The paper presents the results of the pitting resistance investigations of selected stainless steels in the chloride environment and the simultaneous impact of erosive factors using the cyclic polarization technique. Additionally, using electrochemical techniques, ie: electrochemical impedance spectroscopy (EIS) and measurement of corrosion potential, the behavior of the passive layer of selected stainless steels in the environment of chlorides and erosion was examined. On the basis of the obtained results, the resistance of stainless steels 1.4301 and 1.4404 was found, both on the effect of chloride ions and erosive factors in the studied systems. Both tested steels are susceptible to pitting corrosion. It was found that a good measure of erosive impact on stainless steel is both impedance spectrum analysis and continuous monitoring of the corrosion potential of steel.

The article presents results of pitting corrosion studies of selected silicon cast irons. The range of studies included low, medium and high

silicon cast iron. The amount of alloying addition (Si) in examined cast irons was between 5 to 25 %. Experimental melts of silicon cast

irons [1-3] were conducted in Department of Foundry of Silesian University of Technology in Gliwice and pitting corrosion resistance

tests were performed in Faculty of Biomedical Engineering in Department of Biomaterials and Medical Devices Engineering of Silesian

University of Technology in Zabrze. In tests of corrosion resistance the potentiostat VoltaLab PGP201 was used. Results obtained in those

research complement the knowledge about the corrosion resistance of iron alloys with carbon containing Si alloying addition above 17 %

[4-6]. Obtained results were supplemented with metallographic examinations using scanning electron microscopy. The analysis of

chemical composition for cast irons using Leco spectrometer was done and the content of alloying element (silicon) was also determined

using the gravimetric method in the laboratory of the Institute of Welding in Gliwice. The compounds of microstructure were identify by

X-ray diffraction.

The microstructure and corrosion properties of spark plasma sintered yttria dispersed and yttria free duplex and ferritic stainless samples were studied. Spark plasma sintering (SPS) was carried out at 1000°C by applying 50 MPa pressure with holding time of 5 minutes. Linear sweep voltammetry (LSV) tests were employed to evaluate pitting corrosion resistance of the samples. Corrosion studies were carried out in 0.5, 1 and 2 M concentration of NaCl and H2SO4 solutions at different quiet time of 2, 4, 6, 8 and 10 seconds. Yttria dispersed stainless steel samples show more resistance to corrosion than yttria free stainless steel samples. Pitting potential decreases with increase in reaction time from 2 to 10 seconds. Similarly, as concentration of NaCl and H2SO4 increases from 0.5 M to 2 M the corrosion resistance decrements due to the availability of more Cl¯ and SO4 2¯ ions at higher concentration.

In the paper the results and analysis of corrosion tests were presented for low-alloyed cast steel in as-cast state and after heat treatment

operations. Such alloys are applied for heavy loaded parts manufacturing, especially for mining industry. The corrosion test were

performed in conditions of high salinity, similar to those occurring during the coal mining. The results have shown, that small changes in

chemical composition and the heat treatment influence significantly the corrosion behaviour of studied low-alloyed cast steels.

The aeronautical industry is a sector constantly looking for new materials and equipment because of its tendency to expand quickly. The Ti6Al4V titanium alloy is used frequently in the aeronautic, aerospace, automobile, chemical and medical industry because it presents high strength combined with low density (approximately 4.5 g/cm3), good creep resistance (up to 550°C), excellent corrosion resistance, high flexibility, good fatigue and biocompatibility. As a result of these properties, this titanium alloy is considered an excellent material for manufacturing structural parts in the aircraft industry for modern aeronautic structures, especially for airframes and aero-engines. But its use is also problematic because the Ti6Al4V titanium alloy manifests hydrogen embrittlement, by means of hydrides precipitation in the metal. The Ti6Al4V alloy becomes brittle and fractures because of hydrogen diffusion into metal and because titanium hydrides appear and create pressure from within the metal, thus generating corrosion. Because of titanium hydrides, the titanium alloy suffers from reduced ductility, tensile strength and toughness, which can result in fractures of aeronautical parts. This poses a very serious problem for aircrafts. In this paper, rapid hydrogen embrittlement is presented along with XRD, SEM and TEM analysis. Its goal is to detect the presence of titanium hydrides and to spot the initial cracks in the metallic material.