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Number of results: 31
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Abstract

This article discusses issues related to continuous casting of brass. The tested material was CuZn39Pb2 brass with the use of continuous casting and different parameters of the process. The position consists of a melting furnace with a graphite refining pot of about 4000 cm3 chuting capacity, a graphite crystallizer of 9,5 mm nominal diameter, a primary and secondary cooling system and an extracting system as well. The analysis was carried out in terms of technological parameters of the process and type of charge. Highlighted: feedrate ingot, number of stops, and technological temperatures. The surface quality of the obtained ingots and the structure were analyzed. The most favorable conditions were indicated and technological recommendations indicated. They have been distinguished for ingots for plasticity and other technologies. Favorable casting conditions are low feed and low temperature. Due to the presence of impurities coming from the charge it is disadvantageous to have Ni greater than 0.053% by mass, and Fe more than 0.075% by mass. It is recommended to maintain a high zinc content in the melt which is associated with non-overheating of the metal during casting and earlier melting.

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Authors and Affiliations

P. Kwaśniewski
K. Najman
W. Wołczyński
A.W. Bydałek
P. Schlafka
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Abstract

In this paper results of microstructural observations for series of CuZn39Pb2 alloys produced from qualified scraps are presented. The individual alloy melts were differentiated in terms of thermal parameters of continuous casting as well as refining methods and modifications. Structural observations performed by SEM and TEM revealed formation of different types of intermetallic phases including “hard particles”. EDS results show that “hard particles” are enrich in silicon, phosphorus, iron, chromium and nickel elements. Additionally, formation of Al-Fe-Si and Al-Cr in alloy melts was observed as well. It was found that quantity and morphology of intermetallic phases strongly depends upon the chemical composition of raw materials, process parameters, modifiers and refining procedure applied during casting. It was observed that refining process results in very effective refinement of intermetallic phases, whereas modifiers, particularly carbon-based, results in formation of large particles in the microstructure.

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Authors and Affiliations

A.W. Bydałek
A. Kula
L. Błaż
K. Najman
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Abstract

The temperature of liquid steel for continuous casting determines the casting speed and cooling conditions. The failure to meet the required casting process parameters may result in obtaining slabs of inconsistent quality. Numerical methods allow for real processes to be modelled. There are professional computer programs on the market, so the results of the simulations allow us to understand the processes that occur during casting and solidification of a slab. The study attempts to evaluate the impact of the superheat temperature on the slab structure based on the industrial operating parameters of the continuous casting machine.

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Authors and Affiliations

P. Drożdż
ORCID: ORCID
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Abstract

The presented results of investigations are part of a larger study focused on the optimization of the flow and mixing of liquid steel in the industrial tundish of continuous casting machine. The numerical simulations were carried out concern the analysis of hydrodynamic conditions of liquid steel flow in a tundish operating in one of the national steelworks. Numerical simulations were performed using the commercial code ANSYS Fluent. The research concerns two different speeds of steel casting. In real conditions, these speeds are the most commonly used in the technological process when casting two different groups of steel. As a result of computational fluid dynamics (CFD) calculations, predicted spatial distributions of velocity and liquid steel turbulence fields and residence time distribution (RTD) curves were obtained. The volume fractions of different flows occurring in the tundish were also calculated. The results of the research allowed a detailed analysis of the influence of casting speed on the formation of hydrodynamic conditions prevailing in the reactor.

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Authors and Affiliations

M. Warzecha
T. Merder
P. Warzecha
A.M. Hutny
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Abstract

The paper presents the research results of horizontal continuous casting of ingots of aluminium alloy containing 2% wt. silicon (AlSi2).

Together with the casting velocity (velocity of ingot movement) we considered the influence of electromagnetic stirring in the area of the

continuous casting mould on refinement of the ingot’s primary structure and their selected mechanical properties, i.e. tensile strength, yield

strength, hardness and elongation. The effect of primary structure refinement and mechanical properties obtained by electromagnetic

stirring was compared with refinement obtained by using traditional inoculation, which consists in introducing additives, i.e. Ti, B and Sr,

to the metal bath. On the basis of the obtained results we confirmed that inoculation done by electromagnetic stirring in the range of the

continuous casting mould guarantees improved mechanical properties and also decreases the negative influence of casting velocity, thus

increasing the structure of AlSi2 continuous ingots.

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Authors and Affiliations

J. Szajnar
M. Stawarz
D. Bartocha
T. Wróbel
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Abstract

In paper is presented results of studies concerning ingot of Al with a purity of 99.5% cast with use of stand of horizontal continuous

casting. Mainly together with casting velocity was considered influence of electromagnetic stirrer, which was placed in continuous casting

mould on refinement of ingots structure and theirs usability to plastic deformation. Effect of structure refinement and usability to plastic

deformation obtained by influence of electromagnetic stirring was compared with refinement obtained by use of traditional inoculation,

which consists in introducing of additives i.e. Ti and B to metal bath. On the basis of obtained results was affirmed that inoculation

realized by electromagnetic stirring in range of continuous casting mould guarantees improvement in structure refinement and usability to

rolling of pure Al continuous ingots.

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Authors and Affiliations

J. Szajnar
D. Bartocha
T. Wróbel
M. Stawarz
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Abstract

There has been a growing interest in the peritectic due to increasing productivity, quality, and alloy development. Differential scanning calorimetry (DSC) has traditionally been used to study steel solidification but suffers significant limitations when measuring the solidus and peritectic. This work covers a new thermal analysis system that can characterize the peritectic reaction. Heats of AISI/SAE 1030 and 4130 steel were poured to provide some benchmarking of this new technique. The peritectic was detected and the reaction temperature measured. Measurements agree reasonably well with reference information. A review of the literature and thermodynamic calculations did find some disagreement on the exact temperatures for the peritectic and solidus. Some of this difference appears to be related to the experimental techniques employed. It was determined that the system developed accurately indicates these reaction temperatures. The system provides a unique method for examining steel solidification that can be employed on the melt deck.

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Authors and Affiliations

R.B. Tuttle
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Abstract

The paper presents the research results of the influence of the precipitation hardening on hardness and microstructure of selected Al-Si and Al-Cu alloys obtained as 30 mm ingots in a horizontal continuous casting process. The ingots were heat treated in process of precipitation hardening i.e. supersaturation with subsequent accelerated or natural ageing. Moreover in the range of the study it has been carried out investigations of chemical constitution, microscopic metallographic with use of scanning electron microscope with EDS analysis system, and hardness measurements using the Brinell method. On basis of obtained results it has been concluded that the chemical constitution of the investigated alloys enables to classify them into Al alloys for the plastic deformation as EN AW-AlSi2Mn (alternatively cast alloy EN AC-AlSi2MgTi) and as EN AW-AlCu4MgSi (alternatively cast alloy EN AC-AlCu4MgTi) grades. Moreover in result of applied precipitation hardening has resulted in the precipitation from a supersaturated solid solution of dispersive particles of secondary phases rich in alloying element i.e. Si and Cu respectively. In consequence it has been obtained increase in hardness in case of AlSi2Mn alloy by approximately 30% and in case of AlCu4MgSi alloy by approximately 20% in comparison to the as-cast state of continuous ingots.
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Authors and Affiliations

T. Wróbel
P.M. Nuckowski
P. Jurczyk
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Abstract

In paper is presented idea of construction and influence of selected parts of stand of horizontal continuous casting on quality of pure Al and AlSi2

alloy ingots. The main parts of the made stand belong to induction furnace, which is also tundish, water cooled continuous casting mould, system

of recooling, system of continuous ingot drawing and cutting. Mainly was considered influence of electromagnetic stirrer, which was placed

in continuous casting mould on refinement of ingots structure. Effect of structure refinement obtained by influence of electromagnetic stirring was

compared with refinement obtained by use of traditional inoculation, which consists in introducing of additives i.e. Ti and B to metal bath. The

results of studies show possibility of effective refinement of Al and AlSi2 alloy primary structure, only with use of horizontal electromagnetic field

and without necessity of application of inoculants. This method of inoculation is important, because inoculants decrease the degree of purity

and electrical conductivity of pure aluminum and moreover are reason of point cracks formation during rolling of ingots.

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Authors and Affiliations

J. Szajnar
D. Bartocha
T. Wróbel
M. Stawarz
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Abstract

As in many thermal processing technologies, there is a delicate balance between productivity and quality during ingot cooling process. Higher cooling velocities increase productivity but also create higher temperature gradients inside the ingot. Such a fast cooling does not leave sufficient time to establish the equilibrium within the solid, thus the final metal structure is strongly affected by the set up cooling mode throughout the liquid metal solidification. The first intention in this paper is to compare between three cooling modes in order to identify the required mode for a continuous casting process. Then, we study the influence of heat transfer coefficient on metal liquid-to-solid transition through the spray-cooled zone temperature and the metal latent heat of solidification. A gray iron continuous casting process subjected to water-sprays cooling was simulated using the commercial software for modeling and simulating multiphysics and engineering problems. The primary conclusions, from the obtained results, show the forcefulness of water spray cooling regarding standard cooling. Afterward, we highlight the great influence of heat transfer coefficient on the location of transition region as well as the relationship between heat transfer coefficient, wall outer temperature, latent heat dissipation, and the solidification time.

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Authors and Affiliations

Hocine Mzad
Abdessalam Otmani
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Abstract

Whereas approximately 96.3% of the steel produced worldwide is made by continuous casting, great emphasis is put on the superior efficiency of this process. The water model of the tundish and mathematical modeling is often used for the simulation of the steel flow during continuous casting. The experiments were performed on a model of the tundish with two outlets, at two casting speeds (0.8 m.s–1 and 1.2 m.s–1). Eight setups of the tundish were evaluated, which differed in the design of the dams (with or without drainage holes), in their distance from the center of the tundish, and their height. The contribution of the work is the analysis of phenomena in the tundish water model in conditions of repeatability (ten repetitions). The goal is to find the setup providing the most symmetrical flow, with the minimum difference in the residence times Δτ on the two outlets. Taking into account the results obtained at both casting speeds, the most preferred is setup 2 with the 87 mm high dams placed 587 mm from the center of tundish (Δτ = 0.5). The setup 3 (Δτ = 8.25) appears to be the least appropriate. The higher the casting speed, the higher the number of unsuitable arrangements.
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Authors and Affiliations

P. Blaško
1
ORCID: ORCID
B. Bulko
1
ORCID: ORCID
J. Petrík
1
ORCID: ORCID
P. Demeter
1
ORCID: ORCID
V. Socha
2
ORCID: ORCID
L. Hanáková
2
ORCID: ORCID
P. Palfy
1
ORCID: ORCID
M. Solc
1
ORCID: ORCID
A. Vasilňáková
1
ORCID: ORCID

  1. Technical University of Košice, Faculty of Materials, Metallurgy and Recycling, Letná 9, 04 001 Košice, Slovakia
  2. Czech Technical University in Prague, Faculty of Transportation Sciences, Horská 3, 128 00 Prague, Czech Republic
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Abstract

The paper presents the results of research aimed at developing assumptions for the preparation of a charge in the form of fine scrap copper alloys (chips/shells) guaranteeing effective removal of impurities and obtaining a metal bath of the required metallurgical quality. The tests were conducted for tin-zinc-lead bronze of the CC499K grade. As part of the work, the characteristics of this type of waste available on the market were made in terms of quality and the possibility of their use for the production of both alloys and finished products, taking into account the elimination of harmful impurities that may ultimately affect the production process adversely.
The subject of the work was the selection of appropriate waste cleaning methods in the form of an oily shell in the CC499K (CuZn5Sn5Pb2) grade and its drying in terms of increasing the use of impure waste from machining as scrap for direct melting. The waste was assessed in relation to individual parametres. The research was carried out on 3 groups of waste, with varying degrees of moisture.
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Authors and Affiliations

W. Malec
1
ORCID: ORCID
B. Cwolek
1
ORCID: ORCID
A. Brudny
1
ORCID: ORCID
J. Kulasa
1
ORCID: ORCID
W. Marek
2
K. Stolorz
2
D. Wróbel
2
A. Filipowicz
2

  1. Łukasiewicz Research Network - Institute of Non-Ferrous Metals, Poland
  2. COGNOR S.A. Oddział OM Szopienice w Katowicach, Poland
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Abstract

The mold temperature of the downward continuous unidirectional solidification (CUS) cannot be controlled higher than the liquidus of alloys to be cast. Therefore, the continuous casting speed becomes the main parameter for controlling the growth of columnar crystal structure of the alloy. In this paper, the tin bronze alloy was prepared by the downward CUS process. The microstructure evolution of the CUS tin bronze alloy at different continuous casting speeds was analysed. In order to further explain the columnar crystal evolution, a relation between the growth rate of columnar crystal and the continuous casting speed during the CUS process was built. The results show that the CUS tin bronze alloy mainly consists of columnar crystals and equiaxed crystals when the casting speed is low. As the continuous casting speed increases, the equiaxed crystals begin to disappear. The diameter of the columnar crystal increases with the continuous casting speed increasing and the number of columnar crystal decreases. The growth rate of columnar crystal increases with increasing of the continuous casting speed during CUS tin bronze alloy process.

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Authors and Affiliations

Jihui Luo
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Abstract

This paper presents a numerical model for the horizontal continuous casting of cast iron (HCCCI). A computational three-dimensional (3D) steady-state, coupled with fluid flow and heat transfer simulation model was developed and validated against experimental results to study the shell thickness and solidification of ductile cast iron. The study introduces the influence of an air gap at the melt-mould interface, which has long been known to have a detrimental effect on the efficiency of the process. The effect of the length and thickness of the melt-mould air gaps (also referred to as top air gaps) on solidification and remelting of the solid strand is studied. Parametric studies on top air gaps suggested a substantial effect on the solid and eutectic area at the top-outlet end of the die when the length of air gas was varied. This study serves to create a foundational and working model with the overall objective of process optimisation and analyzing the effect of operating process input parameters on the shell thickness of the strand.
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Authors and Affiliations

A. Chawla
1
ORCID: ORCID
N.S. Tiedje
1
ORCID: ORCID
J. Spangenberg
1
ORCID: ORCID

  1. Technical University of Denmark, Denmark
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Abstract

The copper and copper alloys’ ingots have been subjected to structural observation in order to estimate the Peclet Number at which these ingots were solidifying. It was stated that the formation of columnar structure within the ingots occurred at a high Peclet Number, higher than the threshold value of this parameter, Pe = 500. The formulated relationships of the Growth Law correspond to a high Peclet Number due to application of the adequate development in series of the Ivantsov’s function. The Growth Law has been developed on the basis of the definition of the wavelength of perturbation which leads to the dispersion of the planar s/l interface. New definition of the index of stability connected with the behavior of solute concentration at the s/l interface has been delivered. The current definition is related to non-equilibrium solidification. The index can be easily calculated using some parameters delivered by a given Cu-X phase diagram. Physical meaning of the formulated Growth Law has also been presented.
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Authors and Affiliations

P. Kwapisiński
1
ORCID: ORCID
W. Wołczyński
2
ORCID: ORCID

  1. KGHM Polska Miedź S.A., ul. M. Skłodowskiej-Curie 48, 59-301 Lubin, Polska
  2. Institute of Metallurgy and Materials Sciences PAS, Reymonta St. 25, 30-059 Kraków, Poland
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Abstract

The paper evaluates two approaches of numerical modelling of solidification of continuously cast steel billets by finite element method, namely by the numerical modelling under the Steady-State Thermal Conditions, and by the numerical modelling with the Traveling Boundary Conditions. In the paper, the 3D drawing of the geometry, the preparation of computational mesh, the definition of boundary conditions and also the definition of thermo-physical properties of materials in relation to the expected results are discussed. The effect of thermo-physical properties on the computation of central porosity in billet is also mentioned. In conclusion, the advantages and disadvantages of two described approaches are listed and the direction of the next research in the prediction of temperature field in continuously cast billets is also outlined.
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Authors and Affiliations

M. Tkadlečková
K. Michalek
M. Strouhalová
M. Saternus
T. Merder
J. Pieprzyca
J. Sviželová
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Abstract

Based on the mould temperature measured by thermocouples during slab continuous casting, a difference of temperature thermograph is developed to detect slab cracks. In order to detect abnormal temperature region caused by longitudinal crack, the suspicious regions are extracted and divided by virtue of computer image processing algorithms, such as threshold segmentation, connected region judgement and boundary tracing. The abnormal regions are then determined and labeled with the eight connected component labeling algorithm. The boundary of abnormal region is also extracted to depict characteristics of longitudinal crack. Based on above researches, longitudinal crack with abnormal temperature region can be detected and is different from other abnormalities. Four samples of temperature drop are picked up to compare with longitudinal crack on the abnormal region formation, length, width, shape, et al. The results show that the abnormal region caused by longitudinal crack has a linear and vertical shape. The height of abnormal region is more than the width obviously. The ratio of height to width is usually larger than that of other temperature drop regions. This method provides a visual and easy way to detect longitudinal crack and other abnormities. Meanwhile it has a positive meaning to the intelligent and visual mould monitoring system of continuous casting.
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Authors and Affiliations

Y. Liu
Y. Gao
X. Wang
Y. Sun
Du F.
F. Wang
J. Wang
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Abstract

Determining the boundary conditions of heat transfer in steel manufacturing is a very important issue. The heat transfer effect during contact of two solid bodies occurs in the continuous casting steel process. The temperature fields of solids taking part in heat transfer are described by the Fourier equation. The boundary conditions of heat transfer must be determined to get an accurate solution to the heat conduction equation. The heat flux between the tool and the object processed depends mainly on temperature, pressure and time. It is very difficult and complicated to accomplish direct identification and determination of the boundary conditions in this process. The solution to this problem may be the construction of a process model, performing measurements at a test stand, and using numerical methods. The proposed model must be verified on the basis of parameters which can easily be measured in industrial processes. One of them is temperature, which may be used in inverse methods to determine the heat transfer coefficient. This work presents the methodology for determining the heat flux between two solid bodies staying in contact. It consists of two stages – the experiment and the numerical computation. The problem was solved by using the finite element method (FEM) and a numerical program developed at AGH University of Science and Technology in Krakow. The findings of the conducted research are relationships describing the value of the heat flux versus the contact time and surface temperature.

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Authors and Affiliations

M. Rywotycki
Z. Malinowski
K. Sołek
J. Falkus
K. Miłkowska-Piszczek
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Abstract

In this paper, the mathematical model and numerical simulations of the molten steel flow by the submerged entry nozzle and the filling process of the continuous casting mould cavity are presented. In the mathematical model, the temperature fields were obtained by solving the energy equation, while the velocity fields were calculated by solving the momentum equations and the continuity equation. These equations contain the turbulent viscosity which is found by solving two additional transport equations for the turbulent kinetic energy and its rate of dissipation. In the numerical simulations, coupling of the thermal and fluid flow phenomena by changes in the thermophysical parameters of alloy depending on the temperature has been taken into consideration. This problem (2D) was solved by using the finite element method. Numerical simulations of filling the continuous casting mould cavity were performed for two variants of liquid metal pouring. The effect of the cases of pouring the continuous casting mould on the velocity fields and the solid phase growth kinetics in the process of filling the continuous casting mould was evaluated as these magnitudes have an influence on the high quality of the continuous cast steel slab.

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Authors and Affiliations

L. Sowa
T. Skrzypczak
P. Kwiatoń
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Abstract

Investigation of the tensile and fatigue properties of cast magnesium alloys, created by the heated mold continuous casting process (HMC),

was conducted. The mechanical properties of the Mg-HMC alloys were overall higher than those for the Mg alloys, made by the

conventional gravity casting process (GC), and especially excellent mechanical properties were obtained for the Mg97Y2Zn1

-HMC alloy.

This was because of the fine-grained structure composed of the -Mg phases with the interdendritic LPSO phase. Such mechanical

properties were similar levels to those for conventional cast aluminum alloy (Al84.7Si10.5Cu2.5Fe1.3Zn1 alloys: ADC12), made by the GC

process. Moreover, the tensile properties (UTS and f

) and fatigue properties of the Mg97Y2Zn1

-HMC alloy were about 1.5 times higher

than that for the commercial Mg90Al9Zn1

-GC alloy (AZ91). The high correlation rate between tensile properties and fatigue strength

(endurance limit: l

) was obtained. With newly proposed etching technique, the residual stress in the Mg97Y2Zn1 alloy could be revealed,

and it appeared that the high internal stress was severely accumulated in and around the long-period stacking-order phases (LPSO). This

was made during the solidification process due to the different shrinkage rate between α-Mg and LPSO. In this etching technique, microcracks

were observed on the sample surface, and amount of micro-cracks (density) could be a parameter to determine the severity of the

internal stress, i.e., a large amount to micro-cracks is caused by the high internal stress.

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Authors and Affiliations

M. Okayasu
S. Wu
T. Tanimoto
S. Takeuchi
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Abstract

Detailed studies of the movement of liquid steel (hydrodynamics) on a real object are practically impossible. The solution to this problem are physical modelling carried out on water models and numerical modelling using appropriate programs. The method of numerical modelling thanks to the considerable computing power of modern computers gives the possibility of solving very complex problems.

The paper presents the results of model tests of liquid flow through tundish. The examined object was model of the twonozzle tundish model. The ANSYS Fluent program was used to describe the behavior of liquid in the working area of the tundish model. Numerical simulations were carried out using two numerical methods of turbulence description: RANS (Reynolds-Averaged Navier-Stokes) – model k-ε and LES (Large Eddy Simulation). The results obtained from CFD calculations were compared with the results obtained using the water model.

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Authors and Affiliations

T. Merder
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Abstract

The article presents the results of investigations performed on segregation of elements in the billets. The research were performed under standard industrial conditions, during high carbon steel production cycle. Probes (templates with the thickness of 20 mm) were taken from billets with square cross-section of 160 mm. Segregation of elements was determined based on the quantitative analysis of results performed by using spark spectrometry pursuant to PN-H-04045. Changes in concentrations of elements were analysed along two cross-sections. Element contents were performed at points distanced from each other by approx. 10 mm. The segregation of carbon, sulphur and phosphorus was determined for different billets.

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Authors and Affiliations

A.M. Hutny
M. Warzecha
P. Wieczorek
W. Derda
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Abstract

The article presents tests on a new lead-free bronze CuSn4Zn2PS, intended for fittings for contact with drinking water, in which the addition of lead was replaced with sulphur. The subject of the experimental work was the production of semi-finished products from this alloy based on the charge coming entirely from waste generated after machining. A specialized pilot line was used for the tests, and after cleaning, the waste was melted and then were continuously cast in the form of rods and hollow rods. The cleaning efficiency was assessed, and the manufactured semi-finished products were subjected to tests, including the assessment of the chemical and mechanical homogeneity and the structure of the test batch of the semi-finished casting products in terms of the possibility of manufacturing products meeting the requirements of technical specifications. The obtained results, both in terms of a stable chemical composition, homogeneous and reproducible mechanical properties, fully compliant with the specifications for fittings bronzes (CC499K), as well as the lack of faults of the obtained semi-finished products, despite a very large share of waste material, indicate the possibility of using the tested recycling method for the production of semi-products of sulphur bronze, which is an alloy that is relatively difficult to manufacture.
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Bibliography

[1] Directive (EU) 2020/2184 of the European Parliament and of the Council of 16 December 2020 on the quality of water intended for human consumption, Dz.U.L 435/1 of 23.12.2020.
[2] Acceptance of metallic materials used for products in contact with drinking water, 4MS Common Approach Part B “4MS Common Composition List” Retrieved July, 12, 2022 from http://www.umweltbundesamt.de/en/topics/water/drinking-water/distributing-drinking-water/guidelines-evaluation-criteria.
[3] DIN SPEC 2701:2018.
[4] Haake, M., Hansen, A., Leistritz, F. (2019). EP Patent No. EP 3436615. Germany. The German Patent and Trade Mark Office.
[5] PN-EN 1982:2017 Copper and copper alloys - Ingots and castings
[6] Wieland G05, GD1, GS1, SW3 material specification. Retrieved 12, July, 2022 from https://www.wieland.com/en/content/download/.
[7] Marek, W., Kopańska, D., Bieniek, J., Wróbel, D., Stolorz, K., Filipowicz, A., Malec, W., Cwolek, B., Brudny, A., Juszczyk B., Kulasa, J. (2022). PL Patent application No. PL 436188. Poland. The Patent Office of the Republic of Poland.
[8] Cwolek, B., Malec, W., Brudny, A., Kulasa, J., Marek, W., Stolorz, K., Wróbel, D. & Filipowicz, A. (2022). Development of process conditions for the preparation of copper alloys post-production chips for the continuous casting process. Archives of Foundry Engineering. (in publication).
[9] PN-EN 12861:2018-07 Copper and copper alloys – Scrap.
[10] Hansen, A. (2019). Bleifreier rotguss als armaturen-und installationswerkstoff in der trinkwasserinstallation. METALL – Forschung. 73(11), 452-455.

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Authors and Affiliations

W. Malec
1
ORCID: ORCID
B. Cwolek
1
ORCID: ORCID
A. Brudny
1
ORCID: ORCID
B. Juszczyk
1
ORCID: ORCID
J. Kulasa
1
ORCID: ORCID
A. Hury
1
ORCID: ORCID
W. Marek
2
K. Stolorz
2
D. Wróbel
2
A. Filipowicz
2

  1. Łukasiewicz Research Network — Institute of Non-Ferrous Metals, Poland
  2. COGNOR S.A. Oddział OM Szopienice w Katowicach, Poland

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