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Abstract

The leachability of pollutants from asbestos-containing waste, previously used for roofing was investigated. Laboratory tests were performed under static conditions (tests 1–20) in accordance with the TCLP methodology (with the use of acetic acid as the leaching medium, initial pH = 3.15). The maintaining of constant leaching conditions proved to be impossible at the experimental stage. Following the stabilization of conditions, the pH range for the obtained solutions increased to an average value of 8.3. Aluminum, boron, barium, cadmium, chromium, copper, iron, nickel, lead, strontium, zinc, and mercury were identified in the eluate. The low leachability of individual metals under the planned conditions was observed. In general, no leaching of such metals as cadmium, nickel, and lead was observed. The mercury content in the eluates is below the quantification limit, but the obtained values fall to around the limit of detection for the element. As compared with leaching with the use of distilled water (Klojzy-Karczmarczyk et al. 2021), zinc and boron additionally appear in eluates. The determined value of leachability for the individual analyzed elements increases from double to a few times with the use of the TCLP method. The value of leaching for barium is on average 5.56 mg/kg, for chromium it is 1.10 mg/kg, for copper 0.26 mg/kg, and for iron 0.80 mg/kg. In addition, the leaching of boron of around 3.00 mg/kg and of zinc 1.84 mg/kg was found. Higher leachability values were found only for strontium and aluminum. The leaching of strontium is on average around 62 mg/kg. While the leaching of aluminum is lower than values identified in the previous tests with the use of distilled water and is around 2.76 mg/kg. Products of leaching contain mainly pollutants characteristic of cement (aluminum, strontium, and iron).
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Authors and Affiliations

Beata Klojzy-Karczmarczyk
1
ORCID: ORCID
Janusz Mazurek
1
ORCID: ORCID

  1. Mineral and Energy Economy Research Institute, Polish Academy of Sciences, Kraków, Poland
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Abstract

The growth of the global population, urbanization as well as economic and industrial development, affect the continuously increasing demand for mineral aggregates. The current assessed global production of mineral aggregates amounts to 50 billion Mg/year, which statistically approximates 6.5 Mg per an inhabitant of the globe. In terms of consumption volume, water is the only raw material ahead of aggregates. Despite such a great scale, in many countries and regions the extraction and production of aggregates belong to the least regulated sector of human activity. This refers particularly to the countries of A sia, A frica, and North A merica, where both the resources and the extraction of aggregates, particularly of sand and gravels, are either not monitored and registered. It significantly increases the negative impact on the natural environment, due to the destruction of riverbeds and oxbows, coastal erosion, drying up cultivation areas, etc. In the reports, local terminology of aggregates often functions, which makes it difficult to compare them and prepare appropriate balances. In order to regulate the unfavorable situation, one of the main conclusions of the Report (UNEP 2019) is the need of implementing a common requirement to plan and monitor the process of extraction of natural resources. The paper presents the possibility of forecasting the extraction and producing aggregates based on the consumption of cement, i.e. the basic building material. A lthough the analyzed coefficient of mineral aggregate production per unit of cement consumption (production) varies, its advantage is the fact that the production of cement is identified and taken into account in balances of industrial production of the majority of countries, whereas such identification for mineral aggregate production are still lacking.

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Authors and Affiliations

Ireneusz Ryszard Baic
ORCID: ORCID
Wiesław Kozioł
ORCID: ORCID
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Abstract

The asbestos removal in Poland is carried out based on the Programme of Country Cleaning from Asbestos for the Years 2009–2023. Pursuant to this document asbestos-containing materials should be removed from the territory of the whole country by the end of 2032. The pace of asbestoscontaining products removal was estimated and also the time necessary to implement this process. These figures were estimated using two resources of data. The data gathered in the Asbestos Database (Asbestos Database... 2022) were analysed, and the analysis of detailed stocktaking and its update for 20 selected communes of various nature was carried out. The pace of removing in the analysed communes is definitely diversified. The obtained values generally range from 0.28 to 6.35 kg/R/y (kg per resident/year). An averaged pace of asbestos removal for the entire country is from 2.24 to 3.65 kg/R/y, depending on the adopted method of calculations. The analysis has shown that considering the current pace of asbestos-containing products removing, these materials will not be removed from the area of Poland by the set date, i.e. by the end of 2032. In individual provinces the amount of asbestos and the pace of removal are drastically different. Retaining the current pace of asbestoscontaining products removing, such products will disappear from Poland only within 27–193 years, depending on the province. An average pace of removal, given for the country scale, allows to state that 83 years are needed for the total removal of asbestos products.
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Authors and Affiliations

Beata Klojzy-Karczmarczyk
1
ORCID: ORCID
Jarosław Staszczak
1
ORCID: ORCID

  1. Mineral and Energy Economy Research Institute, Polish Academy of Sciences, Kraków, Poland
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Abstract

Asbestos cement sheets on building roofs and façades as well as asbestos cement water and sewerage pipes are the most frequently existing elements that contain asbestos in Poland. During removal from a specific building such a material automatically becomes hazardous waste. The presented paper covers studies carried out on leachability of pollutants from asbestos-containing waste, previously used for roofing. Laboratory tests under static conditions were carried out (1:10 test, pursuant to rules of the PN-EN 12457/1-4 standard) using distilled water as the leaching medium. Aluminium, boron, barium, cadmium, chromium, copper, iron, nickel, lead, strontium, zinc, and mercury were determined in the eluate. Low leachability of individual metals under the planned conditions was observed. In general, such metals as cadmium, nickel, lead, zinc, boron and mercury were not observed in solutions. The other analysed metals were observed in eluates, but their concentrations were usually low. The low leachability was found for barium (0.019 to 0.419 mg/dm3), chromium (0.019 to 0.095 mg/dm3), copper (0.006 to 0.019 mg/dm3), and iron (<0.01 to 0.017 mg/dm3). Increased leachability values were found only for strontium, between 0.267 and 4.530 mg/dm3, and aluminium, ranging from 0.603 to 3.270 mg/dm3. The analysed asbestos and cement materials feature a low percentage content of asbestos in flat and corrugated asbestos cement sheets (10–15%). Because of that it is possible to presume that pollutants characteristic of cement will be mainly present in products of leaching.
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Authors and Affiliations

Beata Klojzy-Karczmarczyk
1
ORCID: ORCID
Janusz Mazurek
1
ORCID: ORCID
Jarosław Staszczak
2
ORCID: ORCID

  1. Mineral and Energy Economy Research Institute of the Polish Academy of Sciences, Kraków, Poland
  2. Mineral and Energy Economy Research Institute, Polish Academy of Sciences, Kraków, Poland
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Abstract

The document presents current methods of forecasting aggregate production, mainly depending on the size and dynamics of changes in GDP. With a view to developing more accurate forecasts, this article presents the dependence of extraction and consumption of mineral aggregates used in construction on two indicators: the general business climate indicator in the construction industry and the cement consumption volume. The results obtained from regression and correlation analysis turned out more favourable for the dependence of aggregates production on cement consumption. This particularly applies to the dependence of sand and gravel aggregate production and total natural aggregate production on cement consumption. Good dependence has also been confirmed for other European countries as well as for the USA. For Poland, the indicator of sand and gravel aggregates production for cement production in recent years was between 9.5 and 12 Mg/Mg. The values of this indicator vary from country to country, mainly depending on the share of different types of aggregates in total production of aggregates in construction industry. Although the indicator values vary considerably, its advantage is that cement production is identified and included in the industrial production balance sheets of most countries, which is not the case when it comes to the identification or accurate record for the production of construction aggregates. The adoption of this indicator makes it possible to monitor the extraction of natural construction aggregates for individual countries and regions more accurately, as called for – among other things – by UN resolutions.
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Bibliography


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Authors and Affiliations

Ireneusz Ryszard Baic
1
ORCID: ORCID
Wiesław Kozioł
1
ORCID: ORCID
Artur Miros
1
ORCID: ORCID

  1. Łukasiewicz Research Network – Institue of Mechanised Construction & Rock Mining, Warszawa, Poland

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