Ch-chalcedony is a green colored member of the quartz group of gem stones. The appearance of Ch-chalcedony is very similar to that of chrysoprase. Differently, Ch-chalsedonies have a chromium element instead of a nickel element as a trace element. Green quartz used in jewelery as a seal stone, in necklaces and rings and has been one of the most valuable quartz varieties throughout history, with its beautiful green color,more rare than other quartz varieties. The Ch-chalcedonies in the North Anatolian region is yellowish-white, brownish gray, light green to dark green in color ranging from several centimeters to one meter thick in veins and lenses in the Lower-Middle Eocene dolomitic limestones. Ch-chalcedonies are composed of fine-grained and occasionally fibrous needle-like quartz; in some examples, quartz is present together with cristobalite, tridimite and cuspidine minerals. According to geochemical investigations in Ch-chalcedonies, the main oxides that were determined are as follows: SiO2 was observed in the range of 95.86–97.81%, Fe2O3 was observed in the range of 0.61–0.91% and Cr2O3 was observed in the range of 0.125–0.168%. A trace element analysis of Ch-chalcedonies, shows their significant enrichments in: Ni, Mo, Cu, Mn, V, Cr and W, especially in the Cr (up to 705 ppm). The green color of the studied Cr-chalcedonies originates from the element chromium. Taking the possible reserves into account, the hardness, color, massive structures, mineralogical, petrographical and gemological features of Ch-chalcedonies in the region are evaluated together. It is determined that they are suitable for the production of jewelry and ornaments.
A high pressure resonator transducer (0 to 100 MPa) devised by the author has been described. The elastic element of the converter consists of a cylinder with an offset arranged axis hole. Quartz resonators were used for the measurement of deformations of the pipe. Based upon the results of the transducer testing, a new algorithmic method for the minimizalizsation of the temperature error, that eliminates the need for a temperature gauge has been worked out.
The analysis of after reclamation dusts generated during the reclamation treatment of test portions of two kinds of polydispersive material in the Regmas device, is presented in the hereby paper. For the comparative purpose the fresh moulding sand marked as quartz sand „Sibelco” –1K 0.40/0.32/0.20, J88, >14000C, WK = 1.20 (acc. PN-83/H-11077), as well as the spent moulding sand, which was previously subjected to the primary reclamation and to dedusting, were used. Conditions of the process treatment were forced by the frequency of supplying the vibratory drive motors being successively 40, 50 and 60Hz for 5, 10 and 15 min. and by causing a diversified material flow through the functional system of the device (charging hopper, abrasive chamber acting as a buffer space). Two states of the process treatment, when a material was flowing through the chamber, were applied. In the first one, an intergranular surface abrasion of grains occurred as a result of the granular material circulation in the chamber forced by the vibratory drive. In the second one, the forced material flow was performed in the presence of crushing elements (steel balls), additionally introduced into the abrasive chamber. Analyses of the device influence were performed by determinations of the amount of dusts separated in the pneumatic classifier and analysis of their grain sizes by means of Analysette 22NanoTec.
Presented study aimed to determine metals distribution on the quartz fiber filters surface coated with particulate matter by using high and low-volume samplers. The distribution pattern was tested using two different sub-sampling schemes. Each sub-sample was mineralized in the nitric acid in a microwave oven. An analysis was performed by means of atomic absorption spectroscopy with electrothermal atomization GF-AAS technique, and the determined elements were: As, Cd, Pb and Ni. A validation of the analytical procedure was carried out using NIES 28 Urban Aerosols standard reference material.
It was assumed that metal is distributed uniformly if its normalized concentrations on a single sub-sample is within ±15% of the mean concentration over the whole filter. The normalized concentrations values exceed this range, indicating a non-homogenous metals distribution. There were no statistically significant differences in metals concentrations between particular sub-samples in the function of its position along the filters diameter.
The main subject of research in this paper is glauconite with its useful parameters, which is the object of exploitation in the “Górka Lubartowska-Niedźwiada” deposit. The main glauconitic horizon (lower Eocene) is built by loamy fine-grained and medium greenish sands with marine fauna and fragments of amber (ca. 7 m thick). Thin lamins and pockets of silts containing phosphorites and also glauconitic sands with underlaying very thin quartz-glauconitic sands are found at the bottom of this layer. The glauconite deposit in “Górka Lubartowska-Niedźwiada” is an amount of ca. 30% by volume of the main glauconitic horizon. Glauconite of the 1M polytype (XRD) shows large granulometric and morphological differentiation (SEM-EDS). It frequently contains aggregations of euhedral or framboidal pyrite grains (RS), which is indicative of the euxinic nature of the formation environment of the rocks under study. The individual glauconite grains show distinct chemical variability, manifested in a lower share of Al2O3 and an increased content of MgO and CaO (EPMA, XRF). At the same time, a large share of K2O (above 8% by weight) allows it to be included in highly matured glauconite, thus it can be considered as a potential raw material for the production of mineral fertilizers. The association of glauconite with phosphates (SEM-EDS) and anatase inclusions in the grains of glauconite (RS) indirectly point to the contribution of the decomposing organic matter to the formation of grains of this mineral. The xylite fragments preserved in the sediment show a low degree of coalification, which is typical of soft lignite. This also shows that the transformation process was taking place under a relatively small overburden.
In this paper we studied the intensification of the water clarification process on contact clarifiers with quartz sand fil-tering bed, which was modified with a solution of aluminum sulphate coagulant. The modification of the quartz sand filter-ing bed was carried out by applying to the surface of grains of quartz sand solution of coagulant aluminum sulphate with different doses. Investigation of the electrokinetic potential of the filtering material (quartz sand) was carried out by the percolation potential method.
The influence of electrical properties (size and sign of the charge) of the filtering bed itself and suspended solids in the water on the filtration process was studied. The filter material – quartz sand used in contact clarifiers has a negative electric charge. When the electric charge of the particles decreases, that is, as the ζ-potential decreases, the repulsive forces de-crease and it the adhesion of particles becomes possible. This is the process of coagulation of the colloid. The forces of mu-tual gravity between the colloidal particles begin to predominate over the electric repulsive forces at the ζ-potential of thesystem less than 0.03 V.
Modification of quarts filtering bed with a solution of coagulant aluminum sulphate recommended for the purification of surface water allows: to intensify the process of water clarification, to reduce the consumption of reagents by 25–30%, with the obtaining purified water of the required quality, to reduce the production areas necessary for reagent management of treatment facilities, and to reduce the cost of water treatment by 20–25%.
Modern techniques of castings production, including moulding sands production, require a strict technological regime and high quality
materials. In the case of self-hardening moulding sands with synthetic binders those requirements apply mainly to sand, which adds to
more than 98% of the whole moulding sand mixture. The factors that affect the quality of the moulding sands are both chemical (SiO2
,
Fe2O3 and carbonates content) and physical. Among these factors somewhat less attention is paid to the granulometric composition of the
sands. As a part of this study, the effect of sand quality on bending strength Rgu
and thermal deformation of self-hardening moulding sands
with furfural and alkyd resin was assessed. Moulding sands with furfural resin are known [1] to be the most susceptible to the sand quality.
A negative effect on its properties has, among others, high content of clay binder and so-called subgrains (fraction smaller than 0,1mm),
which can lead to neutralization of acidic hardeners (in the case of moulding sands with furfuryl resin) and also increase the specific
surface, what forces greater amount of binding agents. The research used 5 different quartz sands originating from different sources and
characterized with different grain composition and different clay binder content.
en
pl
