Setting time in geopolymers is known as the time taken for the transition phase of liquid to solid of the geopolymer system in which is represented in the initial setting and final setting. Setting time is significant specifically for application in the construction field. This study intends to determine the setting time of high calcium fly ash geopolymers and the properties of the geopolymers after setting (1-day age). This includes the determination of heat evolved throughout geopolymerization using Differential Scanning Calorimeter. After setting properties determination includes compressive strength and morphology analysis at 1-day age. High calcium fly ash was used as geopolymer precursor. Meanwhile, for mixing design, the alkali activator was a mixture of sodium silicate and sodium hydroxide (concentration varied from 6M-14M) with a ratio of 2.5 and a solid-to-liquid ratio of 2.5. From this study, it was found that high calcium fly ash geopolymer with 12M of NaOH has a reasonable setting time which is suitable for on-site application as well as an optimal heat evolved (–212 J/g) which leads to the highest compressive strength at 1-day age and no formation of microcracks observed on the morphology. Beyond 12M, too much heat evolved in the geopolymer system can cause micro-cracks formation thus lowering the compressive strength at 1-day age.

An attempt was made in the present work to study the compressive strength and microstructure of geopolymer containing high calcium fly ash (HCFA) and silica fume. Concentration of sodium hydroxide solution 8M, 10M, 12M & 14M, liquid to binder ratio 0.5 and sodium hydroxide to sodium silicate ratio 2.5 were selected for the mixes. Geopolymer mortar test results indicated that the mix with 40% silica fume by the weight of HCFA yielded higher compressive strength under ambient curing. The XRD pattern typically shows the major portion of amorphous phase of geopolymer. The existence of C-A-S-H gel, N-A-S-H gel and hydroxysodalite gel products were observed through SEM which developed dense microstructure and thus enhanced strength of HCFA and silica fume geopolymer.