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Number of results: 6
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Abstract

As a result of experimental data processing, the ratio of alloying elements Кγ' was proposed for the first time, which can be used to assess the mechanical properties, taking into account the complex effect of the main alloy components. The regularities of the influence of the composition on the properties of heat-resistant nickel alloys of equiaxial crystallization are established. It is shown that for multicomponent nickel systems it is possible with a high probability to predict a mismatch, which significantly affects the strength characteristics of alloys of this class. A promising and effective direction in solving the problem of predicting the main characteristics of heat-resistant materials based on nickel is shown.
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Authors and Affiliations

A.A. Glotka
1
ORCID: ORCID
V.E. Ol’shanetskii
1
ORCID: ORCID

  1. Zaporizhzhia Polytechnic National University, Ukraine, Zaporizhzhia, st. Zhukovskogo, 64, 69063
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Abstract

Paper presents the results of evaluation of heat resistance and specific heat capacity of MAR-M-200, MAR-M-247 and Rene 80 nickel

superalloys. Heat resistance was evaluated using cyclic method. Every cycle included heating in 1100°C for 23 hours and cooling for 1

hour in air. Microstructure of the scale was observed using electron microscope. Specific heat capacity was measured using DSC

calorimeter. It was found that under conditions of cyclically changing temperature alloy MAR-M-247 exhibits highest heat resistance.

Formed oxide scale is heterophasic mixture of alloying elements, under which an internal oxidation zone was present. MAR-M-200 alloy

has higher specific heat capacity compared to MAR-M-247. For tested alloys in the temperature range from 550°C to 800°C precipitation

processes (γ′, γ′′) are probably occurring, resulting in a sudden increase in the observed heat capacity.

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Authors and Affiliations

R. Przeliorz
M. Góral
P. Gradoń
F. Binczyk
T. Mikuszewski
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Abstract

Operating conditions turbocharger (high temperature and corrosive environment) mean that the device is classified into one of the most elements of the emergency drive unit of the car. The failure rate can be reduced through the use of modern heat-resistant materials, which include based alloys FeAl intermetallic phase. Intermetallic alloys belong to the group of materials known as prospective due to their advantageous properties, in particular their high specific strength, high melting point and good resistance to corrosion and oxidation at high temperatures. In the article presented results of the research axis roll control system variable geometry blades made of intermetallic alloy Fe40Al5Cr0,2TiB as a substitute so far made of austenitic steel. A verification service conditions, comparing the degradation of the material previously used by manufacturers of turbochargers for elements of the control system degradation axes made of intermetallic alloy Fe40Al5Cr0,2TiB. The study consisted of determining microstructure and corrosion products after use. Observations of the structure and the surface of the corrosion tests were performed using light microscopy, scanning electron microscopy and X-ray microanalysis EDS chemical composition.

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Authors and Affiliations

J. Cebulski
D. Pasek
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Abstract

The austenitic stainless steels are a group of alloys normally used under high mechanical and thermal requests, in which high temperature oxidation is normally present due to oxygen presence. This study examines the oxide layer evolution for Fe24Cr12NiXNb modified austenitic stainless steel A297 HH with 0,09%Nb and 0,77%Nb content at 900°C under atmospheric air and isothermal oxidation. The modifiers elements such as Mo, Co and Ti, added to provide high mechanical strength, varied due to the casting procedure, however main elements such as Cr, Ni, Mn and Si were kept at balanced levels to avoid microstructure changing. The oxide layer analysis was performed by confocal laser scanning microscopy (CLS) and scanning electron microscopy (SEM). The elemental analysis of the different phases was measured with energy dispersive X-ray spectroscopy (EDX). The Nb-alloyed steel generated a thicker Cr oxide layer. Generally elemental Nb did not provide any noticeable difference in oxide scale growth, for the specific range of Nb amount and temperature studied. High temperature oxidation up to 120h was characterized by protective Cr oxidation, after this period a non-protective Fe-based oxidation took place. Cr, Fe and Ni oxides were observed in the multilayer oxide scale.
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Bibliography

[1] Abbasi, M., Park, I., Ro, Y., Ji, Y., Ayer, R. & Shim, J.H. (2019). G-phase formation in twenty-years aged heat-resistant cast austenitic steel reformer tube. Materials Characterization. 148, 297-306. DOI: 10.1016/j.matchar. 2019.01.003.
[2] Madern, N., Monnier, J., Baddour-Hadjean, R., Steckmeyer, A. & Joubert, J.M. (2018). Characterization of refractory steel oxidation at high temperature. Corrosion Science. 132, 223-233. DOI: 10.1016/j.corsci.2017.12.029.
[3] Kondrat’ev, S.Y., Kraposhin, V.S., Anastasiadi, G.P. & Talis, A.L. (2015). Experimental observation and crystallographic description of M7C3 carbide transformation in Fe-Cr-Ni-C HP type alloy. Acta Materialia. 100, 275-281. DOI: 10.1016/j.actamat.2015.08.056.
[4] Dewar, M.P. & Gerlich, A.P. (2013). Correlation between experimental and calculated phase fractions in aged 20Cr32Ni1Nb austenitic stainless steels containing nitrogen . Metallurgical and Materials Transactions A. 44, 627-639. DOI: 10.1007/s11661-012-1457-1.
[5] Pascal, C., Braccini, M., Parry, V., Fedorova, E., Mantel, M., Oquab, D. & Monceau, D. (2017). Relation between microstructure induced by oxidation and room-temperature mechanical properties of the thermally grown oxide scales on austenitic stainless steels. Materials Characterization. 127, 161-170. DOI: 10.1016/j.matchar.2017.03.003.
[6] Chen, H., Wang, H., Sun, Q., Long, C., Wei, T., Kim, S.H., Chen, J., Kim, C., & Jang, C. (2018). Oxidation behavior of Fe-20Cr-25Ni-Nb austenitic stainless steel in high-temperature environment with small amount of water vapor. Corrosion Science. 145, 90-99. DOI: 10.1016/j.corsci. 2018.09.016.
[7] Zhang, X., Li, D., Li, Y. & Lu, S. (2019). Effect of aging treatment on the microstructures and mechanical properties evolution of 25Cr-20Ni austenitic stainless steel weldments with different Nb contents. Journal of Materials Science & Technology. 35, 520-529. DOI: 10.1016/j.jmst.2018.10.017.
[8] Birks, N., Meier, G.H. & Pettit, F.S. (2006). Introduction to the high temperature oxidation of metals, Second edition. Cambridge University Press. DOI: 10.1017/ CBO9781139163903.
[9] Li, D.S., Dai, Q.X., Cheng, X.N., Wang, R.R. & Huang, Y. (2012). High-temperature oxidation resistance of austenitic stainless steel Cr18Ni11Cu3Al3MnNb. Journal of Iron Steel Research International. 19, 74-78. DOI: 10.1016/S1006-706X(12)60103-4.
[10] Kaya, A.A. (2002). Microstructure of HK40 alloy after high-temperature service in oxidizing/carburizing environment: II. Carburization and carbide transformations. Materials Characterization. 49, 23-34. DOI: 10.1016/S1044-5803(02)00284-X.
[11] Li, H., Zhang, B., Jiang, Z., Zhang, S., Feng, H., Han, P., Dong, N., Zhang, W., Li, G., Fan, G. & Lin, Q. (2016). A new insight into high-temperature oxidation mechanism of super-austenitic stainless steel S32654 in air. Journal of Alloys and Compounds. 686, 326-338. DOI: 10.1016/j.jallcom.2016.06.023.
[12] M. Salehi Doolabi, B. Ghasemi, S.K. Sadrnezhaad, A. Feizabadi, A. HabibollahZadeh, D. Salehi Doolabi, M. AsadiZarch. (2017). Comparison of Isothermal with cyclic oxidation behavior of “Cr-Aluminide” coating on inconel 738LC at 900 °C. Oxidation of Metals. 87, 57-74. DOI: 10.1007/s11085-016-9657-5.
[13] De Almeida, L.H., Ribeiro, A.F. & Le May, I. (2002). Microstructural characterization of modified 25Cr-35Ni centrifugally cast steel furnace tubes. Materials Characterization. 49, 219-229. DOI: 10.1016/S1044-5803(03)00013-5.
[14] Nishimoto, K., Saida, K., Inui, M. & Takahashi, M. (2001). Changes in microstructure of HP-modified, heat-resisting cast alloys under long-term aging. Repair weld cracking of service-exposed, HP-modified, heat-resisting cast alloys (2nd report). Welding International. 15(7), 509-517. DOI: 10.1080/ 09507110109549397.
[15] Joubert, J.M., St-Fleur, W., Sarthou, J., Steckmeyer, A. & Fournier, B. (2014). Equilibrium characterization and thermodynamic calculations on highly alloyed refractory steels. Calphad Comput. Coupling Phase Diagrams Thermochem. 46, 55-61. DOI: 10.1016/j.calphad. 2014.02.002.
[16] Ramos, P.A., Coelho, R.S., Pinto, H.C., Soldera, F., Mücklich, F. & Brito, P. (2021). Microstructure and cyclic oxidation behavior of modified Nb-alloyed A297 HH refractory austenitic stainless steel. Materials Chemistry and Physics. 263, 124361. DOI: 10.1016/j.matchemphys. 2021.124361.
[17] Ramos, P.A., Coelho, R.S., Soldera, F., Pinto, H.C., Mücklich, F. & Brito,P. (2020). Residual stress analysis in thermally grown oxide scales developed on Nb-alloyed refractory austenitic stainless steels. Corrosion Science. 178, 109066. DOI: 10.1016/j.corsci.2020.109066.
[18] McCafferty E. (2010). Introduction to corrosion science. Springer Science & Business Media. DOI: 10.1007/978-1-4419-0455-3.

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Authors and Affiliations

P.A. Ramos
1 2
R.S. Coelho
3
H.C. Pinto
4
F. Soldera
5
F. Mücklich
5
P.P. Brito
1

  1. Pontifical Catholic University of Minas Gerais, Brazil
  2. Federal Institute of Science and Technology of Minas Gerais, Brazil
  3. SENAI CIMATEC, Institute of Innovation for Forming and Joining of Materials, Av. Orlando Gomes, 1845, Piatã, 41650-010, Salvador-BA, Brazil
  4. Department of Materials Engineering - SMM, São Carlos School of Engineering – EESC, University of São Paulo – USP, São Carlos, SP, Brazil
  5. Chair of Functional Materials, Department of Materials Science, Saarland University, 66123, Saarbrücken, Saarland, Germany
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Abstract

High-temperature plastic properties of heat-resistant stainless steel X15CrNiSi 20-12 were assessed on the basis of hot tensile tests and nil strength tests. The results were supported by metallographic analyses using SEM and EDX analysis. The formability of the investigated steel can be divided into roughly three temperature areas. In the temperature range of 900°C to about 1050°C, formability was negatively affected by precipitation of carbide particles at grain boundaries. As the temperature rose to 1200°C, these particles dissolved, resulting in an increase in formability. Further temperature increases resulted in a relatively steep drop in formability caused by overheating of the material. The nil ductility temperature of 1280°C and the nil-strength temperature of 1362°C were determined. The Plastic and strength properties of the investigated material were compared with the deformation behavior of the reference steel X5CrNi 18-10, which shows a significantly wider range of suitable forming temperatures.

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Authors and Affiliations

R. Kawulok
ORCID: ORCID
I. Schindler
ORCID: ORCID
H. Navrátil
ORCID: ORCID
V. Ševčák
J. Sojka
K. Konečná
ORCID: ORCID
B. Chmiel
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Abstract

The paper presents FEM approach for comparative analyses of wall connections applied in cast grates used for charge transport in furnaces for heat and thermal-chemical treatment. Nine variants of wall connection were compared in term of temperature differences arising during cooling process and stresses caused by the differences. The presented comparative methodology consists of two steps. In first, the calculations of heat flow during cooling in oil for analysed constructions were carried out. As a result the temperature distributions vs cooling time in cross-sections of analysed wall connections were determined. In the second step, based on heat flow analyses, calculations of stresses caused by the temperature gradient in the wall connections were performed. The conducted calculations were used to evaluate an impact of thermal nodes reduction on maximum temperature differences and to quantitative comparison of various base design of the cast grate wall connection in term of level of thermal stresses and their distribution during cooling process. The obtained results clearly show which solution of wall connection should be applied in cast grate used for charge transport in real constructions and which of them should be avoided because the risk of high thermal stresses forming during cooling process.
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Bibliography

[1] Lai, G.Y. (2007). High-Temperature Corrosion and Materials Applications. ASM International.
[2] Davis, J.R. (Ed.). (1997). Industrial Applications of HeatResistant Materials. In Davis, J.R. (Eds.), ASM Specialty Handbook - Heat-Resistant Materials (pp. 67-85). ASM International.
[3] Piekarski, B. (2012). Creep-resistant castings used in heat treatment furnaces. Szczecin: West Pomeranian University of Technology Publishing House. (in Polish).
[4] Ul-Hamid et al. (2006). Failure analysis of furnace tubes exposed to excessive temperature. Engineering Failure Analysis. 13(6), 1005-1021. DOI: 10.1016/j.engfailanal.2005.04.003.
[5] Reihani, A., Razavi, S.A., Abbasi, E. et al. (2013). Failure Analysis of welded radiant tubes made of cast heat-resisting steel. Journal of failure Analysis and Prevention. 13, 658–665. DOI: https://doi.org/10.1007/s11668-013-9741-y.
[6] Piekarski, B. (2010). Damage of heat-resistant castings in a carburizing furnace. Engineering Failure Analysis. 17(1), 143-149. DOI: 10.1016/j.engfailanal.2009.04.011.
[7] Nandwana, D., et al. (2010). Design, Finite Element analysis and optimization of HRC trays used in heat treatment process. In World Congress on Engineering 2010, June 30 - July 2, 2010 (pp. 1149-1154). London, U.K.: Newswood Limited.
[8] Sandeep, K., Ajit, K. & Mahesh, N.S. (2012). Improving productivity in a heat treatment shop for piston Pins. SASTECH Journal. 11(2), 38-46.
[9] Standard PN-EN 10295: 2004. Heat resistant steel castings.
[10] Bajwoluk, A. & Gutowski, P. (2019). Thermal stresses in the accessories of heat treatment furnaces vs cooling kinetics. Archives of Foundry Engineering. 19(3), 88-93, DOI: 10.24425/afe.2019.127146.
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Authors and Affiliations

A. Bajwoluk
1
ORCID: ORCID
P. Gutowski
1
ORCID: ORCID

  1. Mechanical Engineering Faculty, West Pomeranian University of Technology, Szczecin, Al. Piastów 19, 70-310 Szczecin, Polska

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