We have presented dielectric and conductivity studies of two liquid crystal (LC) compounds- p-octyloxybenzoic acid (8OBA) and p-decyloxybenzoic acid (10OBA). Dielectric permittivity study of those compounds gives the evidence of space charge polarization and ionic conductance in the samples. Dielectric permittivity is found to be the highest for 8OBA than 10OBA. Both compounds found to exhibit positive dielectric anisotropy. Splay elastic constant as a function of temperature has also been investigated. Frequency and temperature dependent electrical conductivity of these two LC compounds have been studied in detail. Activation energy has been estimated from both dc and ac conduction process.
The study investigates the effect of heat treatment on the microstructure evolution and properties of an age-hardened Cu-3Ti-2Mg alloy. The precipitated Cu2Mg and β'-Cu4Ti phases consequently yield a depletion of the Cu matrix in regards to Ti and Mg solutes, which enhances the electrical conductivity. The Cu2Mg Laves phase and β'-Cu4Ti phase precipitates increase the hardness of the alloy due to the consistency and coherency of the later phase. However, the decrease of hardness is mainly associated with the coarse microstructures, that can be formed due to the phase transformation from metastable β'-Cu4Ti phase to more stable Cu3Ti phase. In the range of experiments, the optimum process is solution treatment at 700°C for 4 h, with subsequent age-hardening at 450°C for 4 h. The electrical conductivity, hardness, tensile strength, and elongation of the Cu-3Ti-2Mg alloy were 15.34 %IACS, 344 HV, 533 MPa, and 12%, respectively.
This paper presents the results of obtaining and investigations of Pb1–xBax(Zr1–yTiy)1–zSnzO3 (PBZTS) ceramics with constant x = 0.03 and y = 0.02, and variable z = 0, 0.04, 0.06 and 0.08 (abbreviations of the samples were following PBZTS0, PBZTS4, PBZTS6, PBZTS8, respectively). The investigated compositions are close to rhombohedral-orthorhombic morphotropic phase boundary. The ceramic samples have been obtained by conventional ceramic technology from simple oxides PbO, ZrO2, TiO2, SnO2 and barium carbonate BaCO3. The ceramic powders, after calcination, have been pressed into discs and sintered using free sintering (FS) method. For samples obtained in such a way, the dielectric properties at various frequencies and electrical conductivity have been investigated. The increase of Sn content orders the microstructure of ceramics, and as a result the improvement of the dielectric properties of ceramic samples can be obtained.
Nonlinear phenomena of the planar and quasi-planar magnetoacoustic waves are considered. We focus on deriving of equations which govern nonlinear excitation of the non-wave motions by the intense sound in initially static gaseous plasma. The plasma is treated as an ideal gas with finite electrical conductivity permeated by a magnetic field orthogonal to the trajectories of gas particles. This introduces dispersion of a flow. Magnetoacoustic heating and streaming in the field of periodic and aperiodic magnetoacoustic perturbations are discussed, as well as generation of the magnetic perturbations by sound. Two cases, corresponding to magnetosound perturbations of low and high frequencies, are considered in detail.
The aim of this paper was to attain defect free, pure copper castings with the highest possible electrical conductivity. In this connection, the effect of magnesium additives on the structure, the degree of undercooling (ΔTα = Tα-Tmin, where Tα – the equilibrium solidification temperature, Tmin – the minimum temperature at the beginning of solidification), electrical conductivity, and the oxygen concentration of pure copper castings have been studied. The two magnesium doses have been investigated; namely 0.1 wt.% and 0.2 wt.%. A thermal analysis was performed (using a type-S thermocouple) to determine the cooling curves. The degree of undercooling and recalescence were determined from the cooling and solidification curves, whereas the macrostructure characteristics were conducted based on a metallographic examination. It has been shown that the reaction of Mg causes solidification to transform from exogenous to endogenous. Finally, the results of electrical conductivity have been shown as well as the oxygen concentration for the used Mg additives.
The aim of this work is the development of Cu-Al2O3 composites of copper Cu-ETP matrix composite materials reinforced by 20 and 30
vol.% Al2O3 particles and study of some chosen physical properties. Squeeze casting technique of porous compacts with liquid copper
was applied at the pressure of 110 MPa. Introduction of alumina particles into copper matrix affected on the significant increase of
hardness and in the case of Cu-30 vol. % of alumina particles to 128 HBW. Electrical resistivity was strongly affected by the ceramic
alumina particles and addition of 20 vol. % of particles caused diminishing of electrical conductivity to 20 S/m (34.5% IACS). Thermal
conductivity tests were performed applying two methods and it was ascertained that this parameter strongly depends on the ceramic
particles content, diminishing it to 100 Wm-1K-1 for the composite material containing 30 vol.% of ceramic particles comparing to 400
Wm-1K-1 for the unreinforced copper. Microstructural analysis was carried out using SEM microscopy and indicates that Al2O3 particles
are homogeneously distributed in the copper matrix. EDS analysis shows remains of silicon on the surface of ceramic particles after
binding agent used during preparation of ceramic preforms.
In this study, two different compositions of submicron-structured titanium (760 nm) and micron-structured chromium (4.66 μm) powders were mixed to fabricate Cr-31.2 mass% Ti alloys by vacuum hot-press sintering. The research imposed various hot-press sintering pressures (20, 35 and 50 MPa), while the sintering temperature maintained at 1250°C for 1 h. The experimental results showed that the optimum parameters of the hot-press sintered Cr-31.2 mass% Ti alloys were 1250°C at 50 MPa for 1 h. Also, the relative density reached 99.94%, the closed porosity decreased to 0.04% and the hardness and transverse rupture strength (TRS) values increased to 81.90 HRA and 448.53 MPa, respectively. Moreover, the electrical conductivity is enhanced to 1.58 × 104 S·cm–1. However, the grain growth generated during the high-temperature and high-pressure of the hot-press sintering process resulted in the grain coarsening phenomenon of the Cr-31.2 mass% Ti alloys after 1250°C hot-press sintering at 50 MPa for 1 h. In addition, the Cr-31.2 mass% Ti alloys were fabricated with the submicron-structured titanium (760 nm) and chromium (588 nm) powders showed more effective compaction than the micron-structured titanium (760 nm) and chromium (4.66 μm) powders did. The closed porosity decreases to 0.02% and the hardness values increase to 83.23 HRA. However, the agglomeration phenomenon of the Cr phase and brittleness of the TiCr2 Laves phases easily led to a slight decrease in TRS (400.54 MPa).
In this research, Co-30 mass% Cr alloys were fabricated by a vacuum hot-press sintering process. Different amounts of submicron cobalt and chromium (the mean grain size is 800 and 700 nm, respectively) powders were mixed by ball milling. Furthermore, this study imposed various hot-press sintering temperatures (1100, 1150, 1200 and 1250°C) and pressures (20, 35 and 50 MPa), while maintaining the sintering time at 1 h, respectively. The experimental results show that the optimum parameters of hot-press sintered Co-30 mass% Cr alloys are 1150°C at 35 MPa for 1 h. Meanwhile, the sintered density reaches 7.92 g·cm–3, the closed porosity decreases to 0.46%, and the hardness and transverse rupture strength (TRS) values increase to 77.2 HRA and 997.1 MPa, respectively. While the hot-press sintered Co-30 mass% Cr alloys at 1150°C and 20 MPa for 1 h, the electrical conductivity was slightly enhanced to 1.79 × 104 S·cm–1, and the phase transformation (FCC → HCP) of cobalt displayed a slight effect on sintering behaviors of Co-30 mass% Cr alloys. All these results confirm that the mechanical and electrical properties of Co-30 mass% Cr alloys are effectively improved by using the hot-press sintering technique.