Strength and permeability properties along with microstructural evolution of hardened slurries composed of fly ash from fluidal bed combustion of brown coal and an addition of OPC/BFSC is assessed in this paper. An increase in the amount of fly ash in slurries influences the development of mechanical strength and a decrease of hydraulic conductivity. SEM, XRD, and porosity analyses confirmed formation of watertight microstructures. The structure of slurries is composed of ettringite, C-S-H phase, AFt, and AFm phases. Ettringite crystallises as relatively short needles forming compact clusters or intermixed with the C-S-H phase. The occurring C-S-H phases are mainly of type I – fibrous and type II – honeycomb
The numerical algorithm of thermal phenomena is based on the solution of the heat conduction equations in Petrov-Galerkin’s formula using the finite element method. In the modeling of phase transformation in the solid state, the models based on the diagrams of continuous heating and continuous cooling (CHT and CCT). In the modeling of mechanical phenomena, equations of equilibrium and constitutive relationships were adopted in the rate form. It was assumed that the hardened material is elastic-plastic, and the plasticizing can be characterized by isotropic, kinematic or mixed strengthening. In the model of mechanical phenomena besides thermal, plastic and structural strains, the transformations plasticity was taken into account. Thermo-physical size occurring in the constitutive relationship, such as Young’s modulus and tangential modulus, while yield point depend on temperature and phase composition of the material. The modified Leblond model was used to determine transformation plasticity. This model was supplemented by an algorithm of modified plane strain state, advantageous in application to the modeling of mechanical phenomena in slender objects. The problem of thermoelasticity and plasticity was solved by the FEM. In order to evaluate the quality and usefulness of the presented numerical models, numerical analysis of temperature fields, phase fractions, stresses and strains was performed, i.e. the basic phenomena accompanying surface layer of progressive-hardening with a movable heat source of slender elements made of tool steel for cold work.
Based on laboratory tests of selected properties of secondary waste (ashes and dusts) from municipal waste incineration plants, the possibility of recovering some properties of waste in the process of filling the post-mining voids in the salt mine was assessed. The furnace bottom ash and the waste from the flue gas treatment from one of the national incineration plants were examined. The grain curves of dry waste and the density of the prepared mixtures were characterized. Twelve variants of the compositions of ash-based mixtures with varying proportions of the individual components were considered, taking into account both fresh water and brine. For each variant of the composition, the amount of redundant liquid appeared as well as the time of solidifying of the mixture to a certain strength and the compressibility values obtained. Considering the possibility of transporting mixtures in mines by means of pipelines at relatively long distances, and allowing the filling of large salt chambers to be filled and evenly filled, flow parameters were determined. In addition, the permeability of solidified waste samples was investigated, showing the potential for reducing the strength of the waste mass due to the action of water or brine. The technical feasibility of eliminating redundant liquid in the binding process has been confirmed, which is particularly important in salt mines. Preliminary values for the amount of binder (5%÷10%) to be added to the mixtures to obtain the specified strength properties of the artificially formed mass at Rc = 0.5 MPa. Attention was paid to the important practical aspect resulting from the rapid increase of this type of waste in the comming years in Poland and at the same time vast potential for their use in salt mining, where we have a huge capacity of salt chambers available.
The contributions of work-hardening of austenite and the presence of martensite on the hardening of an AISI 304L stainless steel were evaluated based on plastic deformation under different reductions in thickness at two rolling temperatures. The cold deformation temperatures of 300 K and 373 K were chosen to induce strain-hardening plus strain-induced martensitic transformation in the former and strain-hardening in the latter. This made it possible to elucidate the real effects of strengthening mechanisms of metastable austenitic stainless steels during mechanical working.
In the paper, the authors present the approach to modelling of austenitic steel hardening basing on the Frederick-Armstrong’s rule and Chaboche elastic-plastic material model with mixed hardening. Non-linear uniaxial constitutive equations are derived from more general relations with the assumption of an appropriate evolution of back stress. The aim of the paper is to propose a robust and efficient identification method of a well known material model.
A typical LCF strain-controlled test was conducted for selected amplitudes of total strain. Continuous measurements of instant stress and total strain values were performed. Life time of a specimen, signals amplitudes and load frequency were also recorded.
Based on the measurement, identification of constitutive equation parameters was performed. The goal was to obtain a model that describes, including hardening phenomenon, a material behaviour during the experiment until the material failure. As a criterion of optimisation of the model least square projection accuracy of the material response was selected.
Several optimisation methods were examined. Finally, the differential evolution method was selected as the most efficient one. The method was compared to standard optimisation methods available in the MATLAB environment. Significant decrease of computation time was achieved as all the optimisation procedures were run parallel on a computer cluster.
In view of the permanent increase of the municipal solid waste incineration (MSWI) residues amount,
the numerous attempts to find a way of their recovery have been undertaken. In this paper the idea of the
recovery of the MSWI residues in Kłodawa salt mine is presented. The idea is to fill the waste in underground
workings, close and/or backfill the underground excavations with self-solidifying mixture prepared
on the basis of MSWI grained solid residues. Two techniques are proposed: 1) hydraulic backfill technique
(HBT) where the mixture is prepared in the surface installation and pumped down into the underground
workings through shaft and the pipelines and 2) dry waste technique (DWT), where dry grained waste is
dropped into the mine by pneumatic pipeline transport, then supplied to the underground mixture-preparing-
installation and pumped as a thin liquid or paste into the selected workings. The description of the
technology is preceded by general characteristic of the hardening backfill in underground mines and by
characteristic of MSWI residues, drafted on the basis of the literature review.
This article presents test results for hydraulic conductivity and porosity structure of hardening slurries prepared of Portland cement, betonite, water and fluidal ashes from the combustion of hard and brown coal. The slurries were exposed to persistent filtering action (180 days) of liquids chemically aggressive to cement binders, i.e. distilled water, 0.5% solution of nitric acid, 1% solution of sodium sulphate, 1% solution of magnesium nitrate and 1% solution of ammonium nitrate. Samples exposed to filtration of tap water constituted the reference base. The research was into relations between hydraulic conductivity and pore structure parameters in slurries, as well as into the influence of the type of aggressive medium on leak tightness of slurries (their porosity and hydraulic conductivity).
In the paper, an attempt is made to explain the previously observed increased effectiveness of utilising hydrated sodium water-glass grade
137 after hardening moulding sands with selected physical methods. In the modified process of preparing sandmixes, during stirring
components, water as a wetting additive was introduced to the sand-binder system. Presented are examination results of influence of faster
microwave heating and slower traditional drying of the so-prepared moulding sands on their tensile and bending strength, calculated per
weight fraction of the binder. The measurement results were confronted with SEM observations of linking bridges and with chemical
analyses of grain surfaces of high-silica base. On the grounds of comprehensive evaluation of hardened moulding sands, positive effects
were found of the applied physical process of binder dehydration and presence of the wetting additive. It was observed that introduction of
this additive during stirring, before adding the binder, improves flowing the binder to the places where durable linking bridges are created.
It was also found that the applied methods of hardening by dehydration enable creation of very durable linking bridges, strongly connected
with the sand base, which results in damages of high-silica grain surfaces, when the bridges are destroyed.
Measurements of the hardening process of the selected self-setting sands are presented in the hereby paper. Moulding sands were prepared
on the matrix of „Szczakowa” sand of the Sibelco Company. Two resins: phenol-formaldehyde-furfuryl (FF/AF) and urea-formaldehydefurfuryl
(MF/AF) were used for making moulding sands. – Methylbenzene-sulphonic acid was applied as a hardener for the moulding sand
on FF/AF resin, while paratoluene-sulphonic acid for the moulding sand on MF/AF resin. Both hardeners were used in two concentrations:
low – the so-called ‘slow’ hardener and high - ‘fast’ hardener. During investigations, the courses of the hardening process were
determined, more accurately changes of the velocity of the ultrasound wave passage through the moulding sand cL = f(t) and changes of
the moulding sand hardening degree versus time, Sx = f(t). In addition, the kinetics of the hardening process was determined.
Measurements were performed on the research stand for ultrasound investigations.
One type of spheroidal cast iron, with additions of 0.51% Cu and 0.72% Ni, was subjected to precipitation hardening. Assuming that the
greatest increase in hardness after the shortest time of ageing is facilitated by chemical homogenisation and fragmentation of cast iron
grain matrix, precipitation hardening after pre-normalisation was executed. Hardness (HB), microhardness (HV), qualitative and
quantitative metalographic (LM, SEM) and X-ray structural (XRD) tests were performed. The acquired result of 13.2% increase in
hardness after ca. 5-hour ageing of pre-normalised cast iron confirmed the assumption.