The behaviour of porous sinters, during compression and compression with reverse cyclic torsion tests is investigated in the article based on the combination of experimental and numerical techniques. The sinters manufactured from the Distaloy AB powder are examined. First, series of simple uniaxial compression tests were performed on samples with three different porosity volume fractions: 15, 20 and 25%. Obtained data were then used during identification procedure of the Gurson-Tvergaard-Needleman finite element based model, which can capture influence of porosity evolution on plasticity. Finally, the identified Gurson-Tvergaard- Needleman model was validated under complex compression with reverse cyclic torsion conditions and proved its good predictive capabilities. Details on both experimental and numerical investigations are presented within the paper.
The paper presents the results of preliminary studies on the properties of products made by vitrification of waste containing fly ashes from sewage sludge incineration. The performed tests of hazardous substances leached from the ashes, as well as the results of other laboratory tests confirmed the efficacy of vitrification. It has been found that the resulting products (sinters) could be used as a substitute aggregate for road foundations.
This paper discusses the mechanical properties of a material fabricated from commercially available metal powder mixtures designed for
use as a metal matrix of diamond impregnated composites. The mixtures with the catalogue numbers CSA and CSA800 provided by a
Chinese producer are suitable for experimental laboratory testing. The specimens were fabricated in a graphite mould using hot pressing.
The material was tested for density, porosity, hardness, and tensile strength under static loading. A scanning electron microscope (SEM)
was used to analyze the microstructure and cleavage fracture of broken specimens. It was essential to determine how the chemical
composition and the fabrication process affected the microstructure and properties of the material. The properties of the sinters were
compared with those of hot pressed specimens fabricated from sub-micron size cobalt powder (Cobalt SMS). Although the as-consolidated
material is inferior to cobalt, it displays a favourable combination of hardness, yield strength and ductility, and seems to have a great
potential for moderate and general purpose applications.
In this paper the development and method of production of modern, Ni-free sintered structural steels containing Cr, Mn and Mo, enabling the production of structural sintered steels in industrial conditions, using safe, with low H2-content, sintering atmospheres is presented. For this purpose, the analysis of microstructure and mechanical properties of these sintered structural steels produced in different processing conditions and also the connections between the microstructure of sintered material and its mechanical properties, was presented. Following the investigations, the appropriate chemical composition of sintered Ni-free steels with properties which are comparable or even better than those of sintered structural steels containing rich and carcinogenic nickel was choosen. Additionally, in the paper the properties of electrolitically coated carbon steels were presented, as the beginning of investigation for improving the mechanical properties of alloyed, structural sintered steels.
The paper presents the results of research on the production and application of sintered copper matrix composite reinforced with titaniumcopper intermetallic phases. Cu- Ti composites were fabricated by powder metallurgy. The starting materials for obtaining the sintered composites were commercial powders of copper and titanium. Experiments were carried out on specimens containing 2.5, 5, 7.5 and 10 % of titanium by weight. Finished powders mixtures containing appropriate quantities of titanium were subjected to single pressing with a hydraulic press at a compaction pressure of 620 MPa. Obtained samples were subjected to sintering process at 880 °C in an atmosphere of dissociated ammonia. The sintering time was 6 hours. The introduction of titanium into copper resulted in the formation of many particles containing intermetallic phases. The obtained sinters were subjected to hardness, density and electrical conductivity measurements. Observations of the microstructure on metallographic specimens made from the sintered compacts were also performed using a optical microscope. An analysis of the chemical composition (EDS) of the obtained composites was also performed using a scanning electron microscope. Microstructural investigations by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) showed that after 6 hours of sintering at 880°C intermetallic compounds: TiCu, TiCu2, TiCu4, Ti2Cu3, Ti3Cu4 were formed. The hardness increased in comparison with a sample made of pure copper whereas density and electrical conductivity decreased. The aim of this work was to fabricate copper matrix composites reinforced with titanium particles containing copper- titanium intermetallic phases using powder metallurgy technology and determine the influence of the titanium particles on the properties of the sintered compacts and, finally, analyse the potentials application for friction materials or electric motors brushes.
Electrochemical Cr coatings doped with diamond nanoparticles were deposited on sintered steels with different carbon contents (0.2-0.8 wt.-%). The mechanical properties of surfaces as hardness and wear resistance increase as compared to the steel substrate. Microcutting and microgridding mechanisms were observed after tribological tests, but also adhesive wear in some areas was observed. X-ray examination indicated that the layer was textured, with the exception of the sample with the highest concentration of diamond nanoparticles in the electrolyte (42 g/l). The intensity ratio ICr110/ICr200 was calculated and compared with the indices for a standard sample. The greatest differences in the intensity ratio occurred for the samples with low carbon content (0.2%C). On the other hand, more the material is textured the greater the difference.
The Polish basis of dolomites is remarkable. Their total reserves reported in the 62 deposits listed in current data bases of mineral resources amount to 1,500,000 t. However, there is a shortage of the so-called converter dolomites of high quality applicable in manufacturing of refractory materials. Such dolomites of the Triassic age have been quarried for many years in the Brudzowice and Ząbkowice Śląskie I deposits in the Silesian-Cracow region. The Libiąż deposit is perspective of this area, considering the character and properties of its dolomites. The dolomites of the Nowa Wioska and Stare Gliny deposits belong into the same group although their applying as refractories seems to be disputable at the moment and would require more detailed analyses of the chemical composition and firing properties of the rocks mentioned. The reason is that the dolomites of these deposits have been reported andmassively quarried up to now mainly for civil engineering (roads, buildings, etc.). Unfortunately, worsening properties of the dolomites occurring in Żelatowa, still another large and developed deposit of the region, have been excluded using these rocks in producing of refractories. Among the group of reserve converter dolomite deposits, the best rock properties have been found in four of them, i.e., Chruszczobród, Chruszczobród I, Chruszczobród II and Libiąż Wielki. The survey presented indicates that there are some possibilities of including dolomites of the Winna and, to a lesser degree, Radkowice-Podwole deposits as the raw materials in manufacturing of refractories. Again, more detailed analyses of the chemical composition and petrographical development, mainly of the grain size distribution, would be required. Dolomitic marbles of the Lower Silesia region represent a separate problem. Traditionally, they have been considered to be non-applicable in manufacturing of refractories because of too coarse grain size of these rocks. It should be stressed, however, that the Lower Silesian marbles occur in several varieties and among them also fineand coarse-grained dolomites occur. Their finest and chemically purest varieties can be an interesting option in extending the basis of refractory dolomitic raw materials in Poland, although selective quarrying would be required in such a case.
In the present paper, elemental Fe, Cr and Ni powders were used to fabricate nano-structured duplex and ferritic stainless steel powders by using high energy planetary ball milling. We have studied the effect of milling atmosphere like wet (toluene) and dry (argon) milling of elemental Fe-18Cr-13Ni (duplex) and Fe-17Cr-1Ni (ferritic) powders for 10 h in a dual drive planetary mill. Stearic acid of 1wt. % was added during milling to avoid agglomeration. The dry and wet milled duplex and ferritic stainless steel powders were characterized by XRD, SEM and particle size analysis techniques. We have found that both the milling atmospheres have great influence in controlling the final particle morphology, size and phase evolution during milling. It was reported that dry milling is more effective in reducing particle size than the wet milling. The Nelson-Riley method of extrapolation was used to calculate the precise lattice parameter and Williamson-Hall method was used to calculate the crystallite size and lattice strain of both the stainless steel milled in argon atmosphere. Dry milled duplex and ferritic stainless steel were then consolidated by conventional sintering method at 1100, 1200 and 1300°C temperatures under argon atmosphere for 1 hour.
Traditional press and sinter processes have gained in the last decades more and more importance in the manufacturing of high volume and precise mechanical components especially in the field of iron based powders. In recent years, the reductions of processing times and temperatures were spotted as critical targets to increase productivity and reduce energy consumption. Electric current assisted sintering (ECAS) technologies have always been seen as an alternative to traditional furnace based sintering techniques and have been the target of different researches with the specific purpose of reducing both operational times and costs. The aim of the present study is to investigate the effect of an innovative process called Electro Sinter Forging (ESF) applied to CuSn15 powders. Thanks to a very short processing time (less than 1 second to densify loose powders), this process is able to retain a very small grain size, thus enhancing mechanical properties of the processed materials. Furthermore, to the authors knowledge, cold – rolled electro – sinter – forged alloys has never been investigated before. First of all, bars were electro – sinter – forged and subsequently characterized in the as sinter – forged condition. The observation of microstructure evidenced an extremely fine microstructure and a reduced degree of porosity. Afterwards, bars were cold rolled after different reduction ratios; macrostructural integrity of the rolled bars was assessed before evaluating the effects of cold rolling on the sinter – forged microstructure.
In the paper the multiferroic (ferroelectric-ferromagnetic) composites based on ferroelectromagnetic/ferroelectric (BaFe1/2Nb1/2O3 (BFN)) powder and ferrite powder (zinc-nickel ferrite) were obtained by two technological methods. In the composite samples the ratio of the ferroelectromagnetic/ferroelectric powder to the magnetic powder was equal to 90:10. The ceramic powders were synthesized by the classical technological method using powder calcination/solid state synthesis, while densification of the composite powders (sintering) was carried by two different methods: (i) Free Sintering method (FS), and (ii) Spark Plasma Sintering (SPS).
At the work, a comparison of measurement results for composite samples obtained by two sintering methods was made. The studies included the following analysis: DTA, XRD, SEM, DC electrical conductivity, electric permittivity and magnetic properties. The result of measurements presented in the work revealed that the ceramic composite obtained by two different technological sintering method (classical technology – Free Sintering method and Spark Plasma Sintering technique) can be promising lead-free materials for functional applications, for example in sensors for magnetic and electric field.
The present research is focused on the characterization of the composites from Al2O3-Cu-Ni system. Two methods of ceramic-metal composite forming were applied: uniaxial powder pressing and Pulse Plasma Sintering (PPS). To obtain the samples the powder mixtures containing 85 vol.% of Al2O3 and 15 vol.% of metal powders were used. Influence of the sintering process on microstructure and mechanical properties of the two series of the composites was analyzed in detail. The selected physical properties of samples were characterized by Archimedes immersion method. Vickers hardness and the fracture toughness of the composites was determined as well. The microstructure of the composites was characterized by XRD, SEM, EDX. Fractography investigation was carried out as well. Independently on composite production method Al2O3, Cu, Ni, and CuNi phases were revealed. Fractography investigation results revealed different character of fracture in dependence of fabrication method. Pulse Plasma Sintered samples were characterized by higher crack resistance and higher Vickers hardness in comparison to the specimens manufactured by uniaxial pressing.
In this study, lead-free 0.94 Na0.5Bi0.5TiO3-0.06BaTiO3 (NBT-BT) compositions at morphotropic phase boundary were successfully synthesized by solid-state reaction method. The effects of the particle size for various milling time (12-24-48 hours) and sintering temperatures (1100-1125-1150-1175oC for 2h) on the electrical properties of the NBT-BT ceramics were evaluated. Experimental results showed that particle size and sintering temperatures significantly affect the electrical properties of NBT-BT ceramics. The particle size of the ceramic powders decreasing while milling time increases to 48 hours. Particle size values for 0, 12, 24 and 48 hours (h) milled powders were measured as nearly 1.5 µm, 1 µm, 700 nm, and 500 nm respectively. The bulk density enhanced with increasing sintering temperature and showed the highest value (5.73 g/cm3) at 1150oC for 48h milled powder. Similarly, the maximum piezoelectric constant (d33) = 105 pC/N, electromechanical coupling coefficient (kp) = 25.5% and dielectric constant (KT) = 575 were measured at 1150oC for 48 h milled powder. However, mechanical quality factor (Qm) was reduced from 350 to 175 with decreasing particle size. Similarly, remnant polarization was dropped by decreasing powder particle size from 56 μC/cm2 to 45 μC/cm2.
The sintering behavior of p-type bismuth telluride powder is investigated by means of dilatometric analysis. The alloy powders, prepared by ball milling of melt-spun ribbons, exhibit refined and flake shape. Differential thermal analysis reveals that the endothermic peak at about 280oC corresponds to the melting of bismuth, and peaks existing between 410oC and 510oC are presumably due to the oxidation and crystallization of the powder. The shrinkage behavior of ball-milled powders was strongly dependent of heating rate by the thermal effect exerted on specimens. In the case of 2oC/min, the peak temperature for the densification is measured at 406oC, while the peak temperature at a heating rate of 20oC/min is approximately 443oC. The relative density of specimen pressureless-sintered at 500oC exhibited relatively low value, and thus further study is required in order to increase the density of sintered body.