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Abstract

The main subject of research in this paper is glauconite with its useful parameters, which is the object of exploitation in the “Górka Lubartowska-Niedźwiada” deposit. The main glauconitic horizon (lower Eocene) is built by loamy fine-grained and medium greenish sands with marine fauna and fragments of amber (ca. 7 m thick). Thin lamins and pockets of silts containing phosphorites and also glauconitic sands with underlaying very thin quartz-glauconitic sands are found at the bottom of this layer. The glauconite deposit in “Górka Lubartowska-Niedźwiada” is an amount of ca. 30% by volume of the main glauconitic horizon. Glauconite of the 1M polytype (XRD) shows large granulometric and morphological differentiation (SEM-EDS). It frequently contains aggregations of euhedral or framboidal pyrite grains (RS), which is indicative of the euxinic nature of the formation environment of the rocks under study. The individual glauconite grains show distinct chemical variability, manifested in a lower share of Al2O3 and an increased content of MgO and CaO (EPMA, XRF). At the same time, a large share of K2O (above 8% by weight) allows it to be included in highly matured glauconite, thus it can be considered as a potential raw material for the production of mineral fertilizers. The association of glauconite with phosphates (SEM-EDS) and anatase inclusions in the grains of glauconite (RS) indirectly point to the contribution of the decomposing organic matter to the formation of grains of this mineral. The xylite fragments preserved in the sediment show a low degree of coalification, which is typical of soft lignite. This also shows that the transformation process was taking place under a relatively small overburden.

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Authors and Affiliations

Lucyna Natkaniec-Nowak
Adam Piestrzyński
Marian Wagner
Wiesław Heflik
ORCID: ORCID
Beata Naglik
Jan Paluch
Krzysztof Pałasz
Stanislava Milovská
Paweł Stach
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Abstract

The analysis of ecological hazards on soil pollution by oil products has been provided in the impact zone of the railway. The results of oil product migration in soils in the area of influence on section Lviv–Khodoriv are given. To study this problem, a method was used to take soil samples according to the standard DSTU ISO 10381-4: 2005. To determine the content of petroleum products used the method MVV No. 081/12-0116-03 Pochvy. Based on the results of the study it was found that contamination with petroleum products in the study area exceeds the norm in the area of influence of the railway at a distance of 5 to –50 m on average 3.5 times. It is proposed to make management decisions to prevent violations of the sanitary protection zone of the railway and the placement of agricultural plots on it. For rehabilitation of contaminated soils, it is advisable to use a natural sorbent – glauconite, which is widespread in the bowels of Ukraine. The adsorption capacity of glauconite relative to diesel fuel has been experimentally established. According to our experiments it is proved the high efficiency of the proposed sorbent, which is 90%. Therefore, in the future it is necessary to periodically monitor the condition of the soil in the area to prevent pollution. This study proves that this practice is necessary.
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Authors and Affiliations

Oksana Chayka
1
ORCID: ORCID
Igor Petrushka
1
ORCID: ORCID
Maria Ruda
1
ORCID: ORCID
Nadiya Paranyak
1
ORCID: ORCID
Olena Matskiv
1
ORCID: ORCID

  1. Lviv National Polytechnic University, Faculty of Ecological Safety and Environmental Protection, Stepana Bandery St, 12, Lviv, Lviv Oblast, 79000, Ukraine

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