The mathematical model and numerical simulations of the solidification of a cylindrical shaped casting, which take into account the process of filling the mould cavity by liquid metal and feeding the casting through the riser during its solidification, are presented in the paper. Mutual dependence of thermal and flow phenomena were taken into account because have an essential influence on solidification process. The effect of the riser shape on the effectiveness of feeding of the solidifying casting was determined. In order to obtain the casting without shrinkage defects, an appropriate selection of riser shape was made, which is important for foundry practice. Numerical calculations of the solidification process of system consisting of the casting and the conical or cylindrical riser were carried out. The velocity fields have been obtained from the solution of momentum equations and continuity equation, while temperature fields from solving the equation of heat conductivity containing the convection term. Changes in thermo-physical parameters as a function of temperature were considered. The finite element method (FEM) was used to solve the problem.
Liquid metal extraction (LME) process results in 100% neodymium (Nd) extraction but the highest extraction efficiency reported for Dysprosium (Dy) so far is 74%. Oxidation of Dy is the major limiting factor for incomplete Dy extraction. In order to enhance the extraction efficiency and to further investigate the limiting factors for incomplete extraction, experiments were carried out on six different particle sizes of under 200 µm, 200-300 µm, 300-700 µm, 700-1000 µm, 1000-2000 µm and over 2000 µm at 900℃ with magnesium-to-magnet scrap ratio of 15:1 for 6, 24 and 48 hours, respectively. This research identified Dy2Fe17 in addition to Dy2O3 phase to be responsible for incomplete extraction. The relationship between Dy2Fe17 and Dy2O3 phase was investigated, and the overall extraction efficiency of Dy was enhanced to 97%.
The combined effect of conjugation, external magnetic field and oscillation on the enhancement of heat transfer in the laminar flow of liquid metals between parallel plate channels is analyzed. In order to make our results useful to the design engineers, we have considered here only the wall materials that are widely employed in liquid metal heat exchangers. Indeed, all the results obtained through this mathematical investigation are in excellent agreement with the available experimental results. The effective thermal diffusivity κ_e is increased by 3×10^6 times due to oscillation and that the heat flux as high as 1.5×10^10 (W/m^2) can be achieved. Based on our investigation, we have recommended the best choice of liquid metal heat carrier, wall material and its optimum thickness along with the optimum value of the frequency to maximize the heat transfer rate. At the optimum frequency, by choosing a wall of high thermal conductivity and optimum thickness, an increase of 19.98% in κ_e can be achieved. Our results are directly relevant to the design of a heat transfer device known as electromagnetic dream pipe which is a very recent development.
Recently, since the demand of rare earth permanent magnet for high temperature applications such as an electric motor has increased, dysprosium (Dy), a heavy rare earth element, is becoming important due to severe bias in its production. To fulfill the increasing need of Dy, recycling offers as a promising alternative. In recycling of rare earths, Hydro-metallurgical extraction method is mainly used however it has adverse environmental effects. Liquid metal extraction on the other hand, is an eco-friendly and simple method as far as the reduction of rare earth metal oxide is concerned. Therefore, liquid metal extraction was studied in this research as an alternative to the hydro-metallurgical recycling method. Magnesium (Mg) is selected as solvent metal because it doesn’t form intermetallic compounds with Fe, B and has a low melting and low boiling point. Extraction behavior of Dy in (Nd,Dy)-Fe-B magnet is observed and effect of Mg ratio on extraction of Dy is confirmed.