The hierarchical structure of InSe<β-CD<FeSO₄>> composition with 4-fold grade expansion was synthesized with the intercalation-deintercalation technique. Electrical properties of the structure obtained were examined using impedance and thermostimulated current spectroscopy methods. Influence of temperature, static magnetic field and illumination on electrical properties of the synthesized compound was investigated. Changes in the impurity spectrum of the expanded hierarchical structure were analyzed and extraordinary magneto- and photoimpedance behavior of InSe<β-CD<FeSO₄>> at room temperature was explained.

In this work, we present findings on the syntheses and study of properties of InSe<PTHQ> nanohybrid. The introduction of guest component in GaSe matrix leads to an increase in inhomogeneities, which is clearly confirmed by the strengthening of the low-frequency horizontal branch of Nyquist diagrams. A constant magnetic field counteracts this effect and changes the behavior of the impedance hodograph at low frequencies to the opposite. Illumination leads to a colossal increase in quantum capacitance, which is clearly demonstrated in the Nyquist diagram. For the synthesized InSe<PTHQ> nanohybrid the interesting behavior of the current-voltage characteristic is reported. As a result of studies of the synthesized InSe<PTHQ> nanohybrid the effect of “negative capacity” is observed, the magnitude of which can be controlled by the electric field. Based on the constructed impedance model and proposed N-barrier model, the physical mechanisms of the investigated processes are suggested.