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Number of results: 13
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Abstract

The aim of the study was to evaluate the influence of different fillers on the chosen functional properties of experimental composites based on typical polymeric matrix, in order to understand the effect of different fillers on their properties and to develop a simple base composite for further investigations with experimental fillers, e.g. with antimicrobial properties. Previous experiments have been usually based on commercially available composites of unknown composition or compilation of monomers, without reinforcing fillers. Scanning electron microscopy was used to investigate the quality of fillers’ dispersion, which was satisfying. Results showed significant differences between materials’ diametral tensile strength (p = 0.0019), compressive strength (p < 0.0001), Vickers micro-hardness (p < 0.0001), flexural modules (p = 0.0018), and the degree of conversion (p < 0.0001), but flexural strength was not significantly different (p = 0.0583). Investigations indicated that no filler type had an especially positive impact on the mechanical properties, but reinforcement effect was achieved by proper compilation of silica nanofiller and variable glass fillers. Nanofiller decreased the degree of conversion.

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Authors and Affiliations

R. Stencel
W. Pakieła
I. Barszczewska-Rybarek
J. Żmudzki
J. Kasperski
G. Chladek
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Abstract

The paper analyses the influence of chemical composition of silicone-based composites on their properties in the aspect of using them as long-term soft denture lining materials. Different concentrations of filler and methylhydrosiloxane-dimethylsiloxane copolymer were used. The filler was introduced into the composite with mechanical mixing combined with ultrasonic homogenization. Scanning electron microscopy was used to investigate the quality of filler dispersion. Shore A hardness, tensile strength, sorption, solubility and tensile bond strength to poly(methyl methacrylate) were measured. Tests show satisfactory results for some experimental composites, which met all the requirements for such materials.

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Authors and Affiliations

E. Jabłońska-Stencel
W. Pakieła
J. Żmudzki
J. Kasperski
G. Chladek
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Abstract

This study examined the effects rheological properties of different composition kaolin and kaolin geo-filler in polypropylene composites. Polypropylene composites with varying composition of kaolin geo-filler 0 wt%, 2 wt%, 4 wt%, 6 wt%, 8 wt%, and 10 wt% was prepared and compared with polypropylene composite with raw kaolin. Kaolin is an aluminosilicate based mineral filler was used to prepare geopolymer paste by combining with alkaline activator solution. The polypropylene composite was compounded using a twin-screw extruder and the melt flow index was determined by a constant weight pressure of 2.16 kg at 230°C in 10 min. Knowing the melt flow index is necessary to predict and control the process, the study has demonstrated that the composition of kaolin filler and kaolin geo-filler affects the melt flow, melt density and surface morphology at varies composition. Composites with kaolin geo-filler have demonstrated high melt flow index process and having better distribution and flow.
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Authors and Affiliations

Zulaikha Zulkifli
1
ORCID: ORCID
Yusrina Mat Daud
1 2
ORCID: ORCID
Farah Farhana Zainal
1 2
ORCID: ORCID
Mohammad Firdaus Abu Hashim
2 3
ORCID: ORCID
Yurdakul Aygörmez
4
ORCID: ORCID

  1. Universiti Malaysia Perlis, Faculty of Chemical Engineering Technology, 02600 Arau, Perlis, Malaysia
  2. University Malaysia Perlis (UniMAP), Green Technology (CEGeoGTech), 01000 Kangar, Perlis, Malaysia
  3. Universiti Malaysia Perlis, Faculty of Engineering Technology, Level 1, Block S2, UniCITI Alam Campus, Sungai Chuchuh, 02100 Padang Besar, Perlis, Malaysia
  4. Yildiz Technical University, Faculty of Civil Engineering, Civil Engineering Department, Davutpasa Campus, Istanbul, Turkey
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Abstract

Polymer composite materials based on the Moplen HP400R polypropylene matrix with a filler from walnut shell flour with 30, 40 and 50% content and 200-315 µm and 315-443 µm fraction were produced by the injection method. The effect of filler content was analysed on the processing properties of the composites such as: MFR Melt Flow Rate and the MVR Melt Volume-flow Rate, as well as the temperature of the filler flour decomposition using the TGA thermogravimetric analysis method. The following was also determined: density, hardness, tensile strength and stiffness modulus of elasticity of the materials in question. The obtained composite material was characterised by low density, which increased with the rising filler content. It was found that the applied natural filler has increased the hardness and stiffness modulus of the composite and decreased the tensile strength.

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Authors and Affiliations

A. Włodarczyk-Fligier
M. Polok-Rubiniec
B. Chmielnicki
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Abstract

In this paper, we have studied the evolution of morphology and brazing behavior of Ag-28Cu alloy filler processed by high energy ball milling. The milling of the powder mixture was carried out for 40 h. The structural and morphological analyses were performed by the X-ray diffraction and scanning electron microscopy. The melting temperature of the braze filler was determined by differential thermal analysis. The filler wetting properties were assessed from the spread area ratio measurements on various Ti substrates. The results indicate that the ball milling can effectively depress the filler melting point and enhance the brazeability. The milled powder mixture showed Ag(Cu) solid solution with a crystallite size of 174-68 nm after 40 h. It was shown that the high energy ball milling can be a potential method to develop low temperature brazing fillers for advanced microjoining applications.

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Authors and Affiliations

Ashutosh Sharma
ORCID: ORCID
Myoung Jin Chae
Byungmin Ahn
ORCID: ORCID
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Abstract

Geopolymer is formed from the alkali activation of materials rich in Si and Al content with the addition of a silicate solution to enhance the properties of the materials. This paper presents research on the mechanical properties of fly ash-based geopolymer filler in epoxy resin by varying different solid to liquid ratios using sodium hydroxide and sodium silicate as the alkaline activator. However, the common problem observed from the solid to liquid ratio is the influence of curing time and compressive strength of geopolymer to have the best mechanical property. The mix design for geopolymers of solid to liquid ratio is essential in developing the geopolymer’s mechanical strength. A series of epoxy filled with fly ash-based geopolymer materials with different solid to liquid ratio, which is prepared from 0.5 to 2.5 solid to liquid ratio of alkaline activator. The tensile strength and flexural strength of the epoxy filled with fly ash-based geopolymer materials is determined using Universal Testing Machine under tensile and flexural mode. It was found that the optimum solid to liquid ratio is 2.0, with the optimum tensile and flexural strength value. However, both the tensile and flexural properties of epoxy filled with fly ash-based geopolymer suddenly decrease at a 2.5 solid to liquid ratio. The strength is increasing with the increasing solid to liquid ratio sample of geopolymer filler content.
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Authors and Affiliations

Mohammad Firdaus Abu Hashim
1 2
ORCID: ORCID
Che Mohd Ruzaidi Ghazali
1 3
ORCID: ORCID
Yusrina Mat Daud
1 4
ORCID: ORCID
Meor Ahmad Faris
1 2
ORCID: ORCID
Mohd Mustafa Al Bakri Abdullah
1 4
ORCID: ORCID
Farah Farhana Zainal
1 4
ORCID: ORCID
Saloma Hasyim
5
ORCID: ORCID
Muhammad Taqiyuddin Lokman
2

  1. Universiti Malaysia Perlis, Center of Excellence Geopolymer & Green Technology (CEGeoGTech), School of Materials Engineering, (UniMAP), 02600 Jalan Kangar-Arau, Perlis, Malaysia
  2. Universiti Malaysia Perlis, (UniMAP), Faculty of Mechanical Engineering Technology, Perlis, Malaysia
  3. Universiti Malaysia Terengganu, Faculty of Ocean Engineering Technology and Informatic, 21030 Kuala Nerus, Terengganu Darul Iman, Malaysia
  4. Universiti Malaysia Perlis, (UniMAP), Faculty of Chemical Engineering Technology, 02600 Jalan Kangar-Arau, Perlis, Malaysia
  5. Sriwijaya University, Civil Engineering Department, Faculty of Engineering, Indonesia
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Abstract

The article presents the results of research on polymer composites based on polypropylene filled with various fillers. The physical and thermal properties of the composites are the result of the used polymer matrix as well as the properties and geometric features of the used filler. The geometric shape of the filler is particularly important in the processing of plastics in which the flow is forced, and high shearing tension occurs, which determines the high macromolecular orientation and specific arrangement of the filler particles. Thermal analysis (STA) was used in the research and photographs were taken using a scanning electron microscope (SEM) of fractures of polymer composites. The following fillers were used: talc, fibreglass, glass beads, and a halogen-free nitrogen-phosphorus flame retardant. The test material was obtained by extrusion. Shapes for strength tests, which were subjected to scanning microscopy tests after a static tensile test, were obtained by injection. The carried-out tests allowed us to determine the influence of the type and shape of individual fillers on structural changes in the structure of polypropylene composites and the degree of sample weight loss in a specific temperature range, depending on the used filler.
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Authors and Affiliations

Przemysław Postawa
1
Bartłomiej Jeż
1
ORCID: ORCID
Sylwester Norwiński
1
Aleksandra Kalwik
1

  1. Department of Technology and Automation, Faculty of Mechanical Engineering and Computer Science, Czestochowa University of Technology,Al. Armii Krajowej 19c, 42-200 Czestochowa, Poland
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Abstract

This article discusses the rheological tests and analyses based on the Schapery non-linear viscoelasticity model that were performed to study asphalt mastic behaviour under high shear stresses. Seven mineral filler types were applied in this study, including a mixed filler with hydrated lime and fillers derived from dust extraction systems. Determination of basic properties of the fillers was followed by creep and recovery tests (DSR) at different levels of shear stress conducted in accordance with a modified MSCR procedure. The first stage in the analysis was the identification of linear viscoelastic region and the non-linear viscoelasticity model parameters such as the length of the loading period, the temperature and the stress level using TTSSP (Time-Temperature- Stress Superposition Principle). Subsequent numerical simulations of strain variation with respect to stress confirmed a high degree of agreement between the non-linear viscoelasticity model and mastic sample behaviour. A strong correlation was found between the non-linear viscoelasticity parameters and mastic properties. The proposed methodology is able to quickly identify and eliminate the fillers that may contribute to HMA deformations.
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Authors and Affiliations

Grzegorz Mazurek
1
ORCID: ORCID

  1. D.Sc., PhD., Eng., Kielce University of Technology, Aleja Tysiąclecia Państwa Polskiego 7, 25-314 Kielce, Poland
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Abstract

Throughout the world, considerable quantities of water treatment sludge (WTS) and sewage sludge (SS) are produced as waste. This study assessed in the laboratory, the possibility to use both waste products when they are incorporated as filler at 1% with relation to the total mass of a hot mix asphalt - HMA. To this end, both waste products were initially reduced to ash through a calcination process. Resistance tests under monotonic load (Marshall and indirect tension tests), and cyclic load (resilient modulus test) were applied on mixes that contained WTS and SS. Besides, moisture damage (modified Lotmman test), and abrasion (Cantabro) resistance were assessed. An analysis of variance (ANOVA) test was performed in order to verify if the results are statically equal or not to those of the control HMA. As a general conclusion, it is reported that both materials show a resistance increase under monotonic load and higher stiffness under cyclic load (cohesion) when they are incorporated into the mix as filler despite the fact that the asphalt content used was less than the control mix. However, some problems are observed associated with moisture damage resistance, and friction wear (adherence).

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Authors and Affiliations

J.G. Bastidas-Martínez
J. Camapum De Carvalho
L.C. Lucena
M.M. Farias
H.A. Rondón-Quintana
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Abstract

7075-T6 Al and AZ31B Mg dissimilar alloys were friction stir lap welded with or without a Zn filler, and the effect of heat input on the joint quality was systematically studied. The experimental and finite element simulation results displayed that the formation characteristics and microstructures of the joint with or without the Zn filler were significantly affected by the heat input. The tensile shear load of joint with or without the Zn filler increased first and then decreased with the decrease of the welding speed from 200 to 50 mm/min. Moreover, the peak temperature in the stir zone was significantly decreased by the Zn filler addition, and the high temperature zone narrowed along the plate thickness direction. These changes of heat input made that longer mixing region boundary length and larger effective lap width were attained as the Zn filler was used. In addition, due to the replacement of Al-Mg intermetallic compounds (IMCs) by Al-Mg-Zn and Mg-Zn IMCs which were less harmful to the joint, the tensile shear load of the joint with the Zn filler was obviously enhanced compared to that of the joint without the Zn filler at each welding speed. The maximum tensile shear load of 7.2 kN was obtained at the welding speed of 100 mm/min.
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Authors and Affiliations

Huaxia Zhao
1
ORCID: ORCID
Peng Gong
2
ORCID: ORCID
Shude Ji
2
ORCID: ORCID
Xue Gong
2
ORCID: ORCID

  1. AVIC Manufacturing Technology Institute, Beijing 100024, P. R. China
  2. Shenyang Aerospace University, College of Aerospace Engineering, Shenyang 110136, P. R. China
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Abstract

On the basis of research, the mechanisms of dissolution and erosion during brazing of aluminium alloys and the influence of these phenomena on brazed joints of heat exchangers are presented. A number of factors have been identified that affect the formation of these phenomena during brazing aluminium alloys, these include : the maximum temperature and holding time at brazing temperature, and the type and amount of filler metal. The research was supported by examples of dissolution and erosion phenomena during series production of aluminium heat exchangers using three brazing profiles (normal, hot and very hot). It has been found that the dissolution of the engine radiator components during brazing, is from 18 to 68%, depending on the brazing profile used. For a very hot profile, erosion in part of the brazed exchanger, even destroys (removes) thin elements of the cooling fins.
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Bibliography

[1] E . Frąckowiak, W. Mroziński, Using flame brazing technology for producing aluminum automotive heat exchangers, Welding Technology Review 9, 57-62 (2007).
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[16] T. Izumi, T. Ueda, Influence of Erosion Phenomenon on Flow Behavior of Liquid Al-Si Filler Between Brazed Component; 13th International Conference on Aluminum Alloys (ICAA13) Pittsburgh (2012).
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Authors and Affiliations

Z. Mirski
1
ORCID: ORCID
J. Pabian
2
ORCID: ORCID
T. Wojdat
1
ORCID: ORCID

  1. Wroclaw University of Science and Technology, Faculty of Mechanical Engineering, Department of Metal Forming, Welding and Metrology, 27 Wybrzeże Wypiańskiego, 50-370 Wrocław, Poland
  2. Research & Development, MAHLE Behr Ostrów Wielkopolski
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Abstract

Welding of AISI H13 tool steel which is mainly used in mold making is difficult due to the some alloying elements and it high hardenability. The effect filler metal composition on the microstructural changes, phase evolutions, and hardness during gas tungsten arc welding of AISI H13 hot work tool steel was investigated. Corrosion resistance of each weld was studied. For this purpose, four filler metals i.e. ER 312, ER NiCrMo-3, ER 80S, and 18Ni maraging steel were supplied. Potentiodynamic polarization test and electrochemical impedance spectroscopy (EIS) were used to study the corrosion behavior of weldments. It was found the ER 80S weld showed the highest hardness owing to fully martensitic microstructure. The hardness in ER 312 and ER NiCrMo3 weld metals was noticeably lower than that of the other weld metals in which the microstructures mainly consisted of austenite phase. The results showed that the corrosion rate of ER 312 weld metal was lower than that other weld metals which is due to the high chromium content in this weld metal. The corrosion rate of ER NiCrMo-3 was lower than that of 18Ni maraging weld. The obtained results from EIS tests confirm the findings of potentiodynamic polarization tests.
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Bibliography

[1] B. Uddeholm, Bohler-Uddeholm H13 tool steel, 2013.
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[8] A. Skumavc, J. Tušek, M. Mulc, D. Klobčar, Metalurgija. 53 (4), 517-520 (2014).
[9] J . Chen, S.-H. Wang, L. Xue, Mater. Sci. 47 (2), 779-792 (2012).
[10] A. Košnik, J. Tušek, L. Kosec, T. Muhič, Metalurgija. 50 (4), 231-234 (2011).
[11] S. Thompson, Handbook of mould: Tool and die repair welding, 1999 Elsevier.
[12] T. Branza, A. Duchosal, G. Fras, F. Deschaux-Beaume, P. Lours, Mater. Process.
[13] P. Peças, E. Henriques, B. Pereira, M. Lino, M. Silva, Build Futur. Innov. (2006).
[14] L.E.E. Jae-Ho, J. Jeong-Hwan, J.O.O. Byeong-Don, Y.I.M. Hong- Sup, M. Young-Hoon, Trans. Nonferrous Met. Soc. China. 19, 284-287 (2009).
[15] S.U.N. Yahong, S. Hanaki, H. Uchida, H. Sunada, N. Tsujii, Mater. Sci. Technol. 19, 91-93 (2009).
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[17] K . Somlo, G. Sziebig, Ifac-papersonline. 52 (22), 101-107 (2019). [18] J .-L. Desir, Eng. Fail. Anal. 8 (5), 423-437 (2001).
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Authors and Affiliations

Sadegh Varmaziar
1
ORCID: ORCID
Hossein Mostaan
1
ORCID: ORCID
Mahdi Rafiei
2
ORCID: ORCID
Mahdi Yeganeh
3
ORCID: ORCID

  1. Faculty of Engineering, Department of Materials and Metallurgical Engineering, Arak University, Arak 38156-8-8349, Iran
  2. Advanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran
  3. Department of Materials Science and Engineering, Faculty of Engineering, Shahid Chamran University of Ahvaz, Ahvaz, Iran
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Abstract

High temperature vacuum brazing is a well-known and commonly used method for joining of nickel based elements and subassemblies of gas turbines, both for stationary and aviation applications. Despite the fact that currently used brazing filler metals meet stringent requirements of aviation and energetic industries, a lot of effort is spent on improving operational properties of the joints through modification of chemical composition or brazing process parameters. This paper aims for both of these aspects – its purpose is evaluation of the impact of filler metal composition, brazing gap width and process conditions on the microstructure of joints between sheet metal elements made of Hastelloy X nickel superalloy. Two different Ni-based filler materials (BNi-2 and Amdry 915) were investigated, based on the results of light and scanning electron microscopy evaluations, energy dispersive X-ray spectroscopy and hardness measurements.
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Authors and Affiliations

K. Krystek
1 2
ORCID: ORCID
K. Krzanowska
1
ORCID: ORCID
M. Wierzbińska
1
ORCID: ORCID
M. Motyka
1
ORCID: ORCID

  1. Rzeszow University of Technology, Department of Materials Science, 12 Powstańców Warszawy Av., 35-959 Rzeszów, Poland
  2. Pratt & Whitney Rzeszów S.A., 120 Hetmańska Str., 35-078 Rzeszów, Poland

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