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Abstract

The exothermic insulating riser played an important role in the solidification process of metal liquid for the improvement of casting quality. This paper focused on the use of organosilicon slag to replace part of the aluminum powder as an exothermic agent for the riser, to reduce production costs and turn waste into treasure. The experiments firstly studied the effect of organosilicon slag content on the combustion temperature and holding time and determined the components of the riser exothermic agent and organosilicon slag. On this basis, the effects of the content of Na3AlF6 flux and alkali phenolic resin binder on the combustion heating time and strength properties of the riser were studied. And the ratio of mixed oxidants was determined by single-factor orthogonal experiments to optimize the addition of three oxidants, Fe3O4, MnO2, and KNO3. Finally, the performance of the riser prepared after optimization was compared with that of the riser prepared with general aluminum powder. The results showed that with the mixture of 21% organosilicon slag and 14% aluminum powder as the exothermic agent, the highest combustion temperature of the prepared exothermic insulating riser was 1451℃ and the holding time was 193 s; the optimal content of Na3AlF6 flux was 4%, and the best addition alkali phenolic resin binder was 12%; the optimized mixing ratio of three oxidants was 12% for Fe3O4, 6% for MnO2, and 6% for KNO3. Under the optimized ratio, the maximum combustion temperature of the homemade riser was 52℃ and the heat preservation time was 14% longer compared with the conventional exothermic insulating riser with 25-35% aluminum powder.
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Authors and Affiliations

Jijun Lu
1
ORCID: ORCID
Jiangbing Qian
1
ORCID: ORCID
Lei Yang
1
ORCID: ORCID
Huafang Wang
1
ORCID: ORCID

  1. School of Mechanical Engineering and Automation, Wuhan Textile University, China
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Abstract

Iron black commonly employs in thermal insulation riser sleeves due to its ability to react with aluminum powder, generating heat. However, the complex production process and unstable composition of iron black lead to high production costs. The potential of using arc furnace flue ash (AFFA) as a complete substitute for iron black and MnO2 and KNO3 oxidizing agents in conventional riser sleeves was investigated in this study. Waste material can be transformed into a valuable resource, while production costs can be reduced by utilizing arc furnace flue ash. The research examined the impact of varying types and amounts of arc furnace flue ash on riser sleeve temperature and holding time by conducting single-factor and orthogonal optimization experiments. The orthogonal optimization experiment determined that the optimum ratio of each oxidant was 6 % arc flue ash, 3 % MnO2 and 6 % KNO3. At this time, the highest temperature was 1512 ℃ and the holding time was 244 s. Results indicated that different types of arc furnace flue ash used as an oxidizing agent demonstrated superior holding capacity and heat generation performance compared to iron black. Additionally, a comparative analysis of factory casting experiments using ductile iron 600-3 (IS) revealed that both arc furnace flue ash and iron black risers effectively countered shrinkage. However, arc furnace flue ash risers exhibited improved mechanical properties, as evidenced by the hardness of the castings.
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Bibliography

[1] Lu, J.J., Qian, J.B., Yang, L. & Wang, H.F. (2023). Preparation and performance optimization of organosilicon slag exothermic insulating riser. Archives of Foundry Engineering. 23(1), 75-82. DOI: 10.24425/afe.2023.144283.
[2] Vasková, I., Conev, M. & Hrubovčáková, M. (2017). The influence of using different types of risers or chills on shrinkage production for different wall thickness for material EN-GJS-400-18LT. Archives of Foundry Engineering. 17(2), 131-136. DOI: 10.1515/afe-2017-0064.
[3] Sowa, L., Skrzypczak, T. & Kwiatoń, P. (2019). The influence of riser shape on feeding effectiveness of solidifying casting. Archives of Foundry Engineering. 19(4), 91-94. DOI: 10.24425/afe.2019.129636.
[4] Krajewski, P.K., Gradowski, A. & Krajewski, W.K. (2013). Heat exchange in the system mould - riser - ambient. part ii: surface heat emission from open riser to ambient. Archives of Metallurgy and Materials. 58(4), 1149-1153. DOI: 10.2478/amm-2013-0140.
[5] Xu, X. Hui,G,D. Ma, B, H . et al. (2017). Research on high efficiency heat insulation risers for casting. Casting technology. 38(03), 726-728. (in Chinese).
[6] Zhang, S.L., Wu, B., Qin, Z.G.,et al .(2010). Ignition temperature of 2Al/Fe2O3 aluminum thermite. Energy Containing Materials. 18(02), 162-166. (in Chinese).
[7] Duan, W. H., Li, G., Zu. C.S., et al (2017). Control of critical characteristics of heat-insulating riser sleeves and countermeasures for application problems. China Casting Equipment and Technology, 2017(06), 20-24. (in Chinese).
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[9] Chen, J. (2022). Application of steelmaking electric arc furnace ash in sintered bricks[J]. Brick and Tile, 2020 (7): 25-27. DOI:10.16001/j.cnki.1001-6945.2020.07.011.
[10] Wang, J., Zhang, Y.Y., Cui, K.K., Fu. T., Gao, J.J. Shahid Hussain, Tahani Saad AlGarni. (2021). Pyrometallurgical recovery of zinc and valuable metals from electric arc furnace dust – A review. Journal of Cleaner Production. 298, 126788. DOI:10.1016/j.jclepro.2021.126788.
[11] Donald, J.R. & Pickles, C.A. (1996). Reduction of electric arc furnace dust with solid iron powder. Canadian Metallurgical Quarterly. 35(3), 255-267. DOI:10.1016/0008-4433(96)00009-2.
[12] Lin, X.L. Peng. Z.W., Yan. J.X., Li. Z., Z. Hwang, J.Y. Zhang, Y.B., Li, G.H., Jiang, T. (2017). Pyrometallurgical recycling of electric arc furnace dust. Journal of Cleaner Production. 149, 1079-1100. DOI:10.1016/j.jclepro.2017.02.128.
[13] Abhilash T. Nair, Aneesh Mathew, Archana A R, M Abdul Akbar.(2022). Use of hazardous electric arc furnace dust in the construction industry: A cleaner production approach. Journal of Cleaner Production. 377, 134282, 0959-6526. DOI:10.1016/j.jclepro.2022.134282
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Authors and Affiliations

Junjie Zhu
1
ORCID: ORCID
Jian Feng
2
ORCID: ORCID
Ling Liu
1
ORCID: ORCID
Huafang Wang
1
ORCID: ORCID
Jijun Lu
1
ORCID: ORCID

  1. School of Mechanical Engineering and Automation, Wuhan Textile University, China
  2. CRRC Corporation Limited, China

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