Methane is accompanied by most of the coal deposits. The methane hazard is excessive content of this gas in the mining excavations. This is a source of high risk security and continuity of the mine. The Piast–Ziemowit is the only non-methane mine in the Polish Mining Group. In 2015, 66,4% of the coal mined in Kompania Węglowa S.A. mines comes from methane coal seams. Methane drainage is the most effective but very costly method of combating methane hazard.The costs of prevention and eradication of methane hazard is charged to the costs of coal mining. Therefore, performance of methane drainage in the mines of the Polish Mining Group is adapted to the scale of the methane hazard. The article presents an analysis of the costs of prevention of methane hazard for mines with different absolute methane and its impact on the level of these costs.

Uncontrolled emissions of landfill gas may contribute significantly to climate change, since its composition represents a high fraction of methane, a greenhouse gas with 100- year global warming potential 25 times that of carbon dioxide. Landfill cover could create favourable conditions for methanotrophy (microbial methane oxidation), an activity of using bacteria to oxidize methane to carbon dioxide. This paper presents a brief review of methanotrophic activities in landfill cover. Emphasis is given to the effects of cover materials, environmental conditions and landfill vegetation on the methane oxidation potential, and to their underlying effect mechanisms. Methanotrophs communities and methane oxidation kinetics are also discussed. Results from the overview suggest that well-engineered landfill cover can substantially increase its potential for reducing emissions of methane produced in landfill to the atmosphere.

Methane explosions are among the greatest hazards in the Polish coal mining industry and unfortunately continue to cause many catastrophes. The constant growth of the depth of coal exploitation in the conditions of the high concentration of mining causes the increase of absolute methane content and methane seam pressure from the mined seams. This situation directly affects the increase in the level of methane hazard in the underground work environment. It is therefore obvious to undertake intensive research that will allow for the development of appropriate solutions that help to exclude the risk of mining catastrophes resulting from the ignition and/or methane explosion. In addition to the development of methane hazard prevention methods, an indispensable element of this approach is a very accurate identification of the mechanisms of the combustion and explosion of this gas. The article presents the method of investigation and examples of results of methane explosions carried out in the 400 m experimental gallery of the Experimental Mine “Barbara” of the Central Mining Institute – the only large scale underground experimental facility in Europe. A n analysis has been performed of the influence of the methane release into mining workings on the distribution of the gas concentration and on the course of its explosion or combustion. The data collected characterizes thermodynamic phenomena that form the basis for determining the level of the explosion hazard. Large scale studies have also allowed to assess the risk of conditions that are sufficient for the development of a coal dust explosion initiated by methane explosions. The large scale of the experiments and the system of continuous recording of the course of the experiments allowed the specific characteristics of the methane explosion and burning in underground mining workings to be identified and isolated. For the first time, the course of experiments was recorded via a camera system deployed along the gallery.

The paper presents the investigations aimed at the determination of the effect of time and wavelength of ultrasound field on the value of capillary suction time (CST), sludge thickening and dry matter of the excess sludge subjected to the process of stabilization.

The investigations were carried out on the excess sludge which comes from communal waste treatment plant. The sludge was exposed to ultrasound field, using ultrasound generator with power of 1500 W, frequency of 20 kHz and amplitude 39.42 μm (which corresponded to the amplitude of 100%). Sonication of the sludge was carried out for different amplitudes and sonication times. The non-conditioned sludge and the sludge initially conditioned with ultrasound field were subjected to the process of stabilization in laboratory flasks (V = 0.5 dm3) for the period of 10 days. On each day, sludge thickening and dewatering capacities were determined.

The sludge subjected to the effect of ultrasound field exhibited elevated levels of CST. However, the sonication time had positive effect on the increase in the degree of thickening for each of the amplitudes studied. Also, the process of stabilization positively affected final thickening and dewatering of the sludge.

The essence of the methane fermentation course is the phase nature of changes taking place during the process. The biodegradation degree of sewage sludge is determined by the effectiveness of the hydrolysis phase. Excess sludge, in the form of a flocculent suspension of microorganisms, subjected to the methane fermentation process show limited susceptibility to the biodegradation. Excess sludge is characterized by a significant content of volatile suspended solids equal about 65 ÷ 75%. Promising technological solution in terms of increasing the efficiency of fermentation process is the application of thermal modification of sludge with the use of dry ice. As a result of excess sludge disintegration by dry ice, denaturation of microbial cells with a mechanical support occurs. The crystallization process takes place and microorganisms of excess sludge undergo the so-called “thermal shock”. The aim of the study was to determine the effect of dry ice disintegration on the course of the methane fermentation process of the modified excess sludge. In the case of dry ice modification reagent in a granular form with a grain diameter of 0.6 mm was used. Dry ice was mixed with excess sludge in a volume ratio of 0.15/1, 0.25/1, 0.35/1, 0.45/1, 0.55/1, 0.65/1, 0.75/1, respectively. The methane fermentation process lasting for 8 and 28 days, respectively, was carried out in mesophilic conditions at 37°C. In the first series untreated sludge was used, and for the second and third series the following treatment parameters were applied: the dose of dry ice in a volume ratio to excess sludge equal 0.55/1, pretreatment time 12 hours. The increase of the excess sludge disintegration degree, as well as the increase of the digestion degree and biogas yield, was a confirmation of the supporting operation of the applied modification. The mixture of reactant and excess sludge in a volume ratio of 0.55/1 was considered the most favorable combination. In relation to not prepared sludge for the selected most favorable conditions of excess sludge modification, about 2.7 and 3-fold increase of TOC and SCOD values and a 2.8-fold increase in VFAs concentration were obtained respectively. In relation to the effects of the methane fermentation of non-prepared sludge, for modified sludge, about 33 percentage increase of the sludge digestion degree and about 31 percentage increase of the biogas yield was noticed.

This paper presents mathematical models enabling the calculation of the distribution and patterns of methane inflow to the air stream in a longwall seam being exploited and spoil on a longwall conveyor, taking into account the variability of shearer and conveyor operation and simulation results of the mining team using the Ventgraph-Plus software. In the research, an experiment was employed to observe changes in air parameters, in particular air velocity and methane concentration in the Cw-4 longwall area in seam 364/2 at KWK Budryk, during different phases of shearer operation in the area of the mining wall in methane hazard conditions. Presented is the method of data recording during the experiment which included records from the mine’s system for automatic gasometry, records from a wireless system of eight methane sensors installed in the end part of the longwall and additionally from nine methane anemometers located across the longwall on a grid. Synchronous data records obtained from these three independent sources were compared against the recording the operating condition of the shearer and haulage machines at the longwall in various phases of their operation (cleaning, cutting). The results of the multipoint system measurements made it possible to determine the volume of air and methane flow across the longwall working, and, consequently, to calculate the correction coefficients for determining the volume of air and methane from measurements of local air velocity and methane concentration. An attempt was made to determine the methane inflow from a unit of the longwall body area and the unit of spoil length on conveyors depending on the mining rate. The Cw-4 longwall ventilation was simulated using the data measured and calculated from measurements and the simulation results were discussed.

A mathematical model for the purposes of methane hazard assessment in mines was developed in the Central Mining Institute as part of the statutory activities conducted in 2017 and 2018. The model describes the course of kinetics of methane sorption on coal samples while taking into account the diffusion coefficient. The paper presents the formulas describing the mathematical model of methane emission from coal sidewall to longwall working, taking into account the sorption properties of coal – sorption capacity of coal (related to methane) and the effective diffusion coefficient of methane in coal. In the light of the conducted research, such a methodology for describing this phenomenon enables a more precise determination of the amount of methane released to the longwall from the exploited coal seam, which in turn makes it possible to select appropriate methane prevention measures.

The evaluation of threats connected with the presence of methane in coal seams is based on our

knowledge of the total content of this gas in coal. The most important parameter determining the potential

of coal seams to accumulate methane is the sorption capacity of coal a. It is heavily influenced by the

degree of coalification of the coal substance, determined by the vitrinite reflectance R0 or the content of

volatile matter V daf. The relationship between the degree of coalification and the sorption capacity in the

area of the Upper Silesian Coal Basin (USCB) has not been thoroughly investigated, which is due to the

zonation of methane accumulation in this area and the considerable changeability of methane content in

various localities of the Basin. Understanding this relationship call for in-depth investigation, especially

since it depends on the analyzed reflectance range. The present work attempts to explain the reasons for

which the sorption capacity changes along with the degree of coalification in the area of Jastrzębie (the

Zofiówka Monocline). The relationship between parameters R0 and V daf was investigated. The authors

also analyzed changes of the maceral composition, real density and the micropore volume. Furthermore,

coalification-dependent changes in the sorption capacity of the investigated coal seams were identified.

The conducted analyses have indicated a significant role of petrographic factors in relation to the accumulation

properties of the seams located in the investigated area of USCB.

Anaerobic digestion is an important technology for the bio-based economy. The stability of the process is crucial for its successful implementation and depends on the structure and functional stability of the microbial community. In this study, the total microbial community was analyzed during mesophilic fermentation of sewage sludge in full-scale digesters.

The digesters operated at 34–35°C, and a mixture of primary and excess sludge at a ratio of 2:1 was added to the digesters at 550 m3/d, for a sludge load of 0.054 m3/(m3·d). The amount and composition of biogas were determined. The microbial structure of the biomass from the digesters was investigated with use of next-generation sequencing.

The percentage of methanogens in the biomass reached 21%, resulting in high quality biogas (over 61% methane content). The abundance of syntrophic bacteria was 4.47%, and stable methane production occurred at a Methanomicrobia to Synergistia ratio of 4.6:1.0. The two most numerous genera of methanogens (about 11% total) were Methanosaeta and Methanolinea, indicating that, at the low substrate loading in the digester, the acetoclastic and hydrogenotrophic paths of methane production were equally important. The high abundance of the order Bacteroidetes, including the class Cytophagia (11.6% of all sequences), indicated the high potential of the biomass for efficient degradation of lignocellulitic substances, and for degradation of protein and amino acids to acetate and ammonia.

This study sheds light on the ecology of microbial groups that are involved in mesophilic fermentation in mature, stably-performing microbiota in full-scale reactors fed with sewage sludge under low substrate loading.

The substrates to biogas production in anaerobic digestion, except plant materials, can also be animal feces and manure. It should be highlighted that Poland is one of leaders in the European Union in animal breeding. However, there is no precise data in the literature on the potential of biogas production from animal feces in this country. The aim of the paper was to analyze the biogas production potential from manure in Poland. The aim of work included anaerobic digestion research following materials: cow manure, pig manure, poultry manure and sheep manure. In the next step, based on the obtained results of the biogas yield, energy potential calculations were made. The methane yield for the investigated feedstock materials in the batch culture technology was performed following the internal procedures developed based on the adapted standards, i.e. DIN 38 414-S8 and VDI 4630. Animal wastes were obtained from the Agricultural Experimental Stations of Poznan University of Life Sciences (Poznan, Poland). On a base of achieved results it was concluded that tested substrates have a high energy potential (approx. 28.52 GWh of electricity). The largest potential for electricity production was found in chicken manure (about 13.86 GWh) and cow manure (about 12.35 GWh). It was also shown which regions of Poland have the best chance for development of agriculture biogas plants (Wielkopolskie and Mazowieckie voivodships) and where the potential is the least (Lubuskie and Opolskie voivodeships).

Methane (CH4) sensitivity of zinc oxide (ZnO) thin film has been studied in the present work. The sensor element comprises

of a chemically fabricated ZnO semiconducting layer and a layer of palladium (Pd) as catalyst. The catalyst layer was formed on the surface of semiconducting ZnO following a wet chemical process from palladium chloride (PdCl2) solution. Fundamental features of a sensor element e.g. sensitivity, response time and recovery process has been studied. The effect of operating temperature on performance of the sensor material has been investigated and a choice of optimum temperature was made at around 200oC. The sensor element exhibited reasonable sensitivity of about 86% at this temperature in presence of 1 vol% methane (CH4) in air.

In longwall absolute methane emission rate forecasting, the range of the destressing zone is determined empirically and is not considered to be dependent on the geomechanical parameters of the rock strata. This simplification regarding destressing zone determination may result in significant differences between the forecast and the actual methane emission rates. During the extraction of coal seams using a system involving longwalls with caving under the conditions of low rock mass geomechanical parameters, the absolute methane emission rate forecasts are typically underestimated in comparison to the actual methane emission rates.

In order to examine the influence of the destressing zones on the final forecasting result and to assess the influence of the rock mass geomechanical parameters on the increased accuracy of forecast values, destressing zones were determined for three longwalls with lengths ranging from 186 to 250 m, based on numerical modelling using the finite difference method (FDM). The modelling results confirmed the assumptions concerning the upper destressing zone range adopted for absolute methane emission rate forecasting. As for the remaining parameters, the destressing zones yielded great differences, particularly for floor strata. To inspect the accuracy of the FDM calculation result, an absolute methane emission rate forecasting algorithm was supplemented with the obtained zones. The prepared forecasts, both for longwall methane emission rates as well as the inflow of methane to the longwalls from strata within the destressing zone, were verified via underground methane emission tests. A comparative analysis found that including geomechanical parameters in methane emission rate forecasting can significantly reduce the errors in forecast values.

The methane hazard is one of the most dangerous phenomena in hard coal mining. In a certain range of concentrations, methane is flammable and explosive. Therefore, in order to maintain the continuity of the production process and the safety of work for the crew, various measures are taken to prevent these concentration levels from being exceeded. A significant role in this process is played by the forecasting of methane concentrations in mine headings. This very problem has been the focus of the present article. Based on discrete measurements of methane concentration in mine headings and ventilation parameters, the distribution of methane concentration levels in these headings was forecasted. This process was performed on the basis of model-based tests using the Computational Fluid Dynamics (CFD). The methodology adopted was used to develop a structural model of the region under analysis, for which boundary conditions were adopted on the basis of the measurements results in real-world conditions. The analyses conducted helped to specify the distributions of methane concentrations in the region at hand and determine the anticipated future values of these concentrations. The results obtained from model-based tests were compared with the results of the measurements in realworld conditions. The methodology using the CFD and the results of the tests offer extensive possibilities of their application for effective diagnosis and forecasting of the methane hazard in mine headings.