The studies showed that alkaline lipase from Pseudomonas fluorescens enables an irreversible transesterification of vinyl esters to give enantiomeric excess (eeR) of about 80% using vinyl butyrate as acyl donor and diisopropyl ether as a solvent, at partially optimized conditions. For the native lipase the process was adequately described by a five-parameter Ping-Pong Bi Bi model for both enantiomers plus expression accounting for the formation of enzyme-acyl donor complex, but for the same lipase supported on mesoporous materials of SBA-15-Oc type, R-product inhibition also had to be taken into account. The use of hydrophobic support increased by more than two-fold the rate of the S-solketal conversion but even more that of R-solketal. Thus the immobilization of lipase had very positive effect on the process kinetics but decreased its enantioselectivity.

The cellular users, on high speed railways and highways, travel at a very high speed and follow a nearly straight path, in general. Thus, they typically undergo a maximum frequency of handovers in the cellular environment. This requires a very fast triggering of the handover. In the existing method of handover in 5G cellular communication, for high speed users, neither the decision-making of handover nor the triggering of handover is sufficiently fast. This can lead to poor signal quality and packet losses and in the worst case, radio link failure (RLF) during a handover. This paper proposes a forward handover based method, combined with PN sequence detections, to facilitate a quicker handover for high speed users on railways and highways. The proposed method adds some complexity but can offer a significant improvement in the overall handover delay. A simplistic simulation is used to demonstrate the improvement of the proposed method.