Carbon dioxide (CO2) is a compound responsible for the greenhouse effect. One of the methods of CO2 capture from the gas stream is adsorption process. In this paper, the adsorption equilibrium isotherms of CO2 on zeolite 13X were measured at different temperatures (293.15 K, 303.15 K, 313.15 K, 323.15 K, 333.15 K, 348.15 K, 373.15 K, 393.15 K) and under pressures up to 2 MPa. These data were obtained using an Intelligent Gravimetric Analyzer (IGA-002, Hiden Isochema, UK). Selected multitemperature adsorption isotherm equations, namely Toth, Langmuir–Freundlich, and, Langmuir were correlated with experimental data.
Greenhouse gases such as carbon dioxide and water vapour can be captured from gas streams on a zeolite 13X adsorbent. Experimental water vapour adsorption isotherms and kinetic curves were measured in the temperature range of 293–393 K and pressure up to 2100 Pa. The equilibrium data were developed with Toth and Sips multi-temperature isotherm models. The results of the process rate studies were described using pseudo-first and pseudo-second order kinetic models. Findings were compared with our own results of CO2 adsorption studies on the same zeolite.
This paper discusses the adsorption of Direct Orange 26 azo dye on sunflower husk - an agricultural waste product. During the study, sorption kinetics and equilibrium as well as sorption capacity of the husk were investigated. The adsorption kinetics was analyzed using pseudo-first and pseudo-second order equations, which indicated a chemical sorption mechanism. The sorption equilibrium was approximated with the two-parameter Freundlich and Langmuir equations and the three-parameter Redlich-Peterson equation. The main experiments were carried out in a laboratory adsorption column under different process conditions. Experimental data were interpreted with the Thomas model, based on the volumetric flow rate, initial composition of the feed solution and mass of the adsorbent. The results of modeling the adsorption equilibrium, adsorption kinetics and adsorption dynamics were evaluated statistically.