The aim of the study was to assess the profile of EC (elemental carbon) and OC (organic carbon) temperature fractions in PM1 and PM2.5 samples and in wet deposition samples (material collected on a filter). The research was conducted at the urban background station in Zabrze (southern Poland) in the period of Oct 2020–Oct 2021. PM samples were collected with high-volume samplers; the automatic precipitation collector NSA 181 by Eigenbrodt was used to collect the deposition samples. Concentrations of EC and OC were determined using thermal-optical method (carbon analyzer from Sunset Laboratory Inc., “eusaar_2” protocol). Regardless of the type of research material, organic carbon constituted the dominant part of the carbonaceous matter, and this dominance was more visible in the non-heating season. The profile of temperature fractions of OC and EC was clearly different for dust washed out by precipitation. Noteworthy is a much lower content of pyrolytic carbon (PC) in OC, which can be explained by the fact that PC is most often combined with the water soluble organic carbon. In addition, a high proportion of the OC3 fraction was observed, followed by OC4, which may indicate that these fractions are of a more regional origin. With regard to the EC fractions, the differences are less visible and concern, in particular, the higher share of EC4 and the lower EC2. The obtained results may be a valuable source of information about the actual status of the carbonaceous matter and its transformation in the atmosphere.

The paper presents two sample preparation procedures for the determination of aldehydes in wet deposition. In both cases the 2,4-dinitrophenylhydrazine derivatization and solid phase extraction were applied. The derivatization in method A was applied before the extraction, the extraction in method B was carried out with simultaneous derivatisation. Accuracy of both methods was evaluated on the basis of the analysis of aqueous solutions of selected carbonyl compounds. Both methods were characterized by good recovery, however, due to the precision of the method expressed as RSD for testing of environmental samples the method B was used.

The analysis of environmental samples showed significant differences in the concentrations of aldehydes in wet deposition, depending on the location of the sampling point. In the case of samples taken from agricultural areas the predominant aldehydes were formaldehyde and acetaldehyde. Formaldehyde was from 31% to 47% of the determined compounds. While in samples collected near a traffic source, in the deposition acrolein was determined at the levels from 62% to 64% of the identified compounds.

When identifying the conditions required for the sustainable and long-term exploitation of geothermal resources it is very important to assess the dynamics of processes linked to the formation, migration and deposition of particles in geothermal systems. Such particles often cause clogging and damage to the boreholes and source reservoirs. Solid particles: products of corrosion processes, secondary precipitation from geothermal water or particles from the rock formations holding the source reservoir, may settle in the surface installations and lead to clogging of the injection wells. The paper proposes a mathematical model for changes in the absorbance index and the water injection pressure required over time. This was determined from the operating conditions for a model system consisting of a doublet of geothermal wells (extraction and injection well) and using the water occurring in Liassic sandstone structures in the Polish Lowland. Calculations were based on real data and conditions found in the Skierniewice GT-2 source reservoir intake. The main product of secondary mineral precipitation is calcium carbonate in the form of aragonite and calcite. It has been demonstrated that clogging of the active zone causes a particularly high surge in injection pressure during the fi rst 24 hours of pumping. In subsequent hours, pressure increases are close to linear and gradually grow to a level of ~2.2 MPa after 120 hours. The absorbance index decreases at a particularly fast rate during the fi rst six hours (Figure 4). Over the period of time analysed, its value decreases from over 42 to approximately 18 m3/h/MPa after 120 hours from initiation of the injection. These estimated results have been confi rmed in practice by real-life investigation of an injection well. The absorbance index recorded during the hydrodynamic tests decreased to approximately 20 m3/h/MPa after 120 hours.

Biocompatible coatings produced on the basis of the chemically extracted natural hydroxyapatite (HAp) from the animal bones were deposited using multiplex method comprising glow discharge nitriding (GDN) of the titanium alloy substrate and pulsed laser deposition (PLD) of HAp on the formerly fabricated titanium nitride layer (TiN). The TiN interlayer plays an important role improving adhesion of HAp to substrate and preserves the direct contact of the tissue with metallic substrate in the case of possible cracking of HAp coating. Surface morphology of deposited layers, crystallographic texture and residual stress were studied in relation to the type of laser applied to ablation (Nd:YAG or ArF excimer), laser repetition, temperature of substrate and atmosphere in the reactive chamber.

Hybryd PLD method was used for deposition high quality thin Ti, TiN, Ti(C,N) and DLC coatings. The kinetic energy of the evaporated particles was controlled by application of variation of different reactive and non reactive atmospheres during deposition. The purpose was to improve adhesion by building a bridge between the real ceramic coating and the substrate. A new layer composition layout was proposed by application of a buffer, starting layer. Advanced HRTEM investigation based on high resolution transmission electron microscopy was used to reveal structure dependence on specific atmosphere in the reactive chamber. New experimental technique to examine the crystallographic orientation based on X-ray texture tomography was applied to estimate contribution of the atmosphere to crystal orientation. Using Dictyostelium discoideum cells as a model organism for specific and nonspecific adhesion, kinetics of shear flow-induced cell detachment was studied. For a given cell, detachment occurs for critical stress values caused by the applied hydrodynamic pressure above a threshold. Cells are then removed from the substrate with an apparent first-order rate reaction that strongly depends on the stress. The threshold stress depends on cell size and physicochemical properties of the substrate, but it is not affected by depolymerization of the actin and tubulin cytoskeleton.

The contemporary underground mining of raw minerals is more and more associated with geological and mining software packages which support the work of designers from the moment of the exploration of a deposit, determination of its size and quality, geological, hydrogeological and tectonic conditions, by planning the development and cutting of the deposit. Production planning is one of the most important activities carried out in the course of a mining project, because it allows to set specific production results of a mine in relation to a time unit, and then allows for a verification of the degree of completion of the assumed plan. At present, computer-aided design is applicable to daily or long-term output planning taking deposit, qualitative, quantitative and cost constraints into account. In the article, selected forms of ore deposits were presented. On the basis of several dozen boreholes up to 300m in length, an exemplary fragment of the ore cutting model using computer-aided design of mining works was presented. By using modern computer software - ABB MineScape with modular construction, the possibilities of improving the process of development of future exploitation areas have been determined. In particular, the arrangement of boreholes, based on which ones the cross sections were made with, present the exemplary lithostratigraphic thickness of layers, including the location of discontinuous deformations in the form of faults, and an ore bearing zone. For the block model, resources with priority for metal N o. 1 and 2 were calculated. I n the last section of the article, the cutting idea for a shallow ore deposit has been presented. The degree of effective use of the deposit has been analysed for the room and pillar mining method.

The distribution of lignite deposits in Poland turns out to be closely related to tectonic boundaries and the occurrence of salt deposits. What mechanism underlies the connection between these elements?

The earliest studies of the Moon consisted of observations from Earth and meteorites containing lunar material. As technology progressed, the observations were made using remote sensing techniques. The next stage of the Moon reconnaissance consisted of unmanned flights, and later manned flights, with the help of which, in-situ tests were performed. The obtained materials enable the formulation of conclusions both about the geological structure and the mineral resources of the moon. The latest maps provided by the United States Geological Survey (USGS) and NASA Planetary Data System (PDS) enable a detailed analysis of the geological structure of the moon. Since they are available in shapefile format for QGIS and ArcGIS software, they can be freely modified and processed. On the basis of these, it is possible to analyze the complexity of the geological structure of the moon, especially with regard to the structure of its substrate and the surface covered with craters. Data obtained from the observation of the Moon with the use of research satellites and research carried out during landings related to the collection of samples enabled the formulation of conclusions about the raw materials present there. These raw materials are related to the surface layer of the so-called regolith, the recognition of which is relatively good because it is based not only on remote studies but also on the basis of collected samples. Additionally, there are indications of the possible presence of mineral resources related to the substrate, but its recognition is relatively poor because it is based on remote and geophysical surveys. The presented analysis shows that the Moon has such minerals as rare earth elements (REE) and Th and U found in the KREEP area. Fe and Ti are found to be in basaltic lava flows occurring in the mares and aluminum, silicon and Helium-3 occur in the regolith.

The aim of this work was to identify concentration levels of different chemical forms of mercury (TGM, TPM) in the ambient air in selected areas of the Silesian Region, characterized by low and high mercury emission. Based on the obtained data TGM and TPM concentration levels were determined. The project also focused on determination of dry and wet deposition of mercury compounds. Data concerning TGM and TPM flux rates in the ambient air and data on mercury deposition were used to determine a deposition coefficient. The coefficient was calculated as a share of mercury deposition on the land surface (dry and wet) to the amount of this contaminant transported with loads of air in the form of TGM and TPM in a given measurement station. At both monitoring stations the deposition coefficient did not exceed 0.2 %. The idea of calculating the deposition coefficient based on the analysis of TGM and TPM flux rate is a new solution. The proposed deposition coefficient allows to quantify information on a selected contaminant concentration and its potential impact resulting from deposition. Further studies on the deposition coefficient may contribute to the development of methods for estimating the impact of contaminants contained in the ambient air on other environmental components based on the analyses of the contaminant flux rate.

The motion of submicron particles involves the deterministic terms resulting from the aerodynamic convection and/or electrostatic attraction, and the stochastic term from the thermal displacement of particles. The Langevin equation describes such behavior. The Brownian dynamics algorithm was used for integration of the Langevin equation for the calculation of the single fiber deposition efficiency. Additionally the deterministic and stochastic of the particle motion were derived, using the Lagrangian and Eulerian approaches of particle movement and balance, for the calculation of the single fiber deposition efficiency due to both mechanisms separately. Combination of the obtained results allows us for calculation of the coupling effect of inertia and interception with the Brownian diffusion in a form of correlation. The results of calculation show that the omitting of the coupling effect of particular mechanism and using the simple additive rule for determination of the single fiber deposition efficiency introduces significant error, especially for particles with diameter below 300 nm.

Scaling and corrosion associated with the use of natural hard water in cooling towers during recirculation pose great problems from both economical and technical points of view, such as decreased system efficiency and increased frequency of chemical cleaning. Treated municipal wastewater (MWW) is a promising alternative to freshwater as power plant cooling system makeup water, especially in arid regions. In this work, hybrid systems of salt precipitation (SP), nanofiltration (NF) and reverse osmosis (RO) were investigated, as potential pretreatment processes for wastewater reuse as cooling water in the planned Jordan nuclear power plants. The As-Samra wastewater was used to calculate the potential of carbonate and sulfate scale formation. The results were compared to scale potentials from Palo Verde wastewater. Four cases were investigated; SP, NF, SP-RO and NF-RO. The SP pretreatment cases showed the highest monovalent to divalent ratio because of a high removal of Ca and Mg and addition of Na from the chemicals of the SP step. The NF pretreatment cases, showed the lowest calcium sulfate scale potential and this potential decreases with the % pretreatment. The scale amount increases very slightly with concentration times when the SP and NF product is desalinated by RO step.

The purpose of the studies was to estimate efficiency of delivering nebulised drugs into the lower respiratory tract through endotracheal tubes (ET tubes) which are commonly used in the treatment of uncooperative patients. Water solution of Disodium Cromoglycate (DSCG) was nebulised with a constant air flow (25 l/min). Experimental studies were done for eight ET tubes with varying sizes (internal diameter, length) and made of two different materials. Size distribution of aerosol leaving ET tubes was determined with the use of aerosol spectrometer. Fine Particle Fraction (FPF) and Mass Median Aerodynamic Diameter (MMAD) were calculated for the aerosol leaving each tube. Additionally, mass of the Disodium Cromoglycate deposited into each endotracheal tube was determined. ET tubes can significantly influence the parameters of delivered aerosol depending on their diameter. FPF of aerosol delivered in to the respiratory tract is lower if small endotracheal tubes are used. However, MMAD and FPF for large endotracheal tubes are almost identical with MMAD and FPF from nebuliser. The results indicate that a substantial fraction of large droplets is eliminated from the aerosol stream in long endotracheal tubes (270 mm). In this case the mass of drug delivered through ET tubes is reduced but the content of small droplets increases (high value of FPF).

This paper presents the results of experiments on metallization of plastic elements produced using 3D printing technology from the light-hardened resins. The obtained coatings were bimetallic (Cu/Ni). The first step of metallization was the electroless deposition of copper. The second one was electrodeposition of nickel on the previously prepared copper substrate. The parameters of 3D prints preparation and metallization processes were deeply investigated. The etching of plastics substrates and duration of electroless metallization of 3D prints by copper were analyzed. In the next step the influence of nickel electrodeposition time was investigated. The coating were analyzed by XRD method and morphology of surface was analyzed by scanning electron microscopy (SEM). The thickness of coatings was calculated based on mass differences and measured by using optical microscopy method. The optimal parameters for both processes were specified.

Additive manufacturing (AM) is a process that joins similar or dissimilar materials into application-oriented objects in a wide range of sizes and shapes. This article presents an overview of two additive manufacturing techniques; namely Laser metal deposition (LMD) and Wire arc additive manufacturing (WAAM). In LMD, metallic powders are contained in one or more chambers, which are then channelled through deposition nozzles. A laser heats the particles to produce metallic beads, which are deposited in layers with the aid of an in-built motion system. In WAAM, a high voltage electric arc functions as the heat source, which helps with ensuring deposition of materials, while materials in wire form are used for the feedstock. This article highlights some of the strengths and challenges that are offered by both processes. As part of the authors’ original research work, ­Ti-6Al-4V, Stainless steel 316L and Al-12Si were prepared using LMD, while the WAAM technique was used to prepare two Al alloys; Al-5356 and CuAl8Ni2. Microstructural analysis will focus on similarity and differences in grains that are formed in layers. This article will also offer an overall comparison on how these samples compare with other materials that have been prepared using LMD and WAAM.

Molybdenum disulfide (MoS2) is one of the most widely used solid lubricants applied in different ways on the surfaces under friction. In this work, AISI 316 austenitic stainless steel was coated with MoS2, using chemical vapor deposition (CVD) at four different temperatures (400, 500, 600 and 700°C). Coatings properties were investigated using SEM, EDX, XRD and FTIR, Hardness Tester and Roughness tester. The results showed that with simultaneous evaporation of sulfur and molybdenum trioxide (MoO3) in the CVD chamber, a uniform coating layer containing MoS2 and MoO2 phases was formed. Increase in the substrate temperature resulted in the rise in the amount of MoS2 to MoO2 phases. The thickness, grain size and the hardness of the coating were 17-29 μm, 50-120 nm and 260-480 HV respectively. Friction tests carried out using pin-on-plate method under normal loads of 10 N under ambient conditions showed values of the friction coefficient 0.25-0.40.

Boron nitride thin layers were produced by means of the pulsed laser deposition technique from hexagonal boron nitride target. Two types of laser i.e. Nd:YAG with Q-switch as well as KrF coupled with RF generator were used. Influence of deposition parameters on surface morphology, phase composition as well as mechanical properties is discussed. Results obtained using Fourier Transformed Infrared Spectroscopy, Transmission and Scanning Electron Microscopy, Atomic Force Microscopy are presented. Micromechanical properties measured during microindentation, scratch and wear tests are also shown.

Pulsed laser deposition technique was applied for covering elastic cast-polyurethane membranes with titanium nitride and boron nitride layers. The deposition process was realized using a Nd:YAG laser with Qswitch in stages; firstly the membranes were coated with ultra-thin titanium nitride layer (TixN) by evaporation of a metallic titanium disk in nitrogen gas atmosphere and then a layer of boron nitride (BN) was deposited by ablation of hexagonal h-BN target in argon atmosphere. The surface morphology was observed by scanning electron microscopy. Chemical composition was analyzed by energy dispersive X-ray spectrometry. The phase analysis was performed by means of grazing incidence X-ray diffraction and attenuated total reflection infrared spectroscopy. The crystallographic texture was measured. The wear test was performed by pin-on-disk method. Hexagonal boron nitride layers with (0001)[uvtw] texture with flake-like grains were fabricated. The structure and texture of boron nitride was identical irrespectively of substrate roughness or BN thickness. Pin-on-disk wear tests showed that the coatings effectively decreased the friction coefficient from two to even four times comparing to pure polyurethane and polyurethane covered with graphite. This proved that deposited layers can replace graphite as a lubricating material used to protect polymer surfaces.

The aim of the work was to obtain thin bismuth oxide films containing, at room temperature, the Bi1,5Er0,5O3 phase. This phase corresponds to the structure of the high-temperature δ-Bi2O3 phase, in pure bismuth oxide, characterized by the highest ionic conductivity of all known solid state ionic conductors. The high-temperature δ-Bi2O3 phase with the face centered cubic structure, in pure bismuth oxide, occurs only at temperature above 730°C.

Stabilization of the δ-Bi2O3 phase at room temperature was achieved by an addition of the erbium together with the employment of the Pulsed Laser Deposition (PLD) technique. The influence of an amount of Er alloying and the film thickness on surface morphology, microstructure, phase composition of thin films were investigated. The velocity of deposition of thin layers of bismuth stabilized with erbium in the PLD process using the Nd: YAG laser was about 0.5 nm/s.

The investigation results of erbium doped bismuth oxide thin films deposited onto (0001) oriented Al2O3 monocrystalline substrate are presented.

Thin films of uniform thickness, without cracks, and porosity were obtained. All deposited thin films (regardless of the film thickness or erbia (Er2O3) content) exhibited a columnar structure. In films stabilized with erbium, up to approx. 250 nm thickness, the columns have a diameter at the base from 25 to 75 nm. The columns densely and tightly fill the entire volume of the films. With increasing of the film thickness increases, porosity also significantly increases. In thin layers containing from 20 to 30 mole % Er2O3 the main identified phase at room temperature is Bi1.5Er0.5O3. It is similar to the defective fluorite-type structure, and belongs to the Fm-3m space group. This phase corresponds to the structure of the high-temperature δ-Bi2O3 phase in pure bismuth oxide.

Mineral deposits are such type of assets, the valuation of which can be carried out in a very diverse manner. Methods and procedures for such a valuation are most often applied to mineral deposits with mineral reserves (according to the CRIRSCO classification), much less frequently and usually only using a comparative approach for undeveloped, initially recognized mineral deposits (with mineral resources).

In Poland, a significant portion of mineral deposits, mainly of energy, metal and chemical minerals, are covered by the so-called mining property of the Treasury. At the moment, there is a lack of consistent and thoughtful management of these deposits. The appropriate methodology for valuing these deposits, which are at various stages of recognition (sometimes also of development), should be one of the key elements of such management. The State Treasury usually disposes of mining rights by “establishing” mining usufruct in the form of a contract, with the determination of remuneration for this establishment. The rules for determining remuneration for the establishment of mining usufruct are determined on the basis of an internal informal document of the Ministry of the Environment with very simplified rules for determining this remuneration, to a very limited extent related to the actual value of the deposit, which is also variable over time. This fee should be in close relation to the value of the mineral deposit valued at a given moment, taking the current conditions, including technological, environmental, formal and legal, and – in particular – market conditions into account. The valuation of mineral deposits covered by mining property, except for current needs in determining the basis for remuneration for mining usufruct establishing, should also be used to determine the value of these deposits annually as part of the State Treasury property and to present its results as part of the State Treasury Property Status Report.

It is an open matter whether the methodology of valuation of the discussed mineral deposits should be based on accepted and widely used solutions for the valuation of mineral deposits for the purposes of business transactions or based on methodology of valuation of deposits as part of the planned system of Integrated Environmental and Economic National Account (up to date poorly developed). The paper presents the most important elements of both methodological approaches. It seems that the use of selected elements of each of these approaches would be advisable in this case.

The operational mineral deposit reconnaissance tends to evaluate its parameters to conduct safe and profitable production. Particular deposit parameters, important from the point of mineral deposit management, are estimated on the basis of observations carried out by mining geological surveys. These observations usually involve sampling, drilling, laboratory analyses and others. The use of fuzzy description to assess the parameters of the mineral deposit was proposed in the paper. In the fuzzy characteristics, an imprecise descriptive description appeared in place of a particular numerical quantity. This approach was used to description of the ore deposit features (metal content, volume, and metal yield) by assigning them specific characteristic functions, whose distributions were based on basic statistical quantities. Characteristic functions can be used to prepare operational strategies for any configuration of required deposit parameters resulting from the production management needs. For this purpose, selected logical operators of fuzzy sets were used. In the next approach to fuzzy modeling, an opportunity to characterize the deposit in a subjective approach was indicated, where the assessment of the deposit parameters is based on rough, in some way, discretionary observation and evaluation. Such model construction enabled the overall assessment of the deposit from the point of view of any parameters. Through the implementation of appropriate inference rules, adequate fuzzy control planes were obtained, which may also be useful in the context of operational mine strategy planning.

The basis for a mineral deposit delimitation is a qualitative and quantitative assessment of deposit parameters, qualifying a deposit as an economically valuable object. A conventional approach to the mineral deposit recognition and a deposit detailed parameters qualification in the initial stages of development work in the KGHM were presented in the paper. The goals of such recognition were defined, which through a gradual detailed expansion, resulting from the information inflow, allows for the construction of a more complete decision-making model. The description of the deposit parameters proposed in the article in the context of fuzzy logic, enables a presentation of imprecise statements and data, which may be a complement to a traditional description. Selected non-adjustable and adjustable s-norm and t-norm operators were demonstrated. Operators effects were tested for selected ore quality parameters (copper content and deposit thickness) by constructing adequate membership functions. In a practical application, the use of chosen fuzzy logic operators is proposed for the assessment of the qualitative parameters of copper-silver ore in the exploitation blocks for one of the mines belonging to KGHM Polish Copper S.A. The considerations have been extended by including the possibility of using compensation operators.

Waters with mineralization above 1000 mg/dm3, classified as mineral waters, are exploited in many regions of Poland. Their resources are usually not renewable and their excessive exploitation can lead to the deterioration of their physical and chemical properties and negatively affect their quantitative status.

The stages in the life of a groundwater deposit involve prospecting, exploration, development, and exploitation. Deposit management is the basis for a sustainable and economically successful process of using water resources.

The problem of effective management of mineral water deposit management has not been raised so far, which is why the authors decided to address issues that should be taken into account in the abovementioned process. An integrated approach to the prospecting, exploration, opening, and exploitation of mineral waters combining the knowledge of specialists from various disciplines (hydrogeologists, geologists, drillers and producers) will enable the appropriate management of these resources.

The article describes the basic elements of the process, special attention has been paid to the mineral water deposit development plan conditioning the correct and economically justified exploitation of these waters. This plan should take the development strategy and legal and environmental conditions into account. Hydrogeological and mathematical models of mineral water deposits developed as part of the plan provide the basis for determining the extent of the mining area and estimating water resources. The deposit opening, exploitation, and monitoring methods are important elements of the deposit development plan.

The functioning of European economies and societies requires a stable and sustainable supply of mineral resources. For 10 years now EU has been developing raw materials initiative to secure European minerals supply. In many cases, areas with known or hypothetic mineral resources, are not sufficiently valued by society and authorities, remain unprotected and face competing land uses with the risk of becoming sterilized. MINATURA 2020 project was born out of a need to develop a harmonised framework which allow a common way of identifying “mineral deposits of public importance” (MDoPI) and their safeguarding via land use planning. The project has left a useful set of guidelines and proposals how to advance on the creation of a European network of MDoPIs to avoid sterilization of “deposits worth safeguarding”.

In Poland, the need for legal protection of mineral deposits has been discussed intensively in recent years. Various proposals aimed at better system of mineral deposits safeguarding, especially those which should be recognized as of public importance, have been proposed. However, until now only a few coal deposits were recognized as strategic. Currently, the Polish National Mineral Policy is under preparation. Its overriding objective is to provide access to the necessary minerals, also in the longterm perspective. It assumes among others activities aimed at protection of mineral deposits regarding land use planning system.

Paper presents scope and general results of MINATURA2020 project, with details on MINATURA2020 methodology implementation in Poland, Project of the Polish National Mineral Policy with its objectives and key pillars, position of MDoPIs in this Project, and – finally – expected future steps related to MDoPI safeguarding in EU and in Poland.