi17Cu5Mg alloy substantially above Tliq. results

with microcrystalline structure. Evenly distributed in the eutectic warp primeval silicon crystals and supersaturated with alloying additives

of base content (Cu, Mg, Fe) of α(Al) solution, ensures not only increase durability in ambient temperature, but also at elevated

temperature (250o

C), what due to it’s use in car industry is an advantage.

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Authors and Affiliations

J. Piątkowski
P. Kamiński
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Abstract

The paper presents the influence of modification with phosphorus (CuP10) on the tribological properties of the alloy AlSi17Cu5Mg coupled

abrasively with cast-iron EN GJL-350. Tests of coefficient of friction and wear of mass were conducted on tribological tester T-01. An

important aspect in the assessment of the tribological properties is the analysis of initial material microstructure in reference to silumin which

underwent modification with phosphorus. It was found that the difference in structure of tested materials, mainly sizes of primary silicon

crystals significantly influences the tribological properties whereas the speed change of the friction knot does not have such big influence.

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Authors and Affiliations

J. Piątkowski
R. Wieszała
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Abstract

This paper considers the assessment of attenuation in aluminium alloys castings and in cast iron prepared by gravity casting method and by casting under pressure. The issue of ultrasound attenuation is important in setting the conditions of non-destructive (NDT) testing, especially in casted materials. The characteristics of the ultrasonic technique and ultrasonic attenuation and the calculation of the attenuation and the velocity of ultrasound are presented in the theoretical part of this paper. For experimental measurements, cylindrical castings from AlSi alloy (a hypoeutectic alloy with a silicon content of about 7% - AlSi7 and a eutectic alloy with a silicon content of about 12% - AlSi12) and from grey and ductile cast iron were made. The ultrasonic records of the casting control, the calculation of ultrasound attenuation for individual samples are listed and described in the experimental part. The evaluation of measurements and comparison of calculated ultrasound attenuation is at the end of this article.
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Authors and Affiliations

M. Boháčik
M. Mičian
A. Sládek
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Abstract

The paper deals with influence of multiple remelting on AlSi9Cu3 alloy with higher iron content on chosen mechanical properties. Multiple remelting may in various ways influence mechanical, foundry properties, gas saturation, shrinkage cavity, fluidity etc. of alloy. Higher presence of iron in Al-Si cast alloys is common problem mainly in secondary (recycled) aluminium alloys. In Al-Si alloy the iron is the most common impurity and with presence of other elements in alloy creates the intermetallic compounds, which decreases mechanical properties. Iron in the used alloy was increased to about 1.4 wt. %, so that the influence of increased iron content can be investigated. In the paper, the effect of multiple remelting is evaluated with respect to the resulting mechanical properties in cast state, after the heat treatment (T5) and after natural aging. From the obtained results it can be concluded that the multiple remelting leads to change of chemical composition and affect the mechanical properties.
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Authors and Affiliations

M. Matejka
D. Bolibruchová
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Abstract

Paper present a thermal analysis of laser heating and remelting of EN AC-48000 (EN AC-AlSi12CuNiMg) cast alloy used mainly for

casting pistons of internal combustion engines. Laser optics were arranged such that the impingement spot size on the material was a

circular with beam radius rb changes from 7 to 1500 m. The laser surface remelting was performed under argon flow. The resulting

temperature distribution, cooling rate distribution, temperature gradients and the depth of remelting are related to the laser power density

and scanning velocity. The formation of microstructure during solidification after laser surface remelting of tested alloy was explained.

Laser treatment of alloy tests were perform by changing the three parameters: the power of the laser beam, radius and crystallization rate.

The laser surface remelting needs the selection such selection of the parameters, which leads to a significant disintegration of the structure.

This method is able to increase surface hardness, for example in layered castings used for pistons in automotive engines.

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Authors and Affiliations

J. Piątkowski
A. Grabowski
M. Czerepak
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Abstract

The purpose of this study is to identify relationships between the values of the fluidity obtained by computer simulation and by an experimental test in the horizontal three-channel mould designed in accordance with the Measurement Systems Analysis. Al-Si alloy was a model material. The factors affecting the fluidity varied in following ranges: Si content 5 wt.% – 12 wt.%, Fe content 0.15 wt.% – 0.3wt. %, the pouring temperature 605°C-830°C, and the pouring speed 100 g · s–1 – 400 g · s–1. The software NovaFlow&Solid was used for simulations. The statistically significant difference between the value of fluidity calculated by the equation and obtained by experiment was not found. This design simplifies the calculation of the capability of the measurement process of the fluidity with full replacement of experiments by calculation, using regression equation.

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Authors and Affiliations

P. Futáš
J. Petrík
A. Pribulová
P. Blaško
P. Palfy
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Abstract

Casting porosity is the main factor influencing the fatigue properties of Al-Si alloys. Due to the increasing use of aluminum castings, porosity characterization is useful for estimating their fatigue strength. In principle, a combination of metallographic techniques and statistical pore analysis is a suitable approach for predicting the largest defect size that is critical for the casting. Here, the influence of modifiers and casting technology on the largest pore size population in AlSi7Mg alloy specimens is obtained and discussed adopting the Murakami's approach. However, porosity evaluation is a challenge in the case of microshrinkage pores, which are frequently found in industrial castings. Their complicated morphology prevents a reliable definition of an equivalent defect size based on metallographic techniques. This contribution reports the application of X-ray tomography to the 3D reconstruction of real pores in cast Al-Si alloys and provides insight into the complication of microshrinkage pore sizing by metallography.

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Authors and Affiliations

Stanislava Fintová
Giancarlo Anzelotti
Radomila Konečná
Gianni Nicoletto
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Abstract

The study aims to investigate the effect of semisolid structure and strontium (Sr) addition on the wear behavior of hypoeutectic Al-Si alloy. Semisolid hypoeutectic Al-Si alloy was prepared using cooling slope casting with addition of 0 to 0.93 wt.% Sr. Microstructural study was done using an optical microscope. Vicker microhardness and pin on disc tribometer were used for microhardness and wear testing. When compared to conventional casting, the microhardness of the semisolid hypoeutectic Al-Si alloy improved by 9.8%. Sr addition at 0.43 wt.% resulted in a refined eutectic structure with a 17% increase in hardness over conventional casting. The globular structure α-Al formed during semisolid casting reduced porosity, and the addition of Sr refined the eutectic silicon into a fine fibrous structure that is tightly bound with the Al matrix. These are the primary factors that contribute to the high wear resistance in modified-Sr semisolid alloys.
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Authors and Affiliations

N.M. Anas
1
ORCID: ORCID
S.A. Zakaria
1
ORCID: ORCID
A.S. Anasyida
1
ORCID: ORCID
H. Mohamad
1
ORCID: ORCID
B.K. Dhindaw
2
ORCID: ORCID

  1. Universiti Sains Malaysia, Structural Niche Area. School of Mat erials & Mineral Resources Engineering, Engineering Campus, Malaysia 14300 Nibong Tebal, Pulau Pinang
  2. Indian Institute of Technology Kharagpur 721302, India
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Abstract

The technology of high-pressure die-casting (HPDC) of aluminum alloys is one of the most used and most economical technology for mass production of castings. High-pressure die-casting technology is characterized by the production of complex, thin-walled and dimensionally accurate castings. An important role is placed on the effective reduction of costs in the production process, wherein the combination with the technology of high-pressure die-casting is the possibility of recycling using returnable material. The experimental part of the paper focuses on the analysis of a gradual increase of the returnable material amount in combination with a commercial purity alloy for the production of high-pressure die-castings. The returnable material consisted of the so-called foundry waste (defective castings, venting and gating systems, etc.). The first step of the experimental castings evaluation consisted of numerical simulations, performed to determine the points of the casting, where porosity occurs. In the next step, the evaluation of areal porosity and microstructural analysis was performed on experimental castings with different amounts of returnable material in the batch. The evaluation of the area porosity showed only a small effect of the increased amount of the returnable material in the batch, where the worst results were obtained by the casting of the alloy with 90% but also with 55% of the returnable material in the batch. The microstructure analysis showed that the increase in returnable material in the batch was visibly manifested only by a change in the morphology of the eutectic Si.
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Bibliography

[1] Ragan, E. (2007). Die casting of metals. Prešov, Slovakia. (in Slovak).
[2] Eperješi, Ľ., Malik, J., Eperješi Š. & Fecko D. (2013) Influence of returning material on porosity of die castings. Manufacturing Technology. 13(1), 36-39. DOI: 10.21062/ujep/x.2013/a/1213-2489/MT/13/1/36.
[3] Gaustad, G., Olivetti, E. A. & Kirchain, R. (2012). Improving aluminum recycling: A survey of sorting and impurity removal technologies. Resources Conservation and Recycling. 58, 79-87.
[4] Matejka, M., Bolibruchová, D. & Kuriš, M. (2021). Crystallization of the structural components of multiple remelted AlSi9Cu3 alloy. Archives of Foundry Engineering. 21(2), 41-45. DOI: 10.24425/afe.2021.136096.
[5] Bruna, M., Remišová, A. & Sládek, A. (2019). Effect of filter thickness on reoxidation and mechanical properties of aluminium alloy AlSi7Mg0.3. Archives of Metallurgy and Materials. 3, 1100-1106. DOI: 10.24425/amm.2019.129500.
[6] Bryksi Stunova, B. & Bryksi, V. (2016). Analysis of defects in castings cast by rheocasting method SEED. Archives of Foundry Engineering. 16(3), 15-18. DOI: 10.1515/afe-2016-0041.
[7] Podprocká, R. & Bolibruchová, D. (2017). Iron intermetallic phases in the alloy based on Al-Si-Mg by applying manganese. Archives of Foundry Engineering. 17(3), 217-221. DOI: 10.24425/afe.2020.133321.
[8] Martinec, D., Pastircak, R. & Kantorikova, E. (2020). Using of technology semisolid squeeze casting by different initial states of material. Archives of Foundry Engineering. 20(1), 117-121. DOI: 10.24425/afe.2020.131292.
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Authors and Affiliations

M. Matejka
1
ORCID: ORCID
D. Bolibruchová
1
ORCID: ORCID
R. Podprocká
2

  1. University of Zilina, Faculty of Mechanical Engineering, Department of Technological Engineering, Univerzitna 1, 010 26 Zilina, Slovak Republic
  2. Rosenberg-Slovakia s.r.o., Kováčska 38, 044 25 Medzev, Slovak Republic
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Abstract

The European Commission's ambitious plan to reduce CO2 emissions has a significant impact on the global automotive industry. Recent development of new diesel and petrol engines with direct injection is aimed at improving fuel efficiency while maintaining (or enhancing) engine performance. This naturally also increases the demands on the properties of the most stressed engine components (e.g., cylinder heads, engine blocks, pistons), which leads to the development of new materials. Presented work analysed the effect of different mold temperatures (60; 120; 180 °C) on mechanical, physical properties and microstructure of AlSi5Cu2Mg aluminium alloy. This alloy is currently being used for the production of cylinder head castings. The results showed that the changing mold temperature had an effect on mechanical properties (ultimate tensile strength and Young modulus values). SEM with EDX analysis of intermetallic phases revealed there were no size and morphology changes of Cu, Mg and Fe intermetallic phases when the mold temperature changed. No significant effect of different mold temperature on physical properties (thermal and electrical conductivity) and fracture mechanism occurred during experiment. Optimal combination of mechanical and physical properties of AlSi5Cu2Mg alloy was achieved using a permanent mold with temperature ranging from 120 to 180 °C.
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Bibliography

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Authors and Affiliations

L. Širanec
1
ORCID: ORCID
D. Bolibruchová
1
ORCID: ORCID
M. Chalupová
1
ORCID: ORCID

  1. Department of Technological Engineering, Faculty of Mechanical Engineering, University of Žilina, Slovakia
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Abstract

The article presents the most important causes of the unstable connection between cast iron ring inserts and the silumin casting of an engine piston. It is shown that manufacturing defects are mainly related to the alfin processing of inserts in Al-Si alloy (the so-called AS9 alloy). Exceeding the permissible iron content in AS9 alloy causes the crystallization of brittle -Al5FeSi phases. Their unfavorable morphology and large size are the main reasons for the weakening of the diffusion connection between the inserts and the piston, causing an unacceptable proportion of defective products. The study presented in this work was conducted under industrial conditions on a population of 10.000 pistons. Quality control data, production parameters, as well as the micro- and macro-structures of the cast iron inserts, and the interface area between the inserts and the silumin piston, were analyzed. Material and technological solutions have been proposed to reduce the occurrence of casting defects at the insert-piston joint. This includes the introduction of so-called "morphological correctors" of the -Al5FeSi phases, reducing the possibility of gaseous impurities in the AS9 alloy and optimizing the temperature of the alfin alloy.
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Authors and Affiliations

M. Szucki
1
ORCID: ORCID
J. Piątkowski
2
ORCID: ORCID
M. Czerepak
3

  1. Foundry Institute, Technische Universität Bergakademie Freiberg, Bernhard-von-Cotta-Str. 4,09599 Freiberg, Germany
  2. Department of Material Technologies, Silesian University of Technology, Krasińskiego 8, 40-019 Katowice, Poland
  3. Federal-Mogul Gorzyce sp. z o.o., Odlewników 52, 39-432 Gorzyce, Poland
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Abstract

Monitoring the solidification process is of great importance for understanding the quality of the melt, for controlling it, and for predicting the true properties of the alloy. Solidification is accompanied by the development of heat, the magnitude of which depends on the different phases occurring during solidification. Thermal analysis is now an important part of and tool for quality control, especially when using secondary aluminium alloys in the automotive industry. The effect of remelting on the change of crystallization of individual structural components of experimental AlSi9Cu3 alloy was determined by evaluation of cooling curves and their first derivatives. Structural analysis was evaluated using a scanning electron microscope. The effect of remelting was manifested especially in nucleation of phases rich in iron and copper. An increasing number of remelts had a negative effect after the fourth remelting, when harmful iron phases appeared in the structure in much larger dimensions.

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Authors and Affiliations

M. Matejka
ORCID: ORCID
D. Bolibruchova
Justyna Kasińska
ORCID: ORCID
M. Kuriš
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Abstract

The effect of possible modification and refining effect of Al-Cu-P-based pre-alloy combined with Fe on the microstructure and the silicon morphology change in hypereutectic Al-Si cast alloy was studied. The samples in the as-cast state were observed by optical and scanning electron microscopy with energy-dispersive X-ray spectroscopy. The 3D morphology of both primary and eutectic silicon was observed by using colour and deep etching in detail. The results showed that the AlCu19P1.4 pre-alloy (1.07 wt.%) combined with the addition of Fe (0.02 wt.%) has a significant effect on the change of the amount, size and morphology of primary Si. This is significantly refined and changes the shape from a coarse irregular star-shaped, polyhedral, or plate-like shape to a fine polyhedral shape. The average size of the primary Si is reduced by about of 78 % from 135 μm to 28 μm and the number of primary Si particles increased from 7.4 to 237. No change in the morphology of the eutectic Si was observed; a refinement of the structure from a coarse needle/plate-like to a fine plate-like structure was seen. The depth etching method using HCl was very effective in the study of the 3D silicon morphology observed, which could be observed in detail without the presence of artefacts.
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Authors and Affiliations

Eva Tillová
1
ORCID: ORCID
Mária Chalupová
1
Lenka Kuchariková
1
ORCID: ORCID
Mirosław Bonek
2
ORCID: ORCID
Milan Uhríčik
1
Lucia Pastierovičová
1

  1. University of Žilina, Faculty of Mechanical Engineering, Department of Materials Engineering, Univerzitná 8215/1, 010 26 Žilina, Slovak Republic
  2. Silesian University of Technology, Faculty of Mechanical Engineering, Department of Engineering Materials and Biomaterials, ul. Konarskiego 18A, 44-100 Gliwice, Poland

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