Thermodynamic equilibrium-based models of gasification process are relatively simple and widely used to predict producer gas characteristics in performance studies of energy conversion plants. However, if an unconstrained calculation of equilibrium is performed, the estimations of product gas yield and heating value are too optimistic. Therefore, reasonable assumptions have to be made in order to correct the results. This paper proposes a model of the process that can be used in case of deficiency of information and unavailability of experimental data. The model is based on free energy minimization, material and energy balances of a single zone reactor. The constraint quasi-equilibrium calculations are made using approximated amounts of non-equilibrium products, i.e. solid char, tar, CH4 and C2H4. The yields of these products are attributed to fuel characteristics and estimated using experimental results published in the literature. A genetic algorithm optimization technique is applied to find unknown parameters of the model that lead to the best match between modelled and experimental characteristics of the product gas. Finally, generic correlations are proposed and quality of modelling results is assessed in the aspect of its usefulness for performance studies of power generation plants.

Oxygen is an element that is first purposely brought into the steel melt to remove some unwanted elements or to reduce their concentration

(oxidation). In the made cast steel there is on the contrary necessary to reduce the oxygen content with the use of deoxidation to such a

level in order to avoid a reaction with carbon with the formation of CO bubbles. Concentration of oxygen in steel before casting is given,

in particular, by the manner of metallurgical processing and the used deoxidation process. Oxygen is found in molten steels both as

chemically bound in the form of oxides and in the form of oxygen dissolved in the solution – the melt. Chemical composition

of the melt strongly influences the activity of oxygen dissolved in the melt and further on the composition of oxidic inclusions forming in

the melt during the reaction with oxygen. In the Fe-C-Cr-Ni based alloys in the reaction with oxygen greatly participates also chrome,

whose products are often in solid state and they are the cause of forming such defects as e.g. oxidic films.