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Abstract

Currently, a worldwide dynamic rise of interest in using soil as a construction material can be observed. This trend is evident in the rapid rise of the amount of standards that deal with soil techniques. In 2012 the number of standards was larger by one third than five years prior. To create a full standardization of the rammed earth technique it is necessary to take into account the diversity of used soil and stabilizing additives. The proportion of the components, the process of element production and the research methods must also be made uniform. The article describes the results of research on the compressive strength of rammed earth samples that differed from each other with regards to the type of loam used for the mixture and the amount of the stabilizer. The stabilizer used was Portland cement CEM I 42.5R. The research and the analysis of the results were based on foreign publications, the New Zealand standard NZS 4298:1998, the American Standard NMAC14.7.4 and archival Polish Standards from the 1960’s that dealt with earth material.

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Authors and Affiliations

P.L. Narloch
P. Woyciechowski
P. Jęda
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Abstract

This study presents the results of concentrations of rare earth elements and yttrium (REY ), uranium (U), and thorium (Th) in ashes from combustion/co-combustion of biomass (20%, 40%, and 60% share) from the agri-food industry (pomace from apples, walnut shells, and sunflower husks) and hard coal. The study primarily focuses on ashes from the co-combustion of biomass and hard coal, in terms of their potential use for the recovery of rare earth elements (REE ), and the identification of the sources of these elements in the ashes. Research methods such as ICP-MS (inductively coupled plasma mass spectrometry), XRD (X-ray diffraction), and SEM -EDS (scanning electron microscopy with quantitative X-ray microanalysis) were used. The total average content of REY in ash from biomass combustion is 3.55–120.5 mg/kg, and in ash from co-combustion, it is from 187.3 to 73.5 mg/kg. The concentration of critical REE in biomass combustion ash is in the range 1.0–38.7 mg/kg, and in cocombustion ash it is 23.3–60.7 mg/kg. In hard-coal ash, the average concentration of REY and critical REY was determined at the level of 175 and 45.3 mg/kg, respectively. In all samples of the tested ashes, a higher concentration of Th (0.2–14.8 mg/kg) was found in comparison to U (0.1–6 mg/kg). In ashes from biomass and hard-coal combustion/co-combustion, the range of the prospective coefficient (Coutl) is 0.66–0.82 and 0.8–0.85, respectively, which may suggest a potential source for REE recovery. On the basis of SEM -EDS studies, yttrium was found in particles of ashes from biomass combustion, which is mainly bound to carbonates. The carriers of REY , U, and Th in ashes from biomass and hard-coal co-combustion are phosphates (monazite and xenotime), and probably the vitreous aluminosilicate substance.
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Authors and Affiliations

Joanna Adamczyk
1
Danuta Smołka-Danielowska
1
ORCID: ORCID
Arkadiusz Krzątała
1
Tomasz Krzykawski
1

  1. University of Silesia, Katowice, Poland

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