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Abstract

An increasing number of municipal sewage treatment plants in Poland, desirable from an environmental perspective, raises the problem of managing the growing volume of sewage sludge. The thermal treatment of municipal sewage sludge (TTMSS) method, by greatly reducing the waste volume, increases the heavy metal concentration in fly ash (primary, end product of the treatment process), which may constitute a risk factor when attempting to utilize them economically. The research paper concentrates on determining the TTMSS fly ash heavy metal leaching level. For this purpose, ash samples were subjected to leaching with the batch and percolation tests, and the heavy metal content in eluates was determined by the FAAS method. The obtained results served as a base to determine the level of heavy metal immobilization in the ash, the element release mechanism (percolation test), and the impact of the L/S (liquid to solid) ratio and pH on the heavy metal leaching intensity (percolation test). The conducted research indicated high immobilization of heavy metals in TTMSS fly ash, regardless of the applied study method, which corresponds to the results of other researchers. Lead was the most intensively eluted metal.

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Authors and Affiliations

Łukasz Szarek
1
ORCID: ORCID

  1. Warsaw University of Technology, Poland
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Abstract

The paper discusses possible applications of the percolation theory in analysis of the microstructure images of polycrystalline materials.

Until now, practical use of this theory in metallographic studies has been an almost unprecedented practice. Observation of structures so

intricate with the help of this tool is far from the current field of its application. Due to the complexity of the problem itself, modern

computer programmes related with the image processing and analysis have been used. To enable practical implementation of the task

previously established, an original software has been created. Based on cluster analysis, it is used for the determination of percolation

phenomena in the examined materials. For comparative testing, two two-phase materials composed of phases of the same type (ADI

matrix and duplex stainless steel) were chosen. Both materials have an austenitic - ferritic structure. The result of metallographic image

analysis using a proprietary PERKOLACJA.EXE computer programme was the determination of the content of individual phases within

the examined area and of the number of clusters formed by these phases. The outcome of the study is statistical information, which

explains and helps in better understanding of the planar images and real spatial arrangement of the examined material structure. The results

obtained are expected to assist future determination of the effect that the internal structure of two-phase materials may have on a

relationship between the spatial structure and mechanical properties.

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Authors and Affiliations

W. Trzaskowski
S. Świłło
W. Sobaszek
D. Myszka

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