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Abstract

Microalloying elements such as Ti, Nb, V, entered into steel they influence their microstructure and mechanical properties, because formation of carbonitrides, M(C,N). Influence of carbonitrides to the microstructure and mechanical properties depends on their basic stereological parameters: volume fraction, Vv, and their size, r. In this work the Cellular Automata model of the kinetics of the carbonitrides precipitation which enable to predict the image of the microstructure and calculate the size of carbonitrides formed during isothermal annealing of supersaturated steel is presented. In the high temperature the microalloying elements inhibit the austenite grains growth. Chemical composition of steel has influence to volume fraction and size of precipitations. The work is supplemented with examples of experimental comparison.
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Authors and Affiliations

Przemysław Marynowski
ORCID: ORCID
Marcin Hojny

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Abstract

The microalloying elements such as Nb, V are added to control the microstructure and mechanical properties of microalloyed (HSLA) steels. High chemical affinity of these elements for interstitials (N, C) results in precipitation of binary compound, nitrides and carbides and products of their mutual solubility – carbonitrides. The chemical composition of austenite, as well as the content and geometric parameters of undissolved precipitates inhibiting the growth of austenite grains is important for predicting the microstructure, and thus the mechanical properties of the material. Proper selection of the chemical composition of the steel makes it possible to achieve the required properties of the steel at the lowest possible manufacturing cost. The developed numerical model of carbonitrides precipitation process was used to simulate and predict the mechanical properties of HSLA steels. The effect of Nb and V content to change the yield strength of these steels was described. Some comparison with literature was done.
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Bibliography

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Authors and Affiliations

Przemysław Marynowski
1
ORCID: ORCID
Marcin Hojny
1
Tomasz Dębiński
1
ORCID: ORCID

  1. AGH University of Krakow, Poland
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Abstract

The paper addresses the macro- and microsegregation of alloying elements in the new-developed Mn-Al TRIP steels, which belong to the third generation of advanced high-strength steels (AHSS) used in the automotive industry. The segregation behaviour both in the as-cast state and after hot forging was assessed in the macro scale by OES and by EDS measurements in different structural constituents. The structural investigations were carried out using light and scanning electron microscopy. A special attention was paid to the effect of Nb microaddition on the structure and the segregation of alloying elements. The tendency of Mn and Al to macrosegregation was found. It is difficult to remove in Nb-free steels. Microsegregation of Mn and Al between austenite and ferritic structural constituents can be removed.

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Authors and Affiliations

A. Grajcar
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Abstract

A problem is defined to investigate the effect of titanium traces on the corrosion behaviour of low carbon steel. In theory titanium effects surface properties like abrasion resistance in medium carbon steels and corrosion resistance in low as well as medium carbon steels. The present research as indicated by the topic is aimed to experimentally mark the effect of titanium traces on corrosion resistance in the available low carbon steel specimens.
The effect of microalloying with titanium (i.e.0.02wt.%) on the corrosion behavior of low carbon steel in a 3.5 wt.% NaCl solution was studied by electrochemical, SEM, and Raman spectroscopy techniques. The electrochemical results showed that the corrosion of the Ti-bearing steel improved by around 30% compared with the Ti-free steel. The titanium microalloying led to the formation of a more compact corrosion product layer on the metal surface. The SEM analysis showed that the Ti-bearing sample had a smoother surface compared with the Ti-free steel.
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Bibliography

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Authors and Affiliations

Ali R. Sheikh
1
ORCID: ORCID

  1. AGH University of Science and Technology, Kraków, Poland
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Abstract

Innovative procedure of microalloying continuous cast aluminum strip, thickness 10 mm, by Be, Zr and Mn using 3C Pechiney technology (no. 39762, P-377/76), and modifying the existing parameters for strip casting and crystallization was implemented under industrial conditions with two randomly selected batches 2×8 tones, without previous selection of standardized quality of aluminum, purity Al 99.5%, obtained by electrolysis. The application of microalloying and overall structural modification of the technology resulted in obtaining nanoscale, ultra-thin, compact oxide high-gloss film with uniform surface of continuous cast strip, instead of the usual thick and porous oxide film. The outcome of microalloying the obtained equiaxed fine-grained nano/micro structure was avoiding anisotropic and dendritic microstructure of the strip, and improving deformation and plastic properties of modified continuous cast strip subjected to the technology of plastic treatment by rolling until the desired foil thickness of 9 μm was obtained. The invention of microalloying and structural modification, including multiplying effect of several components, directly or indirectly, changed numerous structurally-sensitive properties. The obtained nano/micro structure of crystal grains with equiaxed structure resulted in the synergy of undesirable <111> and inevitable <100> and <110> textures. Numerous properties were significantly enhanced: elastic modulus was improved, and intensive presence of cracks in warm forming condition was prevented due to rapid increase of the number of grains to 10000 grains/cm2 in as-cast state.
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Authors and Affiliations

M.M. Purenović
1
J.M. Purenović
2
J.Č. Baralić
2

  1. University of Niš, Faculty of Sciences and Mathematics, Serbian Academy of Inventors and Scientists, Serbia
  2. University of Kragujevac, Faculty of Technical Sciences Cacak, Department of Physics and Materials, Serbia

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