The article analyzes the present state of the phosphate raw material base to meet Ukrainian chemical enterprises’ needs. In Ukraine, a number of complex apatite and phosphorite deposits have been explored. Their exploitation can lead to a complete supply of Ukrainian chemical enterprises with raw materials and can partly reduce the amount of expensive imported phosphate mineral fertilizers. At present, the following deposits, where apatite is connected with other useful components, are prepared for exploitation: Stremyhorod, Fedorivka, Novopoltavka, Kropyvna and others. The advantage of the development of these deposits is the possibility to extract apatite along with the production of rare earth concentrates, ilmenite, titanomagnetite, as well as feldspars, olivine, pyroxenes, mica and others which will significantly increase the profitability of the deposits development.

The alternative to apatite-containing deposits in Ukraine can be sedimentary deposits of nodule, granular and mixed type phosphorites. Phosphorite deposits can be used mainly for the production of phosphorite and limestone flour. Considerable resources of granular phosphorites have been discovered in Volyn-Podillia and Dnieper-Donetsk which are considered to have a various agricultural effect. They are environmentally friendly ores without impurity which prevents plants from cesium, strontium and reduces nitrates in the soil. Arranging the exploration of phosphorite ores in certain parts of Volyn-Podillia basin and Dnieper-Donets Rift is recommended.

Several closely-spaced phosphorite beds stand out at the Albian–Cenomanian transition in the mid-Cretaceous transgressive succession at the northeastern margin of the Holy Cross Mountains, central Poland. They form a distinctive condensed interval of considerable stratigraphical, palaeontological, and economic value. Here, we correlate the classical section at Annopol with a recently investigated section at Chałupki. We propose a new stratigraphic interpretation of the phosphorite interval, based on lithological correlations, Rare Earth Elements and Yttrium (REE+Y) signatures of phosphorites, age-diagnostic macrofossils, and sequence stratigraphic patterns. This interval has long been considered as exclusively Albian in age. However, new macrofossil data allow us to assign the higher phosphorite levels at Annopol and Chałupki, which were the primary target for the phosphate mining, to the lower Cenomanian. In terms of sequence stratigraphy, the phosphorite interval encompasses the depositional sequence DS Al 8 and the Lowstand System Tract of the successive DS Al/Ce 1 sequence. The proposed correlation suggests that lowstand reworking during the Albian–Cenomanian boundary interval played an important role in concentrating the phosphatic clasts and nodules to exploitable stratiform accumulations. Our conclusions are pertinent to regional studies, assessments of natural resources (in view of the recent interest in REE content of the phosphorites), and dating of the fossil assemblages preserved in the phosphorite interval. On a broader scale, they add to our understanding of the formation of stratiform phosphorite deposits.

Phosphate rocks and elemental phosphorus are considered to be critical raw materials mainly because of such parameters as the growing prices of phosphate fertilizers, the high concentration of producers limited to several countries in the world, the exceptional significance of phosphorus in agriculture and the inability to substitute it.
In Poland 100% of the demand phosphate rocks relies on import. The expansion and mining of the nation’s own resource base may be an alternative to import and a way to provide safety of supplies. Historically, phosphorites from the northern margin of the Holy Cross Mountains were extracted using the underground method, which was abandoned in the beginning of the 1970s due to the unprofitability of extraction. However, in eastern and south-eastern Poland, phosphorite concretions of the Eocene age occur at shallow depths, which can have local significance as mineral deposits and might be extracted in open-pit mines. The economics of mining in shallow opencasts do not require such stringent limiting parameters for phosphate deposits as those currently valid, which were established for underground mining conditions.
In this publication, the authors analyzed contemporary conditions for a cost-effective phosphorite deposit, including the price fluctuations of phosphate rock, a review of threshold parameters of deposits for phosphorite projects in the world, and the economics of open-pit ore extraction, where an aggregate mine with mixed extraction (partially from below the water table) was adopted as a point of reference.
As a result, new threshold parameters defining an ore deposit and its boundaries are proposed for Eocene phosphorites in Poland.