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Abstract

The paper deals with problems related to application of aluminum-silicon alloys for combustion engine cylinder liners

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Authors and Affiliations

A. Trytek
M. Tupaj
M. Mróz
A.W. Orłowicz
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Abstract

The paper presents results of a study concerning an AlSi7Mg alloy and the effect of subjecting the liquid metal to four different processes: conventional refining with hexachloroethane; the same refining followed by modification with titanium, boron, and sodium; refining by purging with argon carried out in parallel with modification with titanium and boron salts and strontium; and parallel refining with argon and modification with titanium, boron, and sodium salts. The effect of these four processes on compactness of the material, parameters of microstructure, and fatigue strength of AlSi7Mg alloy after heat treatment. It has been found that the highest compactness (the lowest porosity ratio value) and the most favorable values of the examined parameters of microstructure were demonstrated by the alloy obtained with the use of the process including parallel purging with argon and modification with salts of titanium, boron, and sodium. It has been found that in the fatigue cracking process observed in all the four variants of the liquid metal treatment, the crucial role in initiation of fatigue cracks was played by porosity. Application of the process consisting in refining by purging with argon parallel to modification with Ti, B, and Na salts allowed to refine the microstructure and reduce significantly porosity of the alloy extending thus the time of initiation and propagation of fatigue cracks. The ultimate effect consisted in a distinct increase of the fatigue limit value.

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Authors and Affiliations

M. Tupaj
ORCID: ORCID
A.W. Orłowicz
ORCID: ORCID
A. Trytek
ORCID: ORCID
Marek Mróz
ORCID: ORCID
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Abstract

Plasma oxidation, similarly to anodic oxidation (anodizing), are classified as electrochemical surface treatment of metals such as Al, Mg, Ti and their alloys. This type of treatment is used to make surface of castings, plastically processed products, shaped with incremental methods to suitable for certain requirements. The most important role of the micro plasma coating is to protect the metal surface against corrosion. It is well known that coating of aluminium alloys containing silicon using anodic oxidation causes significant difficulties. They are linked to the eutectic nature of this alloy and result in a lack of coverage in silicon-related areas. The coating structure in these areas is discontinuous. In order to eliminate this phenomenon, it is required to apply oxidation coatings using the PEO (Plasma Electrolytic Oxidation) method. It allows a consistent, crystalline coating to be formed. This study presents the mechanical properties of the coatings applied to Al-Si alloy using the PEO method. As part of the testing, the coating thickness, microhardness and scratch resistance were determined. On the basis of the results obtained, it was concluded that the thickness of the coatings complies with the requirements of conventional anodizing. Additionally, microhardness values exceeded the results obtained with standard methods.
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Bibliography

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[12] Blawert, C., Karpushenkov, S.A., Serdechnovaa, M., Karpushenkava, L.S. & Zheludkevicha, M.L. (2020). Plasma electrolytic oxidation of zinc alloy in a phosphate-aluminate electrolyte. Applied Surface Science. 505, 144552, DOI: 10.1016/j.apsusc.2019.144552.
[13] Dehnavi, V. (2014). Surface Modification of Aluminum Alloys by Plasma Electrolytic Oxidation. A thesis submitted in partial fulfillment of the requirements for the degree in Doctor of Philosophy The School of Graduate and Postdoctoral Studies, The University of Western Ontario London, Ontario, Canada.
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[24] Gębarowski, W. & Pietrzyk, S. (2012). Plasma electrolytic oxidation of aluminum process technology outline. Rudy i Metale Nieżelazne. 57(4), 237-242. (in Polish).
[25] Duanjie, L. (2014). Scratch hardness measurement using mechanical tester. Retrieved February 12, 2020, from http://nanovea.com/app-notes/scratch-hardness-measurement.pl
[26] Hussein, R.O. & Northwood, D.O. (2014). Production of anti-corrosion coatings on light alloys (Al, Mg, Ti) by plasma-electrolytic oxidation (PEO). In Mahmood Aliofkhazraei (Eds.), Developments in Corrosion Protection (pp. 201-238). London, UK: IntechOpen Limited. DOI: 10.5772/57171.
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[28] Hussein, R.O., Northwood, D.O. & Nie, X. (2012). The influence of pulse timing and current mode on the microstructure and corrosion behaviour of a plasma electrolytic oxidation (PEO) coated AM60B magnesium alloy. Journal of Alloys and Compounds. 541, 41-48, DOI: 10.1016/j.jallcom.2012.07.003.
[29] Matykina, E., Arrabal, R., Skeldon, P. & Thompson, G.E. (2009). Investigation of the growth processes of coatings by AC plasma electrolytic oxidation of aluminum. Electrochimica Acta. 54(27), 6767-6778.
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Authors and Affiliations

P. Długosz
1
ORCID: ORCID
A. Garbacz-Klempka
2
ORCID: ORCID
J. Piwowońska
1
P. Darłak
3
ORCID: ORCID
M. Młynarczyk
3

  1. Lukasiewicz Research Network - Krakow Institute of Technology, 73 Zakopiańska Str. 30-418 Cracow, Poland
  2. AGH University of Science and Technology, Faculty of Foundry Engineering, Reymonta 23 Str., 30-059 Kraków, Poland
  3. AGH University of Science and Technology, Faculty of Foundry Engineering, 23 Reymonta Str., 30-059 Kraków, Poland
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Abstract

In this study, metal matrix composite materials containing melt-spun Al-20Si-5Fe alloys and boron carbide was produced by high energy ball milling and then hot pressing at 200 MPa pressure and 450°C. Mechanical and microstructural characterizations were performed by using an optical microscopy, X-Ray diffractometer, and dynamic microhardness tester. It was observed that boron carbide particles were homogenously distributed in the microstructure and values of microhardness and elastic modules were averagely 830 MPa and 42 GPa, respectively.
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Authors and Affiliations

Fatih Kilicaslan M.
Uzun A.
E. Karakose
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Abstract

In the dissertation it has been shown, that so called “time-thermal treatment” (TTT) of the alloy in liquid state as overheating the metal

with around 250o

C above Tliq. and detailing it in temperature for 30 to 40 minutes has the influence on changing the crystallization

parameters (Tliq., TEmin.

, TEmax., TE(Me), TSol.). It was ascertained, that overheating the AlSi17Cu5Mg alloy substantially above Tliq. results

with microcrystalline structure. Evenly distributed in the eutectic warp primeval silicon crystals and supersaturated with alloying additives

of base content (Cu, Mg, Fe) of α(Al) solution, ensures not only increase durability in ambient temperature, but also at elevated

temperature (250o

C), what due to it’s use in car industry is an advantage.

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Authors and Affiliations

J. Piątkowski
P. Kamiński
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Abstract

This paper considers the assessment of attenuation in aluminium alloys castings and in cast iron prepared by gravity casting method and by casting under pressure. The issue of ultrasound attenuation is important in setting the conditions of non-destructive (NDT) testing, especially in casted materials. The characteristics of the ultrasonic technique and ultrasonic attenuation and the calculation of the attenuation and the velocity of ultrasound are presented in the theoretical part of this paper. For experimental measurements, cylindrical castings from AlSi alloy (a hypoeutectic alloy with a silicon content of about 7% - AlSi7 and a eutectic alloy with a silicon content of about 12% - AlSi12) and from grey and ductile cast iron were made. The ultrasonic records of the casting control, the calculation of ultrasound attenuation for individual samples are listed and described in the experimental part. The evaluation of measurements and comparison of calculated ultrasound attenuation is at the end of this article.
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Authors and Affiliations

M. Boháčik
M. Mičian
A. Sládek
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Abstract

Paper present a thermal analysis of laser heating and remelting of EN AC-48000 (EN AC-AlSi12CuNiMg) cast alloy used mainly for

casting pistons of internal combustion engines. Laser optics were arranged such that the impingement spot size on the material was a

circular with beam radius rb changes from 7 to 1500 m. The laser surface remelting was performed under argon flow. The resulting

temperature distribution, cooling rate distribution, temperature gradients and the depth of remelting are related to the laser power density

and scanning velocity. The formation of microstructure during solidification after laser surface remelting of tested alloy was explained.

Laser treatment of alloy tests were perform by changing the three parameters: the power of the laser beam, radius and crystallization rate.

The laser surface remelting needs the selection such selection of the parameters, which leads to a significant disintegration of the structure.

This method is able to increase surface hardness, for example in layered castings used for pistons in automotive engines.

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Authors and Affiliations

J. Piątkowski
A. Grabowski
M. Czerepak
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Abstract

The study aims to investigate the effect of semisolid structure and strontium (Sr) addition on the wear behavior of hypoeutectic Al-Si alloy. Semisolid hypoeutectic Al-Si alloy was prepared using cooling slope casting with addition of 0 to 0.93 wt.% Sr. Microstructural study was done using an optical microscope. Vicker microhardness and pin on disc tribometer were used for microhardness and wear testing. When compared to conventional casting, the microhardness of the semisolid hypoeutectic Al-Si alloy improved by 9.8%. Sr addition at 0.43 wt.% resulted in a refined eutectic structure with a 17% increase in hardness over conventional casting. The globular structure α-Al formed during semisolid casting reduced porosity, and the addition of Sr refined the eutectic silicon into a fine fibrous structure that is tightly bound with the Al matrix. These are the primary factors that contribute to the high wear resistance in modified-Sr semisolid alloys.
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Authors and Affiliations

N.M. Anas
1
ORCID: ORCID
S.A. Zakaria
1
ORCID: ORCID
A.S. Anasyida
1
ORCID: ORCID
H. Mohamad
1
ORCID: ORCID
B.K. Dhindaw
2
ORCID: ORCID

  1. Universiti Sains Malaysia, Structural Niche Area. School of Mat erials & Mineral Resources Engineering, Engineering Campus, Malaysia 14300 Nibong Tebal, Pulau Pinang
  2. Indian Institute of Technology Kharagpur 721302, India
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Abstract

The article presents the most important causes of the unstable connection between cast iron ring inserts and the silumin casting of an engine piston. It is shown that manufacturing defects are mainly related to the alfin processing of inserts in Al-Si alloy (the so-called AS9 alloy). Exceeding the permissible iron content in AS9 alloy causes the crystallization of brittle -Al5FeSi phases. Their unfavorable morphology and large size are the main reasons for the weakening of the diffusion connection between the inserts and the piston, causing an unacceptable proportion of defective products. The study presented in this work was conducted under industrial conditions on a population of 10.000 pistons. Quality control data, production parameters, as well as the micro- and macro-structures of the cast iron inserts, and the interface area between the inserts and the silumin piston, were analyzed. Material and technological solutions have been proposed to reduce the occurrence of casting defects at the insert-piston joint. This includes the introduction of so-called "morphological correctors" of the -Al5FeSi phases, reducing the possibility of gaseous impurities in the AS9 alloy and optimizing the temperature of the alfin alloy.
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Authors and Affiliations

M. Szucki
1
ORCID: ORCID
J. Piątkowski
2
ORCID: ORCID
M. Czerepak
3

  1. Foundry Institute, Technische Universität Bergakademie Freiberg, Bernhard-von-Cotta-Str. 4,09599 Freiberg, Germany
  2. Department of Material Technologies, Silesian University of Technology, Krasińskiego 8, 40-019 Katowice, Poland
  3. Federal-Mogul Gorzyce sp. z o.o., Odlewników 52, 39-432 Gorzyce, Poland
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Abstract

Production of defect free castings requires good understanding of casting characteristics like mold filling ability and volume deficit characteristic. Pin test piece with cylindrical cores proposed by Engler and Ellerbrok was used to study the mold filling ability. Volume deficit characteristics experiments were conducted using the method designed by Engler. Alloy composition, Mold coat and Pouring temperature were considered as process parameters for the present study and experimental plan has been taken up through design of experiments. The alloy composition is most significant in influencing the mold filling ability, where as pouring temperature is for volume deficit. The Correlation Co-efficient value obtained is -0.98901 indicating strong a negative relation between mold filling ability and volume deficit characteristics. Negative values indicate a relationship between mold filling ability and volume deficit such that as values for mold filling ability increase, for volume deficit decrease.

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Authors and Affiliations

S. Santhi
S. Vadayar
S. Srinivasan
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Abstract

This paper presents the results of hypoeutectic 226 grade alloy as well as prepared on its basis Al-Si alloy containing Cr, V and Mo. The

additives tested were added as AlCr15, AlV10 and AlMo8 master alloys. Alloys tested were poured into DTA sampler as well as using

pressure die casting. An amount of Cr, V and Mo additives in alloy poured into DTA sampler comprised within the range approximately

0.05-0.35%. Alloys to pressure die casting contained 0.05-0.20% Cr, V and Mo. The crystallization process was examined using the derivative

thermal analysis (DTA). The microstructure of castings made in the DTA sampler as well as castings made with use of pressure die

casting were examined. The basic mechanical properties of castings made using pressure die casting were defined too. It has been shown

in the DTA curves of Al-Si alloy containing approximately 0.30 and 0.35% Cr, Mo, and V there is an additional thermal effect probably

caused by a peritectic crystallization of intermetallic phases containing the aforementioned additives. These phases have a morphology

similar to the walled and a relatively large size. The analogous phases also occur in pressure die casting alloys containing 0.10% or more

additions of Cr, V and Mo. The appearance of these phases in pressure die casting Al-Si alloys coincides with a decrease in the value of

the tensile strength Rm and the elongation A. It has been shown die castings made of Al-Si alloys containing the aforementioned additives

have a higher Rm and A than 226 alloy.

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Authors and Affiliations

G. Gumienny
T. Szymczak
T. Pacyniak
I. Stasiak
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Abstract

In the dissertation it has been shown, that so called „time-thermal treatment” (TTT) of the alloy in liquid state, as overheating the metal

with around 250o

C above the Tliq. and detaining it in this temperature for around 30 minutes, improves the mechanical properties (HB, Rm,

R0,2). It was ascertained, that overheating the AlSi17Cu5Mg alloy aids the modification, resulting with microcrystalline structure. Uniform

arrangement of the Si primeval crystals in the warp, and α(Al) solution type, supersaturated with alloying elements present in the base

content (Cu, Mg) assures not only increased durability in the ambient temperature, but also at elevated temperature (250o

C), what is an

advantage, especially due to the use in car industry.

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Authors and Affiliations

J. Piątkowski
P. Kamiński
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Abstract

The study presents the results of the application of a statistical analysis for the evaluation of the effect of high-melting additions introduced into a pressure cast Al-Si alloy on the obtained level of its proof stress Rp0.2. The base Al-Si alloy used for the tests was a typical alloy used for pressure casting grade EN AC-46000. The base alloy was enriched with high-melting additions, such as: Cr, Mo, V and W. The additions were introduced into the base Al-Si alloy in all the possible combinations. The content of the particular high-melting addition in the Al-Si alloy was within the scope of 0.05 to 0.50%. The investigations were performed on both the base alloy and alloy with the high-melting element additions. Within the implementation of the studies, the values of Rp0.2 were determined for all the considered chemical compositions of the Al-Si alloy. A database was created for the statistical analysis, containing the independent variables (chemical composition data) and dependent variables (examined Rp0.2 values). The performed statistical analysis aimed at determining whether the examined high-melting additions had a significant effect on the level of Rp0.2 of the Al-Si alloy as well as optimizing their contents in order to obtain the highest values of the Al-Si alloy's proof stress Rp0.2. The analyses showed that each considered high-melting addition introduced into the Al-Si alloy in a proper amount can cause an increase of the proof stress Rp0.2 of the alloy, and the optimal content of each examined high-melting addition in respect of the highest obtained value of Rp0.2 equals 0.05%.
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Authors and Affiliations

J. Szymszal
G. Gumienny
T. Szymczak
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Abstract

Nowadays, the most popular production method for manufacturing high quality casts of aluminium alloys is the hot and cold chamber die casting. Die casts made of hypereutectoid silumin Silafont 36 AlSi9Mg are used for construction elements in the automotive industry. The influence of the metal input and circulating scrap proportion on porosity and mechanical properties of the cast has been examined and the results have been shown in this article. A little porosity in samples has not influenced the details strength and the addition of the circulating scrap has contributed to the growth of the maximum tensile force. Introducing 80% of the circulating scrap has caused great porosity which led to reduce the strength of the detail. The proportion of 40% of the metal input and 60% of the circulating scrap is a configuration safe for the details quality in terms of porosity and mechanical strength.

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Authors and Affiliations

P. Schlafka
A.W. Bydałek
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Abstract

The paper presents the results of studies on the effect of the AlSi17Cu5 alloy overheating to atemperature of 920°C and modification with phosphorus (CuP10) on the resultingmechanical (HB, Rm, R0.2) and plastic (A5 and Z) properties. It has been shown that, so-called, "timethermal treatment" (TTT) of an alloy in the liquid state, consisting inoverheating the metal to about 250°C above Tliq,holding at this temperature by 30 minutes improvesthe mechanical properties. It has also been found that overheating of alloy above Tliq.enhances the process of modification, resulting in the formation of fine-grain structure. The primary silicon crystals uniformly distributed in the eutectic and characteristics ofthe α(Al) solution supersaturated with alloying elements present in the starting alloy composition (Cu, Fe) provide not only an increase of strength at ambient temperature but also at elevated temperature (250°C).
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Authors and Affiliations

J. Piątkowski
M. Jabłońska
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Abstract

The paper presents the results of the application of a statistical analysis to evaluate the effect of the chemical composition of the die casting Al-Si alloys on its basic mechanical properties. The examinations were performed on the hypoeutectic Al-Si alloy type EN AC-46000 and, created on its basis, a multi-component Al-Si alloy containing high-melting additions Cr, Mo, W and V. The additions were introduced into the base Al-Si alloy in different combinations and amounts (from 0,05% to 0,50%). The tensile strength Rm; the proof stress Rp0,2; the unit elongation A and the hardness HB of the examined Al-Si alloys were determined. The data analysis and the selection of Al-Si alloy samples without the Cr, Mo, W and V additions were presented; a database containing the independent variables (Al-Si alloy's chemical composition) and dependent variables (Rm; Rp0,2; A and HB) for all the considered variants of Al-Si alloy composition was constructed. Additionally, an analysis was made of the effect of the Al-Si alloy's component elements on the obtained mechanical properties, with a special consideration of the high-melting additions Cr, Mo, V and W. For the optimization of the content of these additions in the Al-Si alloy, the dependent variables were standardized and treated jointly. The statistical tools were mainly the multivariate backward stepwise regression and linear correlation analysis and the analysis of variance ANOVA. The statistical analysis showed that the most advantageous effect on the jointly treated mechanical properties is obtained with the amount of the Cr, Mo, V and W additions of 0,05 to 0,10%.

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Authors and Affiliations

J. Szymszal
G. Gumienny
T. Szymczak
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Abstract

This article presents a study of the crystallization and microstructure of the AlSi9 alloy (EN AC-AlSi9) used for the alfin processing of iron ring supports in castings of silumin pistons. Alfin processing in brief is based on submerging an iron casting in an Al-Si bath, maintaining it there for a defined time period, placing it in a chill mould casting machine and immersing it in the alloy. This technology is used for iron ring supports in the pistons of internal combustion engines, among others. Thermal analysis shows that when the AlSi9 alloy contains a minimal content of iron, nucleation and increase in the triple (Al)+Fe+(Si) eutectic containing the -Al8Fe2Si phase takes place at the end of the crystallization of the double (Al)+(Si) eutectic. Due to the morphology of the ”Chinese script” the -Al8Fe2Si phase is beneficial and does not reduce the alloy’s brittleness. After approx. 5 hours of alfin processing, the -Al5FeSi phase crystallizes as a component of the +Al5FeSi+(Si) eutectic. Its disadvantageous morphology is ”platelike” with sharp corners, and in a microsection of the surface, ”needles” with pointed corners are visible, with increases the fragility of the AlSi9 alloys.

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Authors and Affiliations

J. Piątkowski
ORCID: ORCID
M. Czerepak
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Abstract

This work deals with the characterization of structure, magnetic and mechanical properties of (FeNiCo)100-x(AlSi)x (x = 0, 5, 10, 15, 25) multicomponent alloys prepared by casting. The results of X-ray diffraction measurements, scanning electron microscopy observations and hardness and magnetic properties investigations are presented. The studies show that cast (FeNiCo)100-x(AlSi)x alloys reveal dendritic morphology and their phase composition depends on (Al + Si) content. For x ≤ 10 a face-centered cubic phase is observed, while the increase of Al and Si content results in a body-centered cubic phase formation. It leads to a fivefold increase of hardness from 88 HV to 526 HV. The investigated alloys have high magnetic induction reaching 170 emu/g, while their coercivity value is even up to 2.9 kA/m for x = 15, and strongly depends on chemical and phase composition.
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Authors and Affiliations

B. Kurowski
1
ORCID: ORCID
D. Oleszak
1
ORCID: ORCID

  1. Warsaw University of Technology, Faculty of Materials Science and Engineering, Woloska Str. 141, 02-507 Warsaw, Poland
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Abstract

The paper concerns the problem of discontinuity in high pressure die castings (HPDC). The compactness of their structure is not perfect, as

it is sometimes believed. The discontinuities present in these castings are the porosity as follow: shrinkage and gas (hydrogen and gas-air

occlusions) origin. The mixed gas and shrinkage nature of porosity makes it difficult to identify and indicate the dominant source. The

selected parameters of metallurgical quality of AlSi9Cu3 alloy before and after refining and the gravity castings samples (as DI - density

index method), were tested and evaluated. This alloy was served to cast the test casting by HPDC method. The penetrating testing (PT) and

metallographic study of both kinds of castings were realized. The application of the NF&S simulation system allowed virtually to indicate

the porosity zones at risk of a particular type in gravity and high-pressure-die-castings. The comparing of these results with the experiment

allowed to conclude about NF&S models validation. The validity of hypotheses concerning the mechanisms of formation and development

of porosity in HPDC casting were also analyzed.

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Authors and Affiliations

Z. Ignaszak
J. Hajkowski
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Abstract

The impact of casting conditions on microstructure a and mechanical properties was described, especially for cast products from AlSi9Cu3 alloy. Particular attention was paid to the parameters of dendritic structure: DAS 1 and DAS 2. Selected mechanical properties (by static tension test) of test castings made using basic technologies of casting: GSC - gravity sand casting, GDC - gravity die-casting and HPDC - high-pressure die-casting, are presented for cast-on test bars and cast separately. Casts were made of the same alloy AlSi9Cu3. Fractures and the zone near the fracture (after static tension test) was subjected to VT - visual tests, PT - penetration tests and metallographic tests. The condition of porosity (fracture zone) was also assessed. The analysis of virtual results was performed using the NovaFlow & Solid system together with the database and they were compared to experimental tests. This way of validation was applied in order to assess the correlation between the local rate of cooling and the size of DAS for GSC, GDC and HPDC technologies. Finally, the correlation between the parameters of structure and mechanical properties with regard to the impact of porosity was signalized.

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Authors and Affiliations

J. Hajkowski
Z. Ignaszak

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