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Abstract

This investigation was undertaken to determine the optimum conditions for physical-chemical treatment of waste water contaminated with heavy metals in the industry of metallic coatings. The industry uses substances such as: inorganic acids, alkalis, acidic and alkaline metal salts, that has a high water demand in the processes of flushing and cleaning the parts to be coated. According to the preliminary characterization of samples and reported in the literature theory, physico-chemical process was implemented for the removal of contaminants that consisted in chemical oxidation of CN-ions, followed by chemical precipitation made next to a coagulation/flocculation and subsequent adsorption on activated coal. Laboratory scale tests showed the optimal conditions of treatment including chemical oxidation by the addition of 4.15 cm3 of H2O2(30%) per gram of CN, chemical precipitation with NaOH to a pH of 12, followed by coagulation/flocculation with Fe2(SO4)3 at a speed of 135 rpm for 3 min and 20 rpm for 20 min and finally the addition of 1.0 g of adsorbent previously activated at 700°C. From this study, it is clear that the adsorption on activated carbon is highly efficient in the removal ofheavy metals from industrial waste water from electroplating. However, it is also clear that the parallel application of the treatments, shown here, is more effective to completely remove contaminants such as lead, nickel, silver, and copper at la-boratory scale, so it is recommended the simultaneous use of these physico-chemical processes.

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Authors and Affiliations

Jacipt A.R. Valencia
Jordi P. González
Iris Jimenez-Pitre
Geomar Molina-Bolívar
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Abstract

This study is the evaluation of the coagulation efficiency of the aluminum sulfate on the removal of catechol and pyrogallol. The study has focused on the impact of inorganic components of hardness Algerian waters. Jar-test trials were conducted on the two phenolic compounds dissolved in distilled water only, which was later enriched with minerals. Several reaction parameters varied, including the effect of pH and the influence of the salt content, and this approach yielded a better understanding of interaction between phenolic compounds and calcium/magnesium salts. The results indicate that the process efficiency depends on the number and position of OH in molecules. The main mechanisms would be either a physical adsorption, an exchange of ligand, or complexation on the floc surface of aluminum hydroxide. Moreover, the addition of inorganic salts appears to improve removal efficiency of tested phenolic compounds and have an effect on the optimal pH range for coagulation.
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Authors and Affiliations

Lynda Hecini
1
ORCID: ORCID
Hassen Boukerker
2
ORCID: ORCID
Wahida Kherifi
1
ORCID: ORCID
Abdelkarim Mellah
1
ORCID: ORCID
Samia Achour
2
ORCID: ORCID

  1. Scientific and Technical Research Center for Arid Areas (CRSTRA), M.B. 1682 Biskra 07000, Algeria
  2. University of Biskra, Laboratory in Underground and Surface Hydraulics (LARHYSS), Faculty of Science and Technology, Department of Civil Engineering and Hydraulics, Biskra, Algeria
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Abstract

The purpose of the presented research is to analyse possible methods of thickening of the Microcystis aeruginosa (Kützing) Kützing cyanobacteria using the obtained concentrate as a biomass for the production of energy carriers and bio-logically valuable substances. Method of cyanobacteria thickening under the action of electric current and in the electric field, as well as the method of coagulation–flocculation and gravity thickening, was experimentally investigated in lab-scale conditions. Electrical methods didn't show positive results for the Microcystis aeruginosa thickening, despite the re-ports of their potential efficiency in a number of previous studies. The high efficiency of the method of coagulation–flocculation and gravity thickening of Microcystis aeruginosa suspensions was obtained. The optimum concentrations of industrial polymeric coagulants and flocculants for the thickening of Microcystis aeruginosa suspensions were defined in the range of about 10 ppm for the coagulants and about 1 ppm for the flocculants. Negative effect of the previous cavitational treatment of the diluted suspensions of Microcystis aeruginosa on the effectiveness of the coagulation–flocculation and gravitational thickening was confirmed experimentally. Hydrodynamic cavitation should be recommended to use after the thickening as the next step of processing of concentrated suspensions of Microcystis aeruginosa to achieve maximum extraction of energy carriers and biologically valuable substances.

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Authors and Affiliations

Myroslav Malovanyy
Volodymyr Zhuk
Volodymyr Nykyforov
Igor Bordun
Iurii Balandiukh
Galyna Leskiv

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