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Abstract

In this study, the corrosion properties of Ti-6Mo-6V-5Cr-3Sn-2.5Zr alloy were investigated as a function of the cold rolling ratio and annealing temperature. The annealing treatment was carried out at temperature of 680°C, 730°C, and 780°C. The highest corrosion potential observed in the specimen with a 10% rolling ratio was 179 mV, which was more positive than that of the non-rolled specimen (–0.214 Vssc). The lowest corrosion current density (1.30×10–8 A/cm2) was observed in the non-rolled specimen which suggested that the integrity of its passive oxide layer was superior to that of the cold-rolled specimens. Time-dependent EIS evaluation revealed that the consistency of the passive oxide layer was highly affected by the subjected rolling ratio over time.

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Authors and Affiliations

Hocheol Song
Ahmad Zakiyuddin
Sinhye Kim
Kwangmin Lee
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Abstract

The tribological behavior of the PVD-TiAlN coated carbide inserts in dry sliding against two-phase (α-β) titanium alloy,Ti6Al4V grade, was investigated. A modified pin-on-disc device was used to conduct experiments under variable normal load and sliding speed. Scanning electron microscopy (SEM) and X-ray micro-analyses by EDS were applied for observations of wear scars and wear products. It was revealed that the increase of sliding speed contributes to decreasing the friction coefficient under a low normal force, whereas the increase of the normal loading causes the friction coefficient is less sensitive to changes in the sliding speed and its values are equal to μ = 0.26-0.34. The adhesive nature of wear along with severe abrasive action of the Ti alloy were documented.

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Authors and Affiliations

Wit Grzesik
Joanna Małecka
Zbigniew Zalisz
Krzysztof Żak
Piotr Niesłony
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Abstract

The present research investigates the nitriding kinetics of the near-beta-titanium alloy of Ti-Al-Nb-Fe-Zr-Mo-V system at 750, 800, and 850°C in gaseous nitrogen at 10 5 Pa for 2, 4, and 8 h. The parabolic coefficient kp of the layer’s growth rate and the nitriding activation energy E are set as the kinetic parameters of the nitrided layer’s growth. The activation energy for the formation of a nitride layer is ~108 kJ/mol. The authors discuss the morphology of the nitride layers as well as their roughness and surface hardness. The study determines the effective diffusion coefficient for the growth of diffusion layers in the temperature range of 750...850°C: Def = D0 × exp (– E/RT), where D0 = 0.0177 m 2/s; E = 215.7 kJ/mol. The friction coefficient of the disk from near-beta-titanium alloy with a bronze block is lowered by significantly more than 10 times after gas nitriding, and the temperature in the friction zone is reduced by 2.5 times.
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Authors and Affiliations

A.G. Luk’yanenko
1
ORCID: ORCID
I.M. Pohrelyuk
1
ORCID: ORCID
V.M. Fedirko
1
ORCID: ORCID
A.G. Molyar
2
V.S. Trush
1
ORCID: ORCID
T.M. Kravchyshyn
1

  1. G.V. Karpenko Physico-Mechanics Institute of the NAS of Ukraine, Department of Material Science Bases of Surface Engineering, 5, Naukova Str., 79060 Lviv, Ukraine
  2. G.V. Kurdyumov Institute for Metal Physics of the NAS of Ukraine, Department of Physics of Strength and Ductility of Inhomogeneous Alloys,36 Academician Vernadsky Boulevard, 03142 Kyiv, Ukraine

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