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Abstract

IIn this short communication, we revise a correlation for the saturated liquid isothermal compressibility based on the data available in DIPPR (Postnikov, 2016) which considers the molecular non-sphericity and addresses a problem of predicting speeds of sound in saturated long-chained alkanes. In addition, we correct a misprint appeared in the cited work and provide programming code used for the realisation of the proposed calculations.

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Authors and Affiliations

Eugene B. Postnikov
Yuriy V. Nedyalkov
Ilya Polishuk
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Abstract

The last study on n-alkanes in surface sediments of Taihu Lake was in 2000, only 13 surface sediment samples were analysed, in order to have a comprehensive and up-to-date understanding of n-alkanes in the surface sediments of Taihu Lake, 41 surface sediment samples were analyzed by GC-MS. C10 to C37 were detected, the total concentrations of n-alkanes ranged from 2109 ng g−1 to 9096 ng g−1 (dry weight). There was strong odd carbon predominance in long chain n-alkanes and even carbon predominance in short chain n-alkanes. When this finding was combined with the analysis results of wax n-alkanes (WaxCn), carbon preference index (CPI), unresolved complex mixture (UCM), hopanes and steranes, it was considered that the long chain n-alkanes were mainly from terrigenous higher plants, and that the short chain n-alkanes mainly originated from bacteria and algae in the lake, compared with previous studies, there were no obvious anthropogenic petrogenic inputs. Terrestrial and aquatic hydrocarbons ratio (TAR) and C21−/C25+ indicated that terrigenous input was higher than aquatic sources and the nearshore n-alkanes were mainly from land-derived sources. Moreover, the distribution of short chain n-alkanes presented a relatively uniform pattern, while the long chain n-alkanes presented a trend that concentrations dropped from nearshore places to the middle of lake.

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Authors and Affiliations

Yunlong Yu
Yuanyuan Li
Zhigang Guo
Hua Zou
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Abstract

Bisnik Cave is an important site of Middle Palaeolithic, with the longest sequence of Neanderthal settlement phases in Central Europe. In the previous studies of the Bisnik sediments, different elements of palaeoenvironment in the periods of Neanderthal occupation have been recognised, except of palaeovegetation, which could not be derived because of lack of preserved plant micro- or macrofossils. The current work is an attempt to reconstruct palaeovegetation in vicinity of the Bisnik Cave, using analysis of composition of plant-derived n-alkanes, preserved in sediments. In our study, we analyzed one sample from each of the sediment's layers 11 - 19c (early Late Pleistocene and late Middle Pleistocene). Abundant n-alkanes (mostly n-C27, n-C29 and n-C31) were found in all the sampled layers except for the layers 12, 16 and 19d, showing no alkanes at all. There is clear diversification of n-alkanes composition and cpr (carbon preference index) values between layers. Analysis of this composition, allows us to claim that the layers 11 and 14 were accumulated when the cave's vicinity was covered by dense coniferous forests, hence upon warm climate. The layers 19, 19a lower, 19b and 19c, presumably originated during cold periods when open woodlands or grasslands dominated. The other analyzed layers could be counected with intermediate vegetation in form of open woodland. However, not all of the achieved results stay in compliance with the actual stratigraphy, established basing on lithological data and palaeoecology offossil fauna, and we hope that explanation of this discrepancy would be possible after more extensive studies of molecular fossils are done.

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Authors and Affiliations

Maciej T. Krajcarz
Marek R. Gola
Krzysztof J. Cyrek
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Abstract

Thermo-optic properties enhancement of the bi-stable temperature threshold sensors based on a partially filled photonic crystal fiber was reported. Previously tested transducers filled with a selected group of pure n-alkanes had in most cases differences between switching ON and OFF states. Therefore, the modification of filling material by using additional crystallization centers in the form of gold nanoparticles was applied to minimize this undesirable effect. The evaluation of the thermodynamic properties of pentadecane and its mixtures with 14 nm spherical Au nanoparticles based on the differential scanning calorimetry measurements was presented. Optical properties analysis of sensors prepared with these mixtures has shown that they are bounded with refractive index changes of the filling material. Particular sensor switches ON before melting process begins and switches OFF before crystallization starts. Admixing next group of n-alkanes with these nanoparticles allows to design six sensors transducers which change ON and OFF states at the same temperature. Thus, the transducers with a wider temperature range for fiber-optic multi-threshold temperature sensor tests will be used.

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Authors and Affiliations

N. Przybysz
P. Marć
E. Tomaszewska
J. Grobelny
L.R. Jaroszewicz
ORCID: ORCID

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