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Abstract

Deoxidation of steel with carbon under reduced pressure is often used for increasing the steel purity. Suitable units for this purpose in

foundries are vacuum induction furnaces. Possibilities of increasing the steel purity by deoxidation with carbon in the vacuum induction

furnace were studied for the steel for the petrochemistry of specific composition 25Cr/35Ni. The charge composed of the return material

only was melted in the air. During melting the charge oxidized and the oxidizing slag formed. Chemical composition of steel, morphology,

chemical composition of inclusions in the steel and chemical composition of slag after vacuuming were studied on the basis of samples

taken before and after vacuuming. Temperature and oxygen activity were measured before and after vacuuming. Globular inclusions with

dominant content of silicon and manganese were observed in steel before and after vacuuming. Contents of total oxygen in steel didn’t

change significantly during vacuuming. On the basis of composition of inclusions and measured oxygen activity the activity of Cr2O3

in

inclusions was calculated. A slag sample was taken after vacuuming and equilibrium oxygen activity in steel with regard to the Cr2O3

content in the slag was estimated from the slag composition. Equilibrium oxygen activity in relation to the Cr2O3 content in the slag was

higher than equilibrium activity measured in the steel. For this reason it is not possible, under the studied conditions, to decrease oxygen

content in steel during vacuuming.

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Authors and Affiliations

J. Šenberger
V. Pernica

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