This paper presents the content changes in the Chemical Oxygen Demand (COD) solubilised in hydrolisates obtained from thermally disintegrated municipal waste biofractions. A series of tests related to biowaste undergoing thermal treatment at the following temperatures: 55, 75, 95, 115, 135, 155 and 175°C were conducted for 0.5, 1 and 2 hours. The highest increase in COD solid fraction solubilisation (238%) was observed for the samples disintegrated at 175°C for 2 hours. The values of the reaction rate coefficient k20 = 0.6 d-1 and temperature coefficient θ = 1.023 were determined. Statistical analysis of the multiple regression (correlation coefficient R = 0.89) showed that the temperature has a greater impact on COD solid fraction solubilisation - determined β = 0.66. The multiple correlation coefficient for the treatment time was β = 0.61.
This publication presents an assessment of the economic efficiency of a hypothetical installation for the gasification of the municipal and industrial waste for the production of syngas used subsequently for the production of energy or chemical products. The first part of the work presents an example of a technological system for the energo-chemical processing of coal mud and municipal waste, based on the gasification process using a fluidized bed reactor. A hypothetical installation consists of two main blocks: a fuel preparation unit and a gasification unit. In the fuel preparation installation, reception operations take place, storage, and then grinding, mixing, drying and transporting fuel to the gasification unit. In the gasification installation, fuel gasification, oxygen production, cooling and purification of raw process gas and ash treatment are carried out. The following key assumptions regarding the gasification process, as well as the capital expenditures and operating costs related to the process, were estimated. Consequently, based on the method of discounted cash flows, the unit cost of generating energy contained in the synthesis gas (cost of energy, COE) was determined and the results were interpreted. In order to obtain an acceptable efficiency of the gasification process for waste fuels for the production of alternative fuel (process gas), it is necessary to supplement the mixture of waste coal and coal mud with the RDF. In this case, the unit cost of fuel measured by the PLN/GJ index is lower than in the case of hard coal and comparable with brown coal. The use of coal mud for the production of process gas in an economically efficient way is possible only in the case of changes in the legal system allowing for charging fees for the utilization of industrial waste – coal mud.
Municipal waste management has been an area of special interest of the European Commission (EC) for many years. In 2018, the EC pointed out issues related to municipal waste management as an important element of the monitoring framework for the transition towards a circular economy (CE), which is currently a priority in the economic policy of the European Union (EU). In the presented monitoring framework, 10 CE indicators were identified, among which issues related to municipal waste appear directly in two areas of the CE – in the field of production and in the field of waste management, and indirectly – un two other areas – secondary raw materials, and competitiveness and innovation. The paper presents changes in the management of municipal waste in Poland in the context of the implementation of the CE assumptions, a discussion of the results of CE indicators in two areas of the CE monitoring framework in Poland (production and waste management), and a comparison of the results against other European countries.
In Poland, tasks related to the implementation of municipal waste management from July 1, 2013 are the responsibility of the municipality, which is obliged to ensure the conditions for the system of selective collection and collection of municipal waste from residents, as well as the construction, maintenance and operation of regional municipal waste treatment installations (RIPOK). The municipality is also committed to the proper management of municipal waste, in accordance with the European waste management hierarchy, whose overriding objective is to prevent waste formation and limiting its amount, then recycling and other forms of disposal, incineration and safe storage. The study analyzed changes in the value of two selected CE indicators, i.e. (1) the municipal waste generation indicator, in the area of production and (2) the municipal waste recycling indicator, in the area of waste management. For this purpose, statistical data of the Central Statistical Office (GUS) and Eurostat were used. Data has been presented since 2014, i.e. from the moment of initiating the need to move to the CE in the EU. In recent years, there has been an increase in the amount of municipal waste generated in Poland as well as in the EU. According to Eurostat, the amount of municipal waste generated per one inhabitant of Poland increased from 272 kg in 2014 to 315 kg in 2017. It should be noted that the average amount of municipal waste generated in Poland in 2017 was one of the lowest in EU, with a European average of 486 kg/person. Poland has achieved lower levels of municipal waste recycling (33.9%) than the European average (46%). The reason for Poland’s worse results in the recycling of municipal waste may be, among others, the lack of sufficiently developed waste processing infrastructure, operating in other countries such as Germany and Denmark, and definitely higher public awareness of the issue of municipal waste in developed countries. Municipal waste management in Poland faces a number of challenges in the implementation of GOZ, primarily in terms of achieving the recycling values imposed by the EC, up to a minimum of 55% by 2025.
Based on laboratory tests of selected properties of secondary waste (ashes and dusts) from municipal waste incineration plants, the possibility of recovering some properties of waste in the process of filling the post-mining voids in the salt mine was assessed. The furnace bottom ash and the waste from the flue gas treatment from one of the national incineration plants were examined. The grain curves of dry waste and the density of the prepared mixtures were characterized. Twelve variants of the compositions of ash-based mixtures with varying proportions of the individual components were considered, taking into account both fresh water and brine. For each variant of the composition, the amount of redundant liquid appeared as well as the time of solidifying of the mixture to a certain strength and the compressibility values obtained. Considering the possibility of transporting mixtures in mines by means of pipelines at relatively long distances, and allowing the filling of large salt chambers to be filled and evenly filled, flow parameters were determined. In addition, the permeability of solidified waste samples was investigated, showing the potential for reducing the strength of the waste mass due to the action of water or brine. The technical feasibility of eliminating redundant liquid in the binding process has been confirmed, which is particularly important in salt mines. Preliminary values for the amount of binder (5%÷10%) to be added to the mixtures to obtain the specified strength properties of the artificially formed mass at Rc = 0.5 MPa. Attention was paid to the important practical aspect resulting from the rapid increase of this type of waste in the comming years in Poland and at the same time vast potential for their use in salt mining, where we have a huge capacity of salt chambers available.
The new legislative provisions, regulating the trade in solid fuels in our country, draw attention to the need to develop and improve methods and methods of managing hard coal sludge. The aim of the work was to show whether filtration parameters (mainly the permeability coefficient) of hard coal sludge are sufficient for construction of insulating layers in landfills at the stage of their closing and what is the demand for material in the case of such a procedure. The analysis was carried out for landfills for municipal waste in the Opolskie, Śląskie and Małopolskie provinces. For hard coal sludge, the permeability coefficient values are in the range of 10–8–10–11 m/s, with the average value of 3.16 × 10–9 m/s. It can be concluded that this material generally meets the criteria of tightness for horizontal and often vertical flows. When compaction, increasing load or mixing with fly ash from hard coal combustion and clays, the achieved permeability coefficient often lowers its values. Based on the analysis, it can be assumed that hard coal sludge can be used to build mineral insulating barriers. At the end of 2016, 50 municipal landfills were open in the Opolskie, Śląskie and Małopolskie Provinces. Only 36 of them have obtained the status of a regional installation, close to 1/3 of the municipal landfill are within the Major Groundwater Basin (MGB) range. The remaining storage sites will be designated for closure. Assuming the necessity to close all currently active municipal waste landfills, the demand for hard coal sludge amounts to a total of 1,779,000 m3 which, given the assumptions, gives a mass of 2,704,080 Mg. The total amount of hard coal sludge production is very high in Poland. Only two basic mining groups annually produce a total of about 1,500,000 Mg of coal sludge. The construction of insulating layers in landfills of inert, hazardous and non-hazardous and inert wastes is an interesting solution. Such an application is prospective, but it will not solve the problem related to the production and management of this waste material as a whole. It is important to look for further solutions.
In this study, the environmental impacts of the organic fraction of municipal solid waste (OFMSW) treatment and its conversion in anaerobic digestion to glycerol tertiary butyl ether (GTBE) were assessed. The production process is a part of the innovative project of a municipal waste treatment plant. The BioRen project is funded by the EU’s research and innovation program H2020. A consortium has been set up to implement the project and to undertake specific activities to achieve the expected results. The project develops the production of GTBE which is a promising fuel additive for both diesel and gasoline. It improves engine performance and reduces harmful exhaust emissions. At the same time, the project focuses on using non-recyclable residual organic waste to produce this ether additive.
The aim of this paper is the evaluation through Life Cycle Assessment of the environmental impact GTBE production in comparison with a production of other fuels. To quantify the environmental impacts of GTBE production, the ILCD 2011 Midpoint+ v.1.10 method was considered. The study models the production of GTBE, including the sorting and separation of municipal solid waste (MSW), pre-treatment of organic content, anaerobic fermentation, distillation, catalytic dehydration of isobutanol to isobutene, etherification of GTBE with isobutene and hydrothermal carbonization (HTC).
The results indicate that unit processes: sorting and hydrothermal carbonization mostly affect the environment. Moreover, GTBE production resulted in higher environmental impact than the production of conventional fuels.
Biogas plants processing municipal waste are very important investments from the point of view of waste management and also the sustainable development of urban infrastructures. They may also have a potentially negative impact on the environment in the form of odour emission. Olfactometry is the main method for odour impact assessment. Field olfactometry allows for performing a wide range of tests, the results of which are practically instantaneous. The purpose of this work is to provide a tool for assessing the odour impacts of municipal management facilities, including biogas plants processing municipal waste and evaluating the correctness of processes carried out in these plants, namely the method of field olfactometry. In order to compare obtained olfactometric results with the concentration of chemical compounds, chromatographic tests were also carried out using the Photovac Voyager portable chromatograph (hydrogen sulphide – H2S and dimethyl sulphide – (CH3)2S. The results of the odour concentration tests are in line with the results of odorant concentration tests and indicate that cod is strongly related to the concentration of hydrogen sulphide. Thanks to this method, it is possible to find a relationship between odour nuisance, technological processes used in the plant and the type of treated waste.
The manuscript presents the condition of circular economy in Poland in diversified approach: subjective (waste streams, energy), sectoral (construction, wastewater treatment, coal energy), related to the resources (phosphorous and anthropogenic minerals) and considering proper energy management (almost zero energy buildings). The achievements reached in different sectors as well as the requirements towards implementation of CE are presented. The advancement of recycling technologies does not deviate from the global level, in terms of areas specific to Poland. Limiting the exploitation of natural resources and usage of new materials as well as producing more durable products are of CE concern. Also energy and heat recovery in buildings and technological processes (e.g. during wastewater treatment), ways of utilization of combustion by-products and water decarbonization waste are described. The implementation of CE in Poland needs not only research and technical activities, but also the modification of technological processes, the right policy, overcoming crosssectoral barriers, developing legal regulations and support schemes for CE.