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Abstract

Nano technology is an emerging field of interest for civil engineering application. Among the nano materials presently used in concrete, nano-silica possess more pozzolanic nature. It has the capability to react with the free lime during the cement hydration and forms additional C-S-H gel giving strength, impermeability and durability to concrete. Present paper investigates the effects of addition of nano silica in normal strength concrete. Three types of nano-silica in the form of nano suspension having different amount of silica content have been investigated. Mix design has been carried out by using particle packing method. X-Ray diffraction (XRD) analysis has been carried out to find the chemical composition of control concrete and nano modified concrete. Further, experimental investigations have been carried out to characterize the mechanical behaviour in compression, tension and flexure. It has been observed that the addition of nano-silica in normal strength concrete increased the compressive strength and decreased the spilt tensile strength and flexural strength. Also, Rapid chloride permeability test (RCPT) has been conducted to know the chloride permeability of control concrete, nano modified concrete, and nano coated concrete. It has been observed that the chloride permeability is less for nano coated concrete.

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Authors and Affiliations

S. Gopinath
P.Ch. Mouli
A.R. Murthy
N.R. Iyer
S. Maheswaran
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Abstract

The mechanical properties of cement paste modified by nano-TiO2 (nT) and nano-SiO2 (nS) were experimentally studied. The compressive strength increased first and then decreased with the increase of nanoparticle content. When nanoparticles were added into the cement paste as a filler to improve the microstructure, the two kinds of particles both could form a tighter mesh structure, which would enhance the density and strength of the structure. The elastic modulus increased rapidly with the increase of the nT content and reached a peak when the nanoparticle content is about 3%, which was about twice the elastic modulus of ordinary cement paste. The Scanning electron microscopy (SEM) observation results showed that the microstructure of cement was network connection and fiber tube. The hydration progress of ordinary cement slurry was insufficient, and many unreacted cement particles remained. With the addition of nanoparticles, the internal structure of the cement became denser, with fewer pore cracks, smaller pore diameters, more complex fiber tube arrangements, and significant anisotropy, thereby improving strength and mechanical properties.

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Authors and Affiliations

Zhi Wang
Wenjing Qin
Lijuan Zhang

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