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Number of results: 7
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Abstract

The present studies aimed at comparing the effect of the potassium monoionic form (prepared from a model spent ion exchanger) and a conventional potassium fertilizer (KCI) on plant vegetation after addition to depleted soil. To achieve the study aim a pot experiment using orchard grass (Dacrylis glomerata L.) as the test plant was carried out. The vegetation cycle lasted seven weeks. The plants were grown on four series of media: on untreated soil, on soil with added monoionic K form, on soil with added KCI and on soil with Biona-312 substrate added (2% v/v). Biona-312 served as the control fertilizer containing all macro- and microelements. The application of monoionic potassium form positively influenced orchard grass vegetation. The addition of K form into soil increased stem wet and dry biomass, root dry biomass and total dry yield by 15, 10, 13 and 12%, respectively. Bearing in mind that the amount of dry plant matter as source material for humus formation is crucial in soil reclamation, the effectiveness of potassium monoionic form was found to be similar to that of the mineral fertilizer - KCI. Biona-312 was the most efficient fertilizer used in the study, resulting in the greatest yield of Dactylis glomerata L.
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Authors and Affiliations

Magdalena Zdeb
Mariola Chomczyńska
Vladimir S. Soldatov
Lucjan Pawłowski
ORCID: ORCID
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Abstract

The paper presents an impact of the metallurgical wastes dumping site on the following parts of the environment: air, soil and surface waters. Some of the methods used to prevent wastes interactions were showed. The results of the metallurgical wastes leachate samples research, in which toxic metal ions have been found, are presented results of examinations performed on water extracts derived from two types of metallurgical wastes were given. The chemical analysis of water extracts indicate exceeded concentration of toxic metals, such as: lead, arsenic, barium and others. Preliminary results of some metals elimination from the water extracts with PUROLITE ion-exchangers were also presented. The utilised acidous cationit with Na+ groups exchanges the Ba2+ ions in almost 90%, similar to S 930 ionit with chelating groups (Table 5 and 7). Whereas the anionit with hydroxyl groups removes the arsenic ions(V) from the solution with the 60% efficacy (Table 7).

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Authors and Affiliations

Stanisława Sanak-Rydlewska
Agnieszka Gala
Łukasz Wajda
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Abstract

As a rule, nitrates are present in all natural water bodies. Their increased concentrations are connected with the discharge of insufficiently treated wastewater from industrial and communal enterprises, agricultural and livestock complexes. Recent scientific publications concerning treatment methods for nitrates removal from natural water and wastewater were analyzed in order to create effective and low-waste technology for obtaining high quality water. It has been established that the ion exchange method is quite effective for removing nitrates from water. In the paper, the processes of ion exchange removal of nitrates from water on low-axis anionite in DOWEX Marathon WBA in Сl- form were investigated. During the sorption of nitrates with a concentration of 186, 205, 223 and 2200 mg/dm3, it was established that the full exchangeable dynamic capacity was 1.075, 1.103, and 1.195, 1.698 g-eq/dm3, respectively. To regenerate anionite, solutions of ammonia as well as potassium chloride, ammonium chloride and potassium carbonate were used in this work. The choice of potassium and ammonium compounds is due to the prospect of further use of regeneration solutions for the production of liquid fertilizers.
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Bibliography

  1. Alguacil-Duarte, F., González-Gómez, F. & Romero-Gámez, M. (2022). Biological nitrate removal from a drinking water supply with an aerobic granular sludge technology: An environmental and economic assessment. Journal of Cleaner Production, 367. DOI:10.1016/j.jclepro.2022.133059
  2. Bodzek, M. (2019). Membrane separation techniques – removal of inorganic and organic admixtures and impurities from water environment – review. Archives of Environmental Protection, 45, 4, pp. 4–19. DOI:10.24425 / aep.2019.130237.
  3. Boubakri, A., Al-Tahar Bouguecha, S. & Hafiane, A. (2022). FO–MD integrated process for nitrate removal from contaminated groundwater using seawater as draw solution to supply clean water for rural communities. Separation and Purification Technology, 298. DOI:10.1016/j.seppur.2022.121621
  4. Gutiérrez, M., Biagioni, R.N., Alarcón-Herrera, M.T. & Rivas- Lucero, B.A. (2018). An overview of nitrate sources and operating processes in arid and semiarid aquifer systems. Science of the Total Environment, 624, pp. 1513–1522. DOI:10.1016/j. scitotenv.2017.12.252
  5. Hansen, B., Sonnenborg, T.O., Møller, I., Bernth, J.D., Høyer, A., Rasmussen, P., Sandersen P.B.E. & Jørgensen, F. (2016). Nitrate vulnerability assessment of aquifers. Environmental Earth Sciences, 75, 12. DOI:10.1007/s12665-016-5767-2
  6. Kaushal, S.S. (2016). Increased salinization decreases safe drinking water. Environ. Sci. Technol., 50, pp. 2765–2766. doi:10.1021/ acs.est.6b00679.
  7. Królak, E. & Raczuk, J. (2018). Nitrate concentration-related safety of drinking water from various sources intended for consumption by neonates and infants. Archives of Environmental Protection, 44, 1, pp. 3–9. DOI:10.24425/118176
  8. National report on drinking water quality and drinking water supply in Ukraine in 2021. Database ‘Ministry of Regional Development of Ukraine’ (in Ukrainian).
  9. Nujić, M., Milinković, D. & Habuda-Stanić, M. (2017). Nitrate removal from water by ion exchange. Croatian journal of food science and technology, 9, 2, pp. 182–186. DOI:10.17508/ CJFST.2017.9.2.15
  10. Preetham, V. & Vengala, J. (2023). Adsorption isotherm, kinetic and thermodynamic studies of nitrates and nitrites onto fish scales. In Recent Advances in Civil Engineering, pp. 429–442. doi:10.1007/978-981-19-1862-9_27
  11. Remeshevska, I., Trokhymenko, G., Gurets, N., Stepova, O., Trus, I. & Akhmedova, V. (2021). Study of the ways and methods of searching water leaks in water supply networks of the settlements of Ukraine. Ecological Engineering and Environmental Technology, 22, 4, pp. 14–21. DOI:10.12912/27197050/137874
  12. Song, Q., Zhang, S., Hou, X., Li, J., Yang, L., Liu, X. & Li, M. (2022). Efficient electrocatalytic nitrate reduction via boosting oxygen vacancies of TiO2 nanotube array by highly dispersed trace cu doping. Journal of Hazardous Materials, 438. DOI:10.1016/j. jhazmat.2022.129455
  13. Trus, I., Gomelya, M., Skiba, M., Pylypenko, T. & Krysenko, T. (2022). Development of Resource-Saving Technologies in the use of sedimentation inhibitors for reverse osmosis installations. J. Ecol. Eng., 23(1), pp. 206–215. DOI:10.12911/22998993/144075
  14. Trus, I. (2022). Optimal conditions of ion exchange separation of anions in low-waste technologies of water desalination. Journal of Chemical Technology and Metallurgy, 57, 3, pp. 550–558.
  15. Trusa, I. M., Gomelya, M. D. & Tverdokhlib, M. M. (2021). Evaluation of the contribution of ion exchange in the process of demanganization with modified cation exchange resin ku-2- 8. Journal of Chemistry and Technologies, 29, 4, pp. 540–548. DOI:10.15421/jchemtech.v29i4.242561
  16. Trus, I. & Gomelya, M. (2022). Low-waste technology of water purification from nitrates on highly basic anion exchange resin. Journal of Chemical Technology and Metallurgy, 57, 4, pp. 765–772. https://dl.uctm.edu/journal/node/j2022-4/14_21- 93_br4_2022_pp765-772.pdf
  17. Trusb, I., Gomelya, M., Skiba, M. & Vorobyova, V. (2021). Promising method of ion exchange separation of anions before reverse osmosis. Archives of Environmental Protection, 47, 4, pp. 93–97. DOI:10.24425/aep.2021.139505
  18. Trus, I., Gomelya, N., Halysh, V., Radovenchyk, I., Stepova, O. & Levytska, O. (2020). Technology of the comprehensive desalination of wastewater from mines. Eastern-European Journal of Enterprise Technologies, 3(6–105), pp. 21–27. DOI:10.15587/1729-4061.2020.206443 Vasilache, N., Cruceru, L., Petre, J., Chiriac, F. L., Paun, I., Niculescu, M., Pirvu F. & Lupu, G. (2018). The removal of nitrate from drinking water, natural water by ion exchange using ion exchange resin, purolite A520E and A500. Iternational Symposium “The Environment and the Industry”, SIMI 2018, Proceedings Book DOI:10.21698/simi.2018.fp53 Voutchkova, D.D., Schullehner, J., Rasmussen, P. & Hansen, B. (2021). A high-resolution nitrate vulnerability assessment of sandy aquifers (DRASTIC-N). Journal of Environmental Management, 277. DOI:10.1016/j.jenvman.2020.111330 Ward, M.H., Jones, R.R., Brender, J.D., de Kok, T.M., Weyer, P. J., Nolan, B. T., Vilanueva C.M. & van Breda, S.G. (2018). Drinking water nitrate and human health: An updated review. International Journal of Environmental Research and Public Health, 15, 7. DOI:10.3390/ijerph15071557 Wiśniowska, E. & Włodarczyk-Makuła, M. (2020). Removal of nitrates and organic compounds from aqueous solutions by zero valent (ZVI) iron reduction coupled with coagulation/ precipitation process. Archives of Environmental Protection, 46, 3, pp. 22–29. DOI: 10.24425 / aep.2020.134532.
  19. Zabłocki, S., Murat-Błażejewska, S., Trzeciak, J.A. & Błażejewski, R. (2022). High-resolution mapping to assess risk of groundwater pollution by nitrates from agricultural activities in Wielkopolska Province. Poland. Archives of Environmental Protection, 48, 1, pp. 41–57. DOI:10.24425/aep.2022.140544
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Authors and Affiliations

Inna Trus
1
ORCID: ORCID
Mukola Gomelya
1
ORCID: ORCID
Vita Halysh
1
ORCID: ORCID
Mariia Tverdokhlib
1
ORCID: ORCID
Iryna Makarenko
1
Tetiana Pylypenko
1
ORCID: ORCID
Yevhen Chuprinov
2
ORCID: ORCID
Daniel Benatov
1
ORCID: ORCID
Hennadii Zaitsev
2

  1. National Technical University of Ukraine «Igor Sikorsky Kyiv Polytechnic Institute», Kyiv, Ukraine
  2. State University of Economics and Technology: Kryvyi Rih, Ukraine
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Abstract

The present study aimed at a determination of the formula allowing water content to be calculated for model degraded soil enriched with Biona-312 ion exchange substrate. To this end a mixture of sand and Biona- 312 was prepared which was monitored for water content changes. Moisture was determined both gravimetrically and reflectometrically (TOR method). To improve the reliability of the TOR method individual calibration was made. The specific calibration formula as polynomial of the third degree was found for water content determination in sand supplemented with Biona-312. The results confirmed the high potential of the TOR method in moisture monitoring, especially when individual calibration is done.
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Authors and Affiliations

Mariola Chomczyńska
Zbigniew Suchorab
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Abstract

The accumulation and removal of the heavy metals (Cd, Cr, Cu, Ni, Pb, Zn) by fibrous ion exchangers at different stages of a typical biological wastewater treatment system, have been studied. In particular, the chelating ion exchanger FIBAN X- I allows rapid and efficient sorption of the heavy metals from primary treated effluents. The degree of removal of Cu ion wa, about 17%; for both Cd and Pb the removal efficiency wa, >40%. Applied in batch process mode FIBAN X-1 should diminish the content of heavy metals in sewage and treated effluent.
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Authors and Affiliations

Henryk Wasąg
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Abstract

A method to improve the quality of purifi ed water, reduce the cost of reagents for the regeneration of resin and create low-waste processes have been developed. This paper presents the results of ion exchange separation of sulfates and nitrates using AV-17-8 anion exchange resin in NO3 form. The effi ciency of anion separation on the highly basic anion exchange resin AV-17-8 depends on the magnitude and ratio of their concentrations in water. Separation on the AV-17-8 anion exchange resin has been shown to be eff ective at concentrations of sulfates up to 800 mg/dm3 and nitrates up to 100 mg/dm3. Conditions for regeneration of 10% NaNO3 anion exchange resin were determined. Reagent precipitation of sulfates from the used regeneration solution in the form of calcium sulfate was carried out. Calcium sulfate precipitate can be used in the manufacturing of building materials. The regeneration solution is suitable for reuse. The developed results will allow to introduce low-waste desalination technology of highly mineralized waters.
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Bibliography

  1. Berbar, Y., Amara, M. & Kerdjoudj, H. (2008). Anion exchange resin applied to a separation between nitrate and chloride ions in the presence of aqueous soluble polyelectrolyte, Desalination, 223, 238–242.
  2. Berger, E., Fro¨r, O. & Schäfer, R.B. (2019). Salinity impacts on river ecosystem processes: a critical mini-review, Phil. Trans. R. Soc. B, 374, 20180010. DOI:10.1098/rstb.2018.0010.
  3. Bodzek, M. (2019). Membrane separation techniques – removal of inorganic and organic admixtures and impurities from water environment – review, Archives of Environmental Protection, 45 , 4, pp. 4–19. DOI:10.24425 / aep.2019.130237.
  4. Bodzek, M., Konieczny, K. & Rajca, M. (2019). Membranes in water and wastewater disinfection – review, Archives of Environmental Protection, 45, pp. 3–18. DOI:10.24425/aep.2019.126419.
  5. Boyacioglu, H. (2014). Spatial dıfferentiation of water quality between reservoirs under anthropogenic and natural factors based on statistical approach, Archives of Environmental Protection, 40/1, pp. 41–50. DOI:10.2478 / aep-2014-0002.
  6. Chen, Q.-B., Ren, H., Tian, Z., Sun, L. & Wang, J. (2019). Conversion and pre-concentration of SWRO reject brine into high solubility liquid salts (HSLS) by using electrodialysis metathesis, Separation and Purification Technology, 213, pp. 587-598. DOI:10.1016/j.seppur.2018.12.018.
  7. Dharminder, Ram Kumar Singh, Vishal Kumar, Anoop Kumar Devedee, Mruthyunjaya, M. & Reshu Bhardwaj (2019). The clean water: The basic need of human and agriculture, International Journal of Chemical Studies, 7, 2, pp. 1994-1998.
  8. Hilary A. Dugan, H.A., Bartlett, S.L., Burke, S.M., Doubek, J.P. & Krivak, F.E. (2017). Salting our freshwater lakes, Proc. Natl Acad. Sci. USA, 114, 17, pp. 4453-4458. DOI:10.1073/pnas.1620211114.
  9. Gomelya, M.D., Trus, I.M. & Shabliy, T.O. (2014). Application of aluminium coagulants for the removal of sulphate from mine water, Chemistry & Chemical Technology, 8, 2, pp. 197-203. http://science2016.lp.edu.ua/chcht/application-auminium-coagulants-removal-sulphate-mine-water.
  10. Griffith, M.B. (2017). Toxicological perspective on the osmoregulation and ionoregulation physiology of major ions by freshwater animals: teleost fish, crustacea, aquatic insects, and Mollusca, Environ. Toxicol. Chem., 36, pp. 576-600. DOI:10.1002/etc.3676.
  11. Grodzka-Łukaszewska, M., Pawlak, Z. & Sinicyn, G. (2021). Spatial distribution of the water exchange through river cross-section – measurements and the numerical model, Archives of Environmental Protection, 47, 1, pp. 69–79. DOI:10.24425/aep.2021.136450.
  12. Halysh, V., Trus, I., Nikolaichuk, A., Skiba, M., Radovenchyk, I., Deykun, I., Vorobyova, V., Vasylenko, I. & Sirenko, L. (2020). Spent Biosorbents as Additives in Cement Production, Journal of Ecological Engineering, 21, 2, pp. 131–138. DOI:10.12911/22998993/116328.
  13. Hardikar, M., Marquez, I. & Achilli, A. (2020). Emerging investigator series: membrane distillation and high salinity: analysis and implications, Environmental Science: Water Research & Technology, 6, 6, pp. 1538-1552. DOI:10.1039/C9EW01055F.
  14. Kaushal, S.S. (2016). Increased salinization decreases safe drinking water, Environ. Sci. Technol., 50, pp. 2765-2766. DOI:10.1021/acs.est.6b00679.
  15. Lu, H., Wang, L., Wycisk, R., Pintauro, P.N. & Lin, S. (2020). Quantifying the kinetics-energetics performance tradeoff in bipolar membrane electrodialysis, Journal of Membrane Science, 612, 118279. DOI:10.1016/j.memsci.2020.118279.
  16. Luo, T., Abdu, S. & Wessling, M. (2018). Selectivity of ion exchange membranes: A review, Journal of Membrane Science, 555, pp. 429-454. DOI:10.1016/j.memsci.2018.03.051.
  17. Mester, T., Szabó, G., Bessenyei, É., Karancsi, G., Barkóczi, N. & Balla, D. (2017). The effects of uninsulated sewage tanks on groundwater. A case study in an eastern Hungarian settlement, J. Water Land Dev., 33, pp.123-129. DOI:10.1515/jwld-2017-0027.
  18. Mirzavand, M., Ghasemieh, H., Sadatinejad, S.J. & Bagheri, R. (2020). An overview on source, mechanism and investigation approaches in groundwater salinization studies, Int. J. Environ. Sci. Technol., 17, pp. 2463–2476. DOI:10.1007/s13762-020-02647-7.
  19. Mubita, T., Porada, S., Aerts, P. & van der Wal, A. (2020). Heterogeneous anion exchange membranes with nitrate selectivity and low electrical resistance, Journal of Membrane Science, 607, 118000.
  20. Panagopoulos, A. (2020). A comparative study on minimum and actual energy consumption for the treatment of desalination brine, Energy, 212, 118733. DOI:10.1016/j.energy.2020.118733.
  21. Radovenchyk, I., Trus, I., Halysh, V., Krysenko, T.,Chuprinov, E. & Ivanchenko, A. (2021). Evaluation of Optimal Conditions for the Application of Capillary Materials for the Purpose of Water Deironing, Ecol. Eng. Environ. Technol., 2, pp. 1–7. DOI:10.12912/27197050/133256.
  22. Rajca, M. (2012). The impact of selected factors on the removal of anionic water pollutants in ion-exchange process of MIEX®DOC, Archives of Environmental Protection, 38, pp. 115–121. DOI:10.2478/v10265-012-0010-z.
  23. Schuler, M.S., Cañedo-Argüelles, M., Hintz, W.D., Dyack, B., Birk, S. & Relyea, R.A. (2018). Regulations are needed to protect freshwater ecosystems from salinization, Philos Trans R Soc Lond B Biol Sci, 374, 1764, 20180019. DOI:10.1098/rstb.2018.0019.
  24. Trokhymenko, G., Magas, N., Gomelya, N., Trus, I. & Koliehova, A. (2020). Study of the Process of Electro Evolution of Copper Ions from Waste Regeneration Solutions, Journal of Ecological Engineering, 21, 2, pp. 29–38. DOI:10.12911/22998993/116351
  25. Trus, I. & Gomelya, M. (2021). Effectiveness nanofiltration during water purification from heavy metal ions, Journal of Chemical Technology and Metallurgy, 56, 3, pp. 615–620, https://dl.uctm.edu/journal/node/j2021-3/21_20-03p615-620.pdf.
  26. Trus, I., Radovenchyk, I., Halysh, V., Skiba, M., Vasylenko, I., Vorobyova, V., Hlushko, O. & Sirenko, L. (2019). Innovative Approach in Creation of Integrated Technology of Desalination of Mineralized Water, Journal of Ecological Engineering, 20, 8, pp. 107–113. DOI:10.12911/22998993/110767.
  27. Trus, I.M., Gomelya, M.D., Makarenko, I.M., Khomenlo, A.S. & Trokhymenko, G.G. (2020). The Study of the particular aspects of water purification from heavy metal ions using the method of nanofiltration, Naukovyi Visnyk Natsionalnogo Hirnychogo Universytety, 4, pp.117–123. DOI:10.33271/nvngu/2020-4/117
  28. Vörösmarty, C.J., McIntyre, P.B., Gessner, M.O., Dudgeon, D., Prusevich, A., Green, P., Glidden, S., Bunn, Sullivan, C.A.,LiermannC.R. & Davies, P.M.. (2010). Global threats to human water security and river biodiversity, Nature, 467, pp. 555-561. DOI:10.1038/nature09440.
  29. Wiśniowska, E. & Włodarczyk-Makuła, M. (2020). Removal of nitrates and organic compounds from aqueous solutions by zero valent (ZVI) iron reduction coupled with coagulation/precipitation process, Archives of Environmental Protection, 46, 3, pp. 22–29. DOI:10.24425 / aep.2020.134532.
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Authors and Affiliations

Inna Trus
1
ORCID: ORCID
Mukola Gomelya
1
ORCID: ORCID
Viktoria Vorobyova
1
ORCID: ORCID
Margarita Skіba
2
ORCID: ORCID

  1. National Technical University of Ukraine «Igor Sikorsky Kyiv Polytechnic Institute», Kyiv, Ukraine
  2. Ukrainian State Chemical-Engineering University, Dnipro, Ukraine
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Abstract

In the present study, a novel PVA–g–PMA hybrid membrane was developed for application in direct methanol fuel cell (DMFC). Maleic anhydride (MA) was grafted on polyvinyl alcohol (PVA) both ionically and chemically using potassium persulfate (KPS), for the first time. ThePVA–g–PMA thus synthesized was then blended with 3–Amino–4–[3–(triethylammonium sulfonato)phenyl amino]phenylene hydrochloride. The prepared membranes were characterized by FT–IR, TGA. 0.0104 S/cm of proton conductivity was found for the membrane. The ion exchange capacity was found to be 2.175 meq/g and the water uptake capacity as 14.9%. The single-chamber fuel cell power density was higher (34.72 mW/cm2) and current density (62.11 mA/cm2) when compared to Nafion 117 membrane.
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Authors and Affiliations

Pratima Gajbhiye
1
A.K. Tiwari
2
Karan Mann
1
J.S. Kahlon
1
H. Upadhyay
3

  1. School of Chemical Engineering and Physical Sciences, Lovely Professional University, Phagwara, Punjab-144 411, India
  2. Department of Chemical Engineering, NIT Jalandhar, Punjab-144011, India
  3. School of Agriculture, Lovely Professional University, Phagwara, Punjab-144 411, India

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