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Number of results: 8
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Abstract

The paper presents the results of preliminary studies on the properties of products made by vitrification of waste containing fly ashes from sewage sludge incineration. The performed tests of hazardous substances leached from the ashes, as well as the results of other laboratory tests confirmed the efficacy of vitrification. It has been found that the resulting products (sinters) could be used as a substitute aggregate for road foundations.

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Authors and Affiliations

G. Borowski
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Abstract

Bioleaching research considers both the bio- and anthroposphere in the search for novel ways to recover resources and elements, which is important to the concept of sustainable development. Since the efficient, cost-effective and simple recovery of resources is of increasing importance in the circular economy model, the bioleaching of metals is a method currently gaining interest. The process is also of importance considering the need for the neutralization of waste materials/resources that allow for their safe storage and use. In this study, Acidithiobacillus thiooxidans bacteria, which is commonly found and widely utilized in the bioleaching process due to its high tolerance to heavy metals, was used in a twenty-eight-day experiment. The manner in which bacteria inhabit incineration residues was observed using fluorescence optical microscopy and scanning electron microscopy. The concentration of elements in incineration residues and in the post-reaction solutions was measured using inductively coupled plasma mass spectrometry and the efficiency of element recovery was calculated based on the results. Municipal waste incineration bottom ash and sewage sludge incineration fly ash were considered in the experiment. The extraction rates were far from satisfactory, with the average 20 and 50% for bottom ash and sewage sludge ash, respectively. The obtained results were consistent with microscopic observations where the relative number of bacteria increased only slightly over time in the sewage-sludge fly ash and was barely observed in the bottom ash of municipal- -waste incineration.
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Authors and Affiliations

Monika Kasina
1
ORCID: ORCID
Kinga Jarosz
1
ORCID: ORCID
Klaudiusz Salamon
1
ORCID: ORCID
Adam Wierzbicki
1
ORCID: ORCID
Bartosz Mikoda
1
ORCID: ORCID
Marek Michalik
1
ORCID: ORCID

  1. Jagiellonian University, Kraków, Poland
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Abstract

For a very long period of time, Polish waste management was based mainly on landfilling at landfills, which had a negative impact on the surrounding environment. The EU requirements for the Member States have led to a revolution in Polish legislation on waste management and local governments have become responsible for creating local waste management systems that will affect the achievement of EU targets. One of the solutions undertaken by several municipalities is the construction and operation of a municipal waste thermal treatment installation, which not only reduced the amount of waste deposited, but also supported the local power industry by generating electricity and heat. The emission standards for installations producing energy from waste, as in the case of conventional power plants and combined heat and power plants, are very strict, therefore, the continuous monitoring of emitted pollutants is carried out, and waste gas treatment systems are developed based on the best available techniques (BAT). The article presents emission standards applicable to waste incineration plants, including duties in the field of the environment, as well as issues related to the installation as a source of energy. In addition, the currently functioning waste incineration plants in Poland have been briefly characterized, and development plans in this area in the country have been described.

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Authors and Affiliations

Jagoda Gołek-Schild
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Abstract

Laboratory works on combustion of some organic compounds as air pollutants in presence of platinum, palladium and manganese catalysts at various oxygen concentrations were carried out. Several mixtures of nitrogen and oxygen contained vapours of hexane, isooctane, methanol, acetone ethyl acetate and toluene were examined. The experimental results show that conversion efficiency of 95% might be reached, despite of oxygen concentration decreasing to 5%.
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Authors and Affiliations

Walter Mucha
Jan Konieczyński
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Abstract

The article presents the results of plasma vitrification of solid remnants from thermal waste treatment with and without the addition of a carbonate fraction obtained from lead-zinc ore flotation. The substrates used in the research were slags and ashes from medical waste treatment, incineration of municipal waste, sewage sludge as well as hazardous and industrial wastes.

The plasma treatment resulted in acquiring products of different quality depending on the processed substrate. Most of the obtained products were of vitreous and homogenic build. Treatment of remnants from incineration of hazardous and industrial wastes resulted in obtaining heterogeneous and rough surfaced products. A 20% share of the carbonate fraction enabled the obtaining of a vitrified product with a glassy surface and fracture. Hardness of the obtained products was rated in Mohs scale and ranged from 6 to 6,5. Leaching tests showed a decrease in heavy metal concentration in the leachates from vitrificates with the addition of carbonate fraction compared to the ones with it.

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Authors and Affiliations

January Bień
Bartosz Morzyk
Katarzyna Wystalska
Piotr Celary
Jolanta Sobik-Szołtysek
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Abstract

Samples of active coke, fresh and spent after cleaning flue gases from communal waste incinerators, were studied. The outer layers of both coke particles were separately removed by comminution mechanism in a spouted bed. Analyses included density, mercury porosimetry and adsorption. The remaining cores were examined to determine the degree of consumption of coke by adsorption of hazardous emissions (SO2, HCl, heavy metals) through its bed. The differences in contamination levels within the porous structure of the particles were estimated. The study demonstrated the effectiveness of active coke in the cleaning of flue gases.

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Authors and Affiliations

Bronisław Buczek
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Abstract

This study focused on the reclamation of ash from incineration process and development of new artificial lightweight aggregate (LWA) that have comparable properties with existing natural coarse aggregate. The main objective of this study is to examine potential use of recycled municipal solid waste incineration (MSWI) ash as raw material in LWA production with a method of cold-bonded pelletization. Two types of incineration ash which is bottom ash (BA) and fly ash (FA) were collected from Cameron Highland Incineration Plant, Malaysia. The properties of BA and FA are studied by means of X-Ray Fluorescence (XRF) and microstructure of these ashes were inspected using Scanning Electron Microscope (SEM). The properties of BALA and FALA produced in this study is examined including loose bulk density, water absorption and aggregate impact value (AIV). From the results of both types of artificial LWA, the lowest loose bulk density of BALA is BALA50 with 564.14 kg/m3 and highest is at 831.19 kg/m3. For FALA50, lowest loose bulk density is 573.64 kg/m3 and highest is 703.35 kg/m3. Water absorption of BALA and FALA is quite similar with one another in with the value of 23.8% and 22.6%, respectively. Generally, FALA have better qualities of LWA comparing with BALA with lower bulk density and water absorption and can be categorized as strong aggregate. In summary, reclamation and reutilization of incinerator ash has generated acceptable qualities for artificial LWA. Both types of BA and FA shown a great potential to be recycled as additional materials in artificial aggregate production.
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Authors and Affiliations

Norlia Mohamad Ibrahim
1 2
ORCID: ORCID
Roshazita Che Amat
1 2
ORCID: ORCID
Mustaqqim Abdul Rahim
1
ORCID: ORCID
Nur Liza Rahim
1 2
ORCID: ORCID
Abdul Rahim Abdul Razak
3
ORCID: ORCID

  1. Universiti Malaysia Perlis (UniMAP), Faculty of Civil Engineering Technology, Perlis, Malaysia
  2. Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Center of Excellence Geopolymer and Green Technology, Perlis, Malaysia
  3. Universiti Malaysia Perlis (UniMAP), Faculty of Electrical Engineering Technology, Perlis, Malaysia
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Abstract

Municipal waste is a global issue and they are generated in all countries around the world. Both in the European Union and the United States, a common method of non-recyclable waste utilization is thermal incineration with energy recovery. As a result of this treatment, residual waste like bottom ash, air pollution control residues and fly ashes are generated. This research shows that residues from waste incineration can be a potential source of critical raw materials. The analysis of the available literature prove that the residues of municipal waste incinerators contain most of the elements important for the US and EU economies. Material flow analysis has shown that each year, the content of elemental copper in residues may be 29,000 Mg (USA) and 51,000 Mg (EU), and the amount of rare earth elements in residues exceeds their mining in the EU. In the case of other elements, their content may exceed their extraction by even over 300%. The recovery of elements is difficult due to their encapsulation in the aggregate matrix. The heterogeneous nature of residues and the many interactions between different components and incineration techniques can make the process of recovery complicated. Recovery plants should process as much of the residues as possible to make their recovery profitable. However, policy makers from the EU and the US are introducing new legal regulations to increase the availability of critical raw materials. In the EU, new regulations are planned that will require at least 15% of the annual consumption of critical raw materials to come from recycling. Therefore, innovative technologies for recovering critical raw materials from waste have a chance to receive subsidies for research and development.
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Authors and Affiliations

Radosław Jędrusiak
1
ORCID: ORCID
Barbara Bielowicz
2
ORCID: ORCID
Agnieszka Drobniak
3 4
ORCID: ORCID

  1. Krakowski Holding Komunalny Spółka Akcyjna w Krakowie; AGH University of Kraków, Poland
  2. AGH University of Kraków, Poland
  3. University of Silesia in Katowice, Poland
  4. Indiana University, Indiana Geological and Water Survey; United States

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