One of the methods of obtaining energy from renewable sources is the technology of indirect cofiring of biomass. It consists in the gasification of secondary fuel and combustion of the generated gas in the boiler together with its primary fuel. The paper presents a thermodynamic analysis of the use of the boiler flue gases as the converting medium in the process of indirect co-firing - a technology which is being developed at the Institute of Power Engineering and Turbomachinery of the Silesian University of Technology. The basis of the analysis are the data resulting from variant calculations conducted with the use of the Gaseq program. The calculations were made for various compositions of gasified fuel and the converting medium, variable fuel/oxidiser ratios and variable gasification temperatures. As a result, the equilibrium composition and the calorific value of the generated gas were obtained. The main optimisation objective adopted here was the nondimensional efficiency coefficient, which is the ratio of the chemical energy of products to the chemical energy of the process reactants.

The main focus of the paper is on the asymptotic behaviour of linear discrete-time positive systems. Emphasis is on highlighting the relationship between asymptotic stability and the structure of the system, and to expose the relationship between null-controllability and asymptotic stability. Results are presented for both time-invariant and time-variant systems.

The study deals with stability and dynamic problems in bar structures using a probabilistic approach. Structural design parameters are defined as deterministic values and also as random variables, which are not correlated. The criterion of structural failure is expressed by the condition of non-exceeding the admissible load multiplier and condition of non-exceeding the admissible vertical displacement. The Hasofer-Lind index was used as a reliability measure. The primary research tool is the FORM method. In order to verify the correctness of the calculations Monte Carlo and Importance Sampling methods were used. The sensitivity of the reliability index to the random variables was defined. The limit state function is not an explicit function of random variables. This dependence was determined using a numerical procedure, e.g. the finite element methods. The paper aims to present the communication between the STAND reliability analysis program and the KRATA and MES3D external FE programs.

We consider the Debreu private ownership economy in which all consumption plans belong to a proper linear subspace of the commodity-price space ℝ^l. This geometric property of consumption sets means that there is a dependency between quantities of some commodities in all consumption plans. Competitive mechanism makes producers adjust their plans of action to the same dependency. It results in the mild evolution of the production sector to offer production plans which are also contained in the given subspace of ℝ^l. Modified production system and the initial consumption system can form an economy in equilibrium. The aim of this paper is to model gentle changes of producers’ activity that give equilibrium in the Debreu economy with consumption system reduced to a proper subspace of ℝ^l without considering additional costs.

In this paper we investigate the quantitative importance of efficiency wages of no-shirking type in explaining business cycle fluctuations in Bulgarian labor markets. This is done by augmenting a relatively standard real business cycle model with unobservable workers effort by employers and efficiency wage contracts, as well as through the inclusion of a detailed government sector. This imperfection in labor markets introduces a strong internal transmission mechanism that allows the model framework to capture the business cycles in Bulgarian data better than earlier models, and setups assuming perfectly-competitive labor markets in particular.

Acoustical attenuation spectra in the frequency range 12 kHz - 2 GHz and nonequilibrium time domain measurements are briefly reviewed for aqueous solutions of various mono- and disaccharides as well as alkyl glycosides. Several relaxation regimes emerge with relaxation times between 10-11 s and 103 s. In this paper relaxation terms reflecting conformational changes are discussed, particularly mutarotation (103 s), chair-chair ring inversion (1 μs), two modes of pseudorotation (100 ns, 10 ns), disaccharide ring isomerisation (10 ns), and exocyclic side group rotation (1 ns).

Thermodynamic equilibrium-based models of gasification process are relatively simple and widely used to predict producer gas characteristics in performance studies of energy conversion plants. However, if an unconstrained calculation of equilibrium is performed, the estimations of product gas yield and heating value are too optimistic. Therefore, reasonable assumptions have to be made in order to correct the results. This paper proposes a model of the process that can be used in case of deficiency of information and unavailability of experimental data. The model is based on free energy minimization, material and energy balances of a single zone reactor. The constraint quasi-equilibrium calculations are made using approximated amounts of non-equilibrium products, i.e. solid char, tar, CH4 and C2H4. The yields of these products are attributed to fuel characteristics and estimated using experimental results published in the literature. A genetic algorithm optimization technique is applied to find unknown parameters of the model that lead to the best match between modelled and experimental characteristics of the product gas. Finally, generic correlations are proposed and quality of modelling results is assessed in the aspect of its usefulness for performance studies of power generation plants.

The objective of the work are in-depth experimental studies of Cu(II) and Zn(II) ion removal on chitosan gel beads from both one- and two-component water solutions at the temperature of 303 K. The optimal process conditions such as: pH value, dose of sorbent and contact time were determined. Based on the optimal process conditions, equilibrium and kinetic studies were carried out. The maximum sorption capacities equaled: 191.25 mg/g and 142.88 mg/g for Cu(II) and Zn(II) ions respectively, when the sorbent dose was 10 g/L and the pH of a solution was 5.0 for both heavy metal ions. One-component sorption equilibrium data were successfully presented for six of the most useful three-parameter equilibrium models: Langmuir-Freundlich, Redlich-Peterson, Sips, Koble-Corrigan, Hill and Toth. Extended forms of Langmuir-Freundlich, Koble-Corrigan and Sips models were also well fitted to the two-component equilibrium data obtained for different ratios of concentrations of Cu(II) and Zn(II) ions (1:1, 1:2, 2:1). Experimental sorption data were described by two kinetic models of the pseudo-first and pseudo-second order. Furthermore, an attempt to explain the mechanisms of the divalent metal ion sorption process on chitosan gel beads was undertaken.

No adequate reaction has been observed of the decreased contaminant loads discharged by Łódź, particularly the loads of phosphorus, on its concentration in the Ner River. That’s why the im-pact of sediment on phosphorus content in the water was evaluated. Not only was the amount of phosphorus taken under consideration but also the equilibrium phosphate concentration (EPCo). The meaning of EPCo is that any phosphate concentration in the water below this value will lead to phos-phorus release from sediments. Performed study shows that in the Puczniew cross-section EPCo is higher then phosphorus concentration in water, thus with mean concentration of PO4 equal to 9.5 mg PO4·dm–3 phosphorus could be released from sediments. This concentration in Lutomiersk cross-section, however, equals 1.2 mg PO4·dm–3.

Greenhouse gases such as carbon dioxide and water vapour can be captured from gas streams on a zeolite 13X adsorbent. Experimental water vapour adsorption isotherms and kinetic curves were measured in the temperature range of 293–393 K and pressure up to 2100 Pa. The equilibrium data were developed with Toth and Sips multi-temperature isotherm models. The results of the process rate studies were described using pseudo-first and pseudo-second order kinetic models. Findings were compared with our own results of CO2 adsorption studies on the same zeolite.

The local aspect of aging is often ignored. However, municipalities, in particular cities will be affected by the consequences of population aging, in particular a decrease in tax revenues and an increase of expenditures on public goods demanded by the elderly. In this paper we use a static general equilibrium model to analyse the impact of aging on city’s finances. We show that an increase in the number of pensioners will raise the cost of public goods. However, an increase in the number of working elderly can alleviate the situation.

Poland is expected to enter the Exchange Rate Mechanism II (ERM II). The European Central Bank recommends that the ERM II central rate should reflect the best possible assessment of the equilibrium exchange rate. Since the equilibrium rate is changing in time, it is important to identify the pushing and pulling forces of the exchange rate. This knowledge will let the authorities to defend only the exchange rate that is in equilibrium and to assess outcomes of their actions. We use the VEC approach of Johansen to estimate the behavioral equilibrium exchange rate and to identify the pushing forces of the Polish zloty/euro rate. We apply the Gonzalo-Granger decomposition to calculate the permanent equilibrium exchange rate and to identify the pulling forces of the zloty exchange rate. We demonstrate that this approach may be useful for Polish authorities while entering the ERM II as well as within that mechanism.

The paper considers a private ownership economy in which economic agents could realize their aims at given prices, Walras Law is satisfied but agents’ optimal plans of action do not lead to an equilibrium in the economy. It means that the market clearing condition is not satisfied for agents’ optimal plans of action. In this context, the paper puts forward three specific adjustment processes resulting in equilibrium in a transformation of the initial economy. Specifically, it is shown, by the use of strict mathematical reasoning, that if there is no equilibrium in a private ownership economy at given prices, then, under some natural economic assumptions, after a mild evolution of the production sector, equilibrium at unchanged prices can be achieved.