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Abstract

The research on the coupling electromagnetic effect was studied in this paper, in consideration of the wreaking damage of the powerful electromagnetic pulse to the electronic products. The characteristic of the metallic via and stub interconnect with the coupling voltage was calculated by the model, which was the transfer function F( f ) of the protection circuit parameters of DC power source. The research showed that: the smaller radius of Metallic via, the lower amplitude of F( f ), the less energy of a power electro- magnetic pulse (PEP); the higher increase of the width of the stub interconnect, the bigger reduction of the characteristic impedance of plane wave coupling, the depth of the notch band significantly narrowed. The simulations and experiments were done to compare the protection effects of protection circuits with different parameters at last. The results showed that the protection circuit designed could be highly advantageous in protecting the DC power source in this article.

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Authors and Affiliations

Xiaofei Xu
Denghua Li
Shuhui Yang
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Abstract

Among the elements that compose steel slags and blast furnace slags, metallic precipitates occur alongside the dominant glass and crystalline phases. Their main component is metallic iron, the content of which varies from about 90% to 99% in steel slags, while in blast furnace slags the presence of precipitates was identified with the proportion of metallic iron amounting to 100%. During observations using scanning electron microscopy and X-ray spectral microanalysis it has been found that the form of occurrence of metallic precipitates is varied. There were fine drops of metal among them, surrounded by glass, larger, single precipitates in a regular, spherical shape, and metallic aggregates filling the open spaces between the crystalline phases. Tests carried out for: slags resulting from the open-hearth process, slags that are a by-product of smelting in electric arc furnaces, blast furnace slags and waste resulting from the production of ductile cast iron showed that depending on the type of slag, the proportion and form of metallic precipitates is variable and the amount of Fe in the precipitates is also varied. Research shows that in terms of quality, steel and blast furnace slag can be a potential source of iron recovery. However, further quantitative analyses are required regarding the percentage of precipitates in the composition of slags in order to determine the viability of iron recovery. This paper is the first part of a series of publications aimed at understanding the functional properties of steel and blast furnace slags in the aspect of their destructive impact on the components of devices involved in the process of their processing, which is a significant operational problem.

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Authors and Affiliations

Andrzej Norbert Wieczorek
Iwona Jonczy
ORCID: ORCID
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Abstract

Elevated content or heavy metals in soils is characteristic of the Dąbrowa Górnicza region. The highest concentrations of lead. cadmium and zinc exceed herc 650, 15, and 1000 mg/kg of soil, respectively. Samples of soi I from selected sites underwent the speciation analysis with the use of the Tessier method. modified according to Kersten and Forstner. Results of the investigations proved the highest concentrations or these metals in the area of Trzebiesławice. They occur here in the strongly bound forms and, mainly, their occurrence is related to presence of limestone rocks. The greatest amounts of these metals in easily assimilable to plant forms occur within the area of the town of Dąbrowa Górnicza. The most probable source ot· most of these heavy metals in soils are here contaminants emitted by the industry, mainly by the metallurgy. In the vicinity of the town of Błędów, mainly sandy soils occur, characteristic or which is low content of considered metals. Weak sorption capacities of these soils account for relatively good cxtractability of the three metals. In soils from the Lęka area, strong binding of these metals was confirmed. Occurrence or cadmium should be of special attention because this metal occurs as built in the crystal lattice of minerals.
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Authors and Affiliations

Bronisław Wyżgolik
Stanislaw Karweta
Ewa Surowiec
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Abstract

Metals are useful raw materials used in various industries. But one of the side-effects of their production is pollution of the marine environment.
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Authors and Affiliations

Jacek Bełdowski
1
Magdalena Bełdowska
2

  1. PAS Institute of Oceanology in Sopot
  2. Faculty of Oceanography and Geography,University of Gdańsk
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Abstract

Concentration of Zn, Cu, Cd, Pb and Co have been determined in Antarctic water (South Shetland Islands) and in krill exoskeletons with the help of atomic absorption spectrophotometry. Concentrations of these metals both in sea-water and in krill exoskeleton are in order Zn > Cu > Cd > Ni > Pb > Co. Comparing concentrations of these metals in sea-water to their concentrations in krill exoskeleton, the factors have been calculated giving a list of metals in the order of krill chitin ability, which is Ni > Cu > Zn > Cd > Pb > Co accumulation. The highest accumulation factors for Ni and Cu point out to the special role played by these metals in krill life.

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Authors and Affiliations

Witold Neugebauer
Piotr Bykowski
Ewa Neugebauer
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Abstract

The article describes the design of a proven technology for the production of metal foam and porous metal by the foundry. Porous metal formed by infiltrating liquid metal into a mould cavity appears to be the fastest and most economical method. However, even here we cannot do without the right production parameters. Based on the research, the production process was optimised and subsequently a functional sample of metal foam with an irregular internal structure - a filter - was produced. The copper alloy filter was cast into a gypsum mould using an evaporable model.
Furthermore, a functional sample of porous metal with a regular internal structure was produced - a heat exchanger. The aluminium alloy heat exchanger was cast into a green sand mould using preforms. Also, a porous metal casting with a regular internal structure was formed for use as an element in deformation zones. This aluminium alloy casting was made by the Lost Foam method. The aim is therefore to ensure the production of healthy castings, which would find use in the field of filtration of liquid metal or flue gases, in vehicles in the field of shock energy absorption and also in energy as a heat exchanger.
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Bibliography

[1] Lefebvre, L.P., Banhart, J. & Dunand, D. (2008). Porous metals and metallic foams: current status and recent developments. Advanced Engineering Materials. 10(9), 775-787.
[2] Banhart, J. (2001). Manufacture, characterisation and application of cellular metals and metal foams. Progress in Materials Science. 46(6), 559-632.
[3] Banhart, J. (2007). Metal Foams - from Fundamental Research to Applications [online], URL: < https://www.helmholtz-berlin.de/media/media/spezial/people/banhart/html/B-Conferences/b097_banhart2007.pdf>.
[4] Gaillard, Y., Dairon, J., & Fleuriot, M. (2011). Porous materials: innovations with many uses. Slévárenství. 11-12, roč. LIX, 374-378. (in Czech).
[5] Banhart, J. (2005). Aluminium foams for lighter vehicles. International Journal of Vehicle Design. 37, Nos. 2/3, 114-125. [online]. URL: < http://www.helmholtz-berlin.de/media/media/spezial/people/banhart/html/A-Journals/open/article/a082_banhart2005.pdf>.
[6] García-Moreno, F. Commercial Applications of Metal Foams: Their Properties and Production. [online]. URL: < http://www.mdpi.com/1996-1944/9/2/85/html>.
[7] Banhart, J. Metallic Foams II: properties and application [online]. URL: < http://materialsknowledge.org/docs/ Banhart-talk2.pdf>.
[8] Landolsi, M.W. (2016). Metal foam - an innovative material. [online]. URL: < https://conceptec.net/actualites/innovations/ 111-mousse-metallique-un-materiau-innovant>. (in Czech).
[9] Lulusoso. Composite cladding panel manufacturers [online]. URL: < http://www.lulusoso.com/products/ Composite-Cladding-Panel-Manufacturers.html>.
[10] Erg Materials and Aerospace; Duocel® Foam Cells. [online]. URL: < http://www.ergaerospace.com/products/ fuel-cells.html>.
[11] Kroupová, I., Lichý, P., Ličev, L., Hendrych, J. & Souček, K. (2018). Evaluation of properties of cast metal foams with irregular inner structure. Archives of Metallurgy and Materials. 63(4), 1845-1849. ISSN 1733-3490.
[12] Kroupova, I., Bednarova, V., Elbel, T. & Radkovsky, F. (2014). Proposal of method of removal of mould material from the fine structure of metallic foams used as filters. Archives of Metallurgy and Materials. 59(2), 727-730. ISSN 1733-3490.
[13] Yamada. Y., Shimojima, K., Sakaguchi, Y., Mabuchi, M., Nakamura, M., Asahina, T., Mukai, T., Kanahashi, H. & Higashi, K. (2000). Effects of heat treatment on compressive properties of AZ91 Mg and SG91A Al foams with open-cell structure. Materials Science and Engineering: A. 280(1), 225-228. DOI: https://doi.org/ 10.1016/S0921-5093(99)00671-1.
[14] Gawdzinska, K., Chybowski, L. & Przetakiewicz, W. (2017). Study of thermal properties of cast metal-ceramic composite foams. Archives of Metallurgy and Materials. 17(4), 47-50. ISSN 1897-3310.
[15] Haack, P.D., Butcher, R.P., Kim, T. & Lu, J.T. (2001). Novel lightweight metal foam heat exchangers. porvair fuel cell technology, Inc., Department of Engineering, University of Cambridge. January, [online]. URL: < https://www.researchgate.net/publication/267721239_Novel_Lightweight_Metal_Foam_Heat_Exchangers>.
[16] Radkovský, F., Merta, V. (2020). Use of numerical simulation in production of porous metal casting. Archives of Metallurgy and Materials. 54(2), 259-261. ISSN 1580-2949. DOI: 10.17222/mit.2019.145.
[17] Radkovský, F., Gebauer, M., Kroupová, I., Lichý, P. (2017). Metal foam as a heat exchanger. In METAL 2017, Conference proceedings, 26th Anniversary International Conference on Metallurgy and Materials, Tanger Ltd., Ostrava, 24. - 26. 5. 2017, Hotel Voroněž I, Brno.
[18] Lu, T.J., Stone, H.A. & Ashby, M.F. (1998). Heat transfer in open-cell metal foams. Acta Materialia. 46(10, 12) June, 3619-3635. DOI: https://doi.org/10.1016/S1359-6454(98) 00031-7
[19] Boomsma, K., Poulikakos, D. & Zwick, F. (2003). Metal foams as compact high performance heat exchangers. Mechanics of Materials, 35(12), 1161-1176. DOI: https://doi.org/10.1016/j.mechmat.2003.02.001.
[20] Hutter, C., Büchi, D., Zuber, V. & Rohr, R. (2011). Heat transfer in metal foams and designed porous media. Chemical Engineering Science. 66(17), 1 September 2011, 3806-3814. DOI: https://doi.org/10.1016/j.ces.2011.05.005
[21] Lichý, P., Elbel, T., Kroupová, I. & Radkovský, F. (2017). Preparation and evaluation of properties of cast metallic foams with regular inner structure. Archives of Metallurgy and Materials. 62(3), 1643-1646. ISSN 1733-3490. DOI: 10.1515/amm-2017-0251.
[22] Romanek, T. (2017). Manufacturing and Properties of Cast Metallic Foams with Regular Structure, Ostrava, Diploma thesis, VSB - Technical University of Ostrava, [online]. URL: http://www.ergaerospace.com/products/fuel-cells.htm>.
[23] Radkovský, F., Gebauer, M. & Merta, V. (2018). Optimizing of metal foam design for the use as a heat exchanger. Archives of Metallurgy and Materials. 63(4), 1875-1881. ISSN 1733-3490.

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Authors and Affiliations

F. Radkovský
1
ORCID: ORCID
V. Merta
1
ORCID: ORCID
T. Obzina
1

  1. VSB - Technical University of Ostrava, Czech Republic
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Abstract

Research of metallurgical slags chemical composition, originating both from current production as well as gathered in dumping grounds formany years, show that they are very diversified. Slags contain substantial amounts of metals, including heavy metals, apart from elements from groups of non-metals and lanthanoids. In the article occurrence forms and relations with phase components of selected metals (iron, manganese, zinc, lead and others) on the basis of mineralogical and chemical research on slags after steel and ore Zn-Pb production were characterized. It was stated that metals may occur in metallurgical slags as fine drops not separated from slag during a metallurgical process, may form polymetallic aggregates, their own phases (especially oxide ones) and hide in structures of silicate phases. A considerable amount of metals is dissipated in glaze and amorphous substance. The conducted research delivers information on the occurrence of metals in metallurgical slags, which is extremely important during work connected with economic exploitation of slags. It especially refers to increasing attempts of acquiring elements from metallurgical slags. These activities determine the necessity of analyzing chemical and phase composition of slags because they may be an important indication, for instance while working on a proper technology of elements recovery.

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Authors and Affiliations

Iwona Jonczy
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Abstract

The aim of this paper was to investigate the relationship between magnetic susceptibility of topsoil and content of heavy metal being the result of urban and industrial dust-fall. Tools for this study were some complementary statistic methods such as: correlation analysis using Pearson correlation coefficient, Spearman rank correlation coefficient, stepwise regression and .chi-kwadrat" test. The base for statistic analysis was dataset of ca. 600 topsoil samples (20 cm) form Upper Silesian Industrial Region, including content ofAs, Cd, Co, Cr, Cu, Fe, Mn, Ni and Pb as well as values of low-field specific magnetic susceptibility (x) measured for the same samples. The study clearly confirms a significant correlation between the level of inorganic contamination and the measured susceptibility value, although the correlations in soil are usually more sophisticated. The most often observed correlation coefficients between magnetic susceptibility and heavy metals content were on medium (r = 0.5--0.7) and high (r = 0.7--0.9) level. The statistic analysis of the studied parameters can not be based only on Pearson correlation coefficient. The use of some complementary statistic methods allows for more correct interpretation of existing relationships. The comparable values of Pearson linear correlation coefficient and Spearman rank the correlation coefficient, observed in studied dataset within the range of accuracy used, shows the existence of linear correlation. The similar conclusions have been drawn from the analysis of reverse stepwise regression. The observed model of linear multiple regression explains almost 80% of variability of the X value. Foregoing statistical analysis confirms some earlier observations that magnetometry based on topsoil magnetic susceptibility measurement could be a very interesting and alternative or complementary method for monitoring anthropogenic soil pollution and especially heavy metal contamination level.
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Authors and Affiliations

Jarosław Zawadzki
Tadeusz Magiera
Zygmunt Strzyszcz
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Abstract

The research system of soils for evaluation of the ecological state of farm-land soils in Poland is presented in this paper. Granulometrie composition, pH, organic matter content and the content of heavy metals (Cd, Cu, Ni, Pb, Zn) in soils were determined. On the basis of existing criteria (tab. 1) the state of soil pollution with heavy metals for separate provinces and whole country was estimated. The average heavy metal contents (mg/kg) in surface layer of soils in Poland are as follows: Cd-0.21, Cu-6.5, Ni-6.2, Pb-13.6, and Zn-32.4. The farm-land soils of Poland generally contain natural and slightly elevated level of the investigated heavy metals. This allows to produce high quality of agricultural materials appropriate for consumption and feeding of animals.
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Authors and Affiliations

Henryk Terelak
Arkadiusz Tujaka
Teresa Motowicka-Terelak
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Abstract

The research of the soil quality was made in Markowice, the district of Racibórz, the town situated in the South of Poland. The soils of Racibórz were expected to be contaminated with heavy metals after the heavy flood in 1997, which devastated great part of Poland, especially the town. The assays covered macroand microcomponents, contents of total calcium, iron, manganese, sulphur, bioavailable magnesium, potassium and phosphorus, contents of heavy metals (lead, cadmium, zinc, chromium, nickel and copper), electrolytic conductivity, pH of soil, and finally organic matter content in soil. The research showed that soils of the district of Racibórz have a natural content of heavy metals, but the soils have the deficiency of macrocornponcnts, such as phosphorus, magnesium and calcium.
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Authors and Affiliations

Ewa Cebula
Jan Cebula
Jerzy Ciba
Bronisław Wyżgolik
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Abstract

The contents or Cd, Pb. Cu, Mn, Zn, Ni and Fe in different organs or Typha latifolia L., coming from six sites selected within Jezioro Wielkie (Leszczyńskie Lakeland in western Poland), were determined. Three groups or metals, cach with a different accumulation pattern within the plant were distinguished in this study. Pb, Zn and Cu were found to be the least mobile and shown the following accumulation scheme: roots> rhizomes> lower leave part> top leave part. 13y contrast, Mn, a metal which is both easily transported in plants and accumulated in green plant organs, exhibited the following accumulation scheme: roots> top leave part> lower leave part> rhizomes. Ni, Cd and re were accumulated by the cattail as follows: roots> rhizomes> top leaf part> lower leaf part. The fact that Tvpha tatifol io L. had the highest proportion 01· all the metals studied in its roots can suggest that some kind of protection barrier exists which prevents toxic compounds permeating from that part or this plant to its rhizomes and its aerial parts. The confirmation or this thesis requires some further research.
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Authors and Affiliations

Agnieszka Klink
Józef Krawczyk
Barbara Letachowicz
Magdalena Wisłocka
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Abstract

Joint action by the countries surrounding the Baltic is crucial for the conservation of the sea’s unique ecosystem.
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Authors and Affiliations

Blanka Pajda
1
Agata Zaborska
1

  1. PAS Institute of Oceanology in Sopot
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Abstract

Metal contents in the tundra soils (Gelic Regosols, Gelic Gleysols, Gelic Cambisols) of the maritime lowland of Kaffiöyra, in the western Spitsbergen seashore are presented in this publication. The average heave metal contents in samples collected from the depth layer 0—130 cm are follows: Fe 2.9%, Mn 392 ppm, Zn 75 ppm, Cu 23.4 ppm, Ni 24.1 ppm, Co 7.4 ppm, Pb 12.5 ppm, Cd 0.24 ppm. The surface soil layer 0 to 25 cm is poorer in Ca and Mg than the underlying layer 25 to 130 cm. The heave metal contents like Fe, Mn, Ni and Co, are also somewhat lower in the upper layer. The enrichment indices of Pb and Cd are equal in the surface soil layer 1.16 and 1.23 respectively. Correlation coefficients between each studied element and organic carbon, and, on the other hand, soil separates < 20 μm and < 2 μm are very low.

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Authors and Affiliations

Witold Plichta
Irena Kuczyńska
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Abstract

In the years 1987-1995 studies were carried out on the content of Cu, Mn, Zn, Pb and Cd in plants and soil in the Bellsund area, Western Spitsbergen. For the studies the author used predominating species of vascular plants, bryophytes and lichens collected from beaches littoral planes, valleys, slopes and mountain peaks. Some plant species, largely bryophytes and lichens, were shown to contain increased amounts of Zn, Pb and Cd, whilst in others Cu deficiency was found. This paper is summing up studies concerning the content of Cu, Mn, Zn, Pb and Cd in plants of Western Spitsbergen, which were conducted over many years.

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Authors and Affiliations

Zbigniew Jóźwik
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Abstract

The contents of copper, manganese, zinc, lead and cadmium have been determined in plants of the Spitsbergen tundra, collected at Calypsostranda, Lyellstranda and Chamberlindalen in 1987. Five species of vascular plants, four species of mosses and fourteen species of lichens have been investigated. Manganese content in all the studied plants falls in the physiological limits of this element. Appreciable concentrations of copper, and zinc exceeding the physiological concentrations of these elements and presence of lead and cadmium have been shown for many plants.

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Authors and Affiliations

Zbigniew Jóźwik
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Abstract

The results of studies on the air pollution and on the natural sedimentation from the atmosphere in the South Shetlands are (Admiralty Bay) are presented. The amount of dust in the air varied from 0.11 to 10.90 μg x m-3 (the mean being 3.70 μg x m-3). The total amount of substances transported from the atmosphere in the Admiralty Bay region was estimated at 12.7t x km-2 per year, whereas the precipitation transports some 2.5 t x km-2 per year in this region. Preliminary data on the contents of Cu. Cd. Co. Ni. Pb and Zn in the samples of surface waters, snow and rain in the region of the Admiralty Bay are presented and compared with the results of the authors.

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Authors and Affiliations

Kazimierz Pęcherzewski
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Abstract

The aim of this study was to evaluate foundry waste used for various applications in terms of heavy metals quantity of fractions of their binding. The novelty of these studies is the use of speciation procedures to assess the fraction of heavy metals in foundry waste. The two most popular speciation procedures, the Tessier method and the SM&T, and also the TCLP single extraction procedure were used to evaluate the use of foundry waste in agritechnique, road engineering and construction in this research. Additionally, local soils were analyzed and compared to landfill foundry waste (LFW). It was found that LFW may have a negative impact on the natural environment when used for agrotechnological applications due to the increased concentration of mobile and bioavailable fractions (mean 9–18%) of metals. Foundry dusts were characterized by a low percentage of mobile and bioavailable (mean 2–6%) forms, although this does not include electric arc fournance dust (EAFD) (mean 17%). The metal content in TCLP extracts was low in all foundry waste samples and allowed the use of the analyzed wastes in construction and road construction. The usefulness of both speciation procedures for the assessment of the leaching of heavy metal forms from foundry waste was confirmed. However, the SM&T procedure was more effective in leaching mobile and bioavailable forms of heavy metals in foundry waste and soil samples.
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Authors and Affiliations

Marta Bożym
1
ORCID: ORCID

  1. Opole University of Technology, Opole, Poland
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Abstract

The leachability of pollutants from asbestos-containing waste, previously used for roofing was investigated. Laboratory tests were performed under static conditions (tests 1–20) in accordance with the TCLP methodology (with the use of acetic acid as the leaching medium, initial pH = 3.15). The maintaining of constant leaching conditions proved to be impossible at the experimental stage. Following the stabilization of conditions, the pH range for the obtained solutions increased to an average value of 8.3. Aluminum, boron, barium, cadmium, chromium, copper, iron, nickel, lead, strontium, zinc, and mercury were identified in the eluate. The low leachability of individual metals under the planned conditions was observed. In general, no leaching of such metals as cadmium, nickel, and lead was observed. The mercury content in the eluates is below the quantification limit, but the obtained values fall to around the limit of detection for the element. As compared with leaching with the use of distilled water (Klojzy-Karczmarczyk et al. 2021), zinc and boron additionally appear in eluates. The determined value of leachability for the individual analyzed elements increases from double to a few times with the use of the TCLP method. The value of leaching for barium is on average 5.56 mg/kg, for chromium it is 1.10 mg/kg, for copper 0.26 mg/kg, and for iron 0.80 mg/kg. In addition, the leaching of boron of around 3.00 mg/kg and of zinc 1.84 mg/kg was found. Higher leachability values were found only for strontium and aluminum. The leaching of strontium is on average around 62 mg/kg. While the leaching of aluminum is lower than values identified in the previous tests with the use of distilled water and is around 2.76 mg/kg. Products of leaching contain mainly pollutants characteristic of cement (aluminum, strontium, and iron).
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Authors and Affiliations

Beata Klojzy-Karczmarczyk
1
ORCID: ORCID
Janusz Mazurek
1
ORCID: ORCID

  1. Mineral and Energy Economy Research Institute, Polish Academy of Sciences, Kraków, Poland
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Abstract

The paper presents an assessment of flotation efficiency in the separation of plastics from metals derived from printed circuit boards (PCBs). The PCBs were ground in a knife mill prior to flotation. The contact angles of various materials corresponding to the grains from ground PCBs were measured, and a series of flotation tests was carried out to obtain the best product. The impact of the following parameters were investigated: the reagent and its dose, the airflow rate through the flotation tank and the feed concentration. The highest efficiency of metal recovery from PCBs was achieved for Dimethoxy dipropyleneglycol at a concentration of 157 mg/dm3 and with an airflow of 200 dm3/h and a feed concentration of <50 g/dm3. In the hydrophilic product (concentrate), it was mainly Cu (40%) and Sn (7.8%) that were identified by means of XRF, but there were also trace amounts of precious metals such as Au (0.024%), Ag (0.5797%) and Pd (149 ppm). Impurities in the form of Si (5%), Ca (3.2) and Br (2.1) were also identified in this product. Small amounts of metals in their metallic form were identified in the hydrophobic product (waste), mainly Cu (2.3), Al (1.7) and Sn (1.1). As a result of the research, high recovery ratios were obtained for Cu (93%), Sn (84), Ag (83) and Au (69). The purity of obtained metal concentrate with this method was lower in comparison with the other methods of the recovery of metals from ground PCBs for the same feed, i.e. electrostatic or gravity separation. Also considering other factors such as the environmental impact of the flotation process, the number of facilities and their energy consumption, this process should not be used in the developed metal recovery technology. Using electrostatic separation for the same feed obtained much better results.
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Authors and Affiliations

Dawid M. Franke
1
ORCID: ORCID
Umut Kar
2
ORCID: ORCID
Tomasz Suponik
1
ORCID: ORCID
Tomasz Siudyga
3
ORCID: ORCID

  1. Silesian University of Technology, Gliwice, Poland
  2. Eskisehir Osmangazi University, Turkey
  3. University of Silesia, Katowice, Poland
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Abstract

Metallurgical slag is often treated as a material which could be used in the waste management, especially for production different kinds of aggregate. So it is necessary to know that material not only considering technical properties, but also its mineral and chemical composition. Such researches could deliver many valuable information during the waste utilization. Researches were made for samples of the metallurgical slag after steel and Zn-Pb production. Samples were taken from chosen dumps localized in the Upper Silesian District. Beside metallic aggregates, silicate and oxide phases, glaze is one of the main component of the metallurgical slag. The following stages of the glaze devitrification were presented; from not transformed and isotropic glaze pieces to the strong weathered glaze. Transformed glaze is red or brown with the cracks on the surface. Cracks are often filled by the metals oxides, which can be liberated during the glaze devitrification. On the base of researches executed using the electron microprobe the chemical glaze composition was presented. The chemical composition of the glaze is variable what is connected with the kind of the metallurgical slag. The following main elements were distinguished in the metallurgical slag: Si, Al, Fe, Ca and Mg. Slag after steel production contains also Mn, P, S and the slag after Zn-Pb production contains: As, Cd, Cu, Mn, Ni, Pb, Ti, Zn, Na, K, P and S.

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Authors and Affiliations

Iwona Jonczy
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Abstract

This paper discusses the agrotechnical use of foundry waste based on spent foundry sands (SFS). The advantage of foundry waste use is its high concentration of quartz sands and its similar physical properties to soils, including good permeability and filtration rate. An important component of foundry waste containing a mineral binders (green sands) is the presence of a clay fraction. In contrast, organic binders in some foundry wastes increase the percentage of organic matter. However, organic binders may contain toxic substances that are hazardous to the biota. Therefore, it is not recommended to use foundry waste with organic binders in agriculture or horticulture. Moreover, heavy metals may be problematic in the agrotechnical use of foundry waste mainly derived from cast metal. The disadvantage of using foundry waste as soil substrates is the low proportion of fertilizing components. Due to the low content of nutrients in foundry waste, it is recommended that it is used as a structural component mixed with other additives, such as sewage sludge or compost. The paper presents the results of research on the content of pollutants and the assessment of the biotoxicity of foundry waste. Based on the analyzed literature reports and own research, it was found that the use of foundry waste for non-industrial purposes, such as the production of artificial horticultural substrates, soilless substrates and artificial soils (Technosols), should be preceded by numerous studies to confirm the absence of negative impacts on the environment and human health.
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Authors and Affiliations

Marta Bożym
1
ORCID: ORCID

  1. Opole University of Technology, Opole, Poland
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Abstract

The aim of the study was fractionation of Zn, Cu, Ni, Pb in the bottom sediments of two small reservoirs: at Krempna on the Wisłoka River and at Zcslwicc on the Dlubnia River. The partitioning of metals for various fractions was performed with the use of Tessier's sequential chemical extraction method. All together five metal fractions were distinguished: exchangeable metals (fraction I), metals bound to carbonates (fraction II), metals bound to hydrate Fe-Mn oxides (fraction III), metals bound to organic matter (fraction IV), and metals bound to minerals (fraction V). The largest quantities of metals were bound with fraction V, the smallest occurred in the forms most easily available for living organisms, in faction I. Proportions ofZn, Ni and Pb in the exchangeable fraction were about 1%. The amounts of metals bound with fraction II were also relatively low, except lor Zn in bottom sediment at the Zeslawice Reservoir. In this bottom sediment the share of Zn bound to carbonates was 33%. Medium metal quantities were associated with hydrate Fe-Mn oxides (fraction III) and with organic matter (fraction IV). Relatively high proportion ofmetals in fraction V and trace amounts ofmetals in fraction I as well as alkaline and neutral reaction of the sediments may prove a potentially low hazard of the metal release in the case of chemical changes in the reservoirs.
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Authors and Affiliations

Marek Madeyski
Marek Tarnawski
Czesława Jasiewicz
Agnieszka Baran

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