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Abstract

In the last decade a growing interest was observed in low-cost adsorbents for heavy metal ions. Clinoptilolite is a mineral sorbent extracted in Poland that is used to remove heavy metal ions from diluted solutions. The experiments in this study were carried out in a laboratory column for multicomponent water solutions of heavy metal ions, i.e. Cu(II), Zn(II) and Ni(II). A mathematical model to calculate the metals' concentration of water solution at the column outlet and the concentration of adsorbed substances in the adsorbent was proposed. It enables determination of breakthrough curves for different process conditions and column dimensions. The model of process dynamics in the column took into account the specificity of sorption described by the Elovich equation (for chemical sorption and ion exchange). Identification of the column dynamics consisted in finding model coefficients β, KE and Deff and comparing the calculated values with experimental data. Searching for coefficients which identify the column operation can involve the use of optimisation methods to find the area of feasible solutions in order to obtain a global extremum. For that purpose our own procedure of genetic algorithm is applied in the study.

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Authors and Affiliations

Elwira Tomczak
Władysław Kamiński
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Abstract

The biodiversity of aqueous environments has been affected due to the disposal of wastewater highly contaminated with heavy metal ions, causing much damage to ecosystems. These pollutants are very toxic and bioaccumulate in living organisms. This work attempts to evaluate the adsorption of nickel ad cadmium ions using three biomasses from agricultur-al residues (corn cob – CC, orange peel – OP, and oil palm bagasse – PB) modified with alumina nanoparticles. The bio-masses were characterized via compositional analysis and a point of zero charges to quantify the presence of lignin, cellu-lose, hemicellulose, and the feasible pH, taking advantage of the biomass charge. After modification with Al2O3 nanoparti-cles. The resulting adsorbents were characterized via FT-IR analysis to identify the functional groups that most contributed to the adsorption performance. Furthermore, the influence of Al2O3 nanoparticles was analysed on the adsorption capacities of the evaluated biomasses using batch systems at a temperature of 25°C and pH 6. All biomasses displayed a high content of cellulose, estimating a weight percentage of about 19.9%, 14.3%, and 13.1% for PB, OP, and CC samples, respectively. The FT-IR spectrum confirmed hydroxyl and carboxyl functional groups, which contribute to enhancing the adsorption capacities of the modified biomasses. Functional adsorption capacity was observed for all biomasses after modification with Al2O3 nanoparticles, achieving at pH 6.0 a cadmium removal from 92% (CC-Al2O3 and PB-Al2O3) up to 95.8±0.3% (OP-Al2O3). In nickel ions, it was estimated a broader adsorption capacity at pH 6.0 of about 86±0.4% after using the CC-Al2O3 sample, 88±0.1% for the PB-Al2O3 adsorbent, and 98±0.2% for the OP-Al2O3 sample, confirming the suitability of these Al2O3-modified biomasses for the removal of heavy metal ions.
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Authors and Affiliations

Adriana Herrera-Barros
1
ORCID: ORCID
Candelaria Tejada-Tovar
1
ORCID: ORCID
Angel D. Gonzalez-Delgado
1
ORCID: ORCID

  1. University of Cartagena, Avenida del Consulado Calle 30 No. 48-152, Cartagena, Bolívar, Colombia
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Abstract

The study has investigated the technical characteristics of a number of sorption materials (natural mineral) and the pos-sibility of their use for the purification of surface and wastewater from oil and oil products. At the first step, regularities of the process of purification of oily waters have been established taking into account the processes of filtration and sorption. After that, the sorption capacity of the sorbents has been estimated, and the factors influencing it analysed. As a final step, the optimal conditions for the sorption process have been selected depending on the conditions and nature of purification. Results indicated that the maximum purification degree has been reached at the concentration of 500 mg∙dm–3 and temper-ature of 20°С.
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Authors and Affiliations

Saltanat T. Tleuova
1
ORCID: ORCID
Banu A. Userbayeva
2
ORCID: ORCID
Alibek S. Tleuov
1
ORCID: ORCID
Marina M. Yeskendirova
1
ORCID: ORCID
Raissa R. Yakubova
1
ORCID: ORCID
Kulyash Z. Kerimbayeva
2

  1. M. Auezov South Kazakhstan State University, Department of Chemical Technology of Inorganic Substances, Tauke khan aven, 5, Shymkent, 160012, Kazakhstan
  2. South Kazakhstan State Pedagogical University, Department of Chemistry, Shymkent, Kazakhstan

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