The presented article describes the method for determining one of the trace elements occurring in coalbismuth. The subjects of the analysis were coal type 34, 35 and their fly ashes derived from Jastrzębska Spółka Węglowa. The main reason for the research was the extensive use of bismuth in many industry sectors. Additionally, bismuth is on the list of deficit elements, therefore the possibility of obtaining an alternative for its recycling source of it is needed, is required. The research was carried out using atomic absorption spectrometry with electrothermal atomization in a graphite cuvette. The samples were incinerated at 800°C and microwave mineralization in a high-pressure closed system was performed until the spectrometric analysis was achieved. In order to achieve mineralization, a mixture of HF and HNO3 acids was used to turn the samples into acidic solutions. The preparation of the samples was based on available literature data and own observations. In the experiment, the effects of the additive modifier was modified by changing the temperature in further steps: drying, incineration, cooling, atomization and burning were described. In addition, the palladium modifier was used in order to limit secondary reactions and enable the evaporation of matrix components. The measurement conditions which are presented in this article allow for a linear calibration curve to be established. However, this is not clear and the definitive method for determining the bismuth in coal is carried out through the use of ET-AAS.
This paper investigates the behaviour of axially-loaded tubular columns filled with M20 grade concrete and partially replaced concrete. The parameters varying in the study are slenderness ratio (13.27, 16.58 & 19.9), and normal M20 grade concrete, partially replaced quarry dust and concrete debris. The effects of the various concrete mixes and composite action between the steel tube and the concrete core are studied and a graph visualizing the differences between the load carrying capacity and the axial deflection is plotted. Some of the performance indices like the Ductility Index (DI), Concrete Contribution Ratio (CCR), Confinement Index (θ) and Strength Index (SI) are also evaluated and compared amongst the CFST columns. From the results it has been noted that an increase in the L/D ratio decrease the behaviour of the composite columns irrespective of the in filled materials. The composite action was achieved in the CFST columns filled with partially replaced quarry dust and concrete debris when compared with hollow steel columns. The load carrying capacity of the CFST column increases by 32 % compared with the hollow tubular columns.
Recycling construction and demolition waste not only reduces project costs; and saves natural resources, but also solves the environmental threat caused by construction waste disposal. In this paper, C25 waste road concrete is used as an experimental material, the uniaxial compression strength and tensile splitting strength of C25 RAC whose coarse aggregate replacement rate is 0%, 25%, 50%, 75%, and 100% are tested under the condition that the water-to-cement ratio is 0.47, 0.55 and 0.61. The results show: (1) the uniaxial compression strength and tensile splitting strength decrease with the increase of RAC; (2) for concrete with the same water-to-cement ratio, when the coarse aggregate replacement rate changes from 0% to 50%, the uniaxial compression strength and tensile splitting strength of RAC changes slightly. When the coarse aggregate replacement rate changes from 50% to 100%, the uniaxial compression strength and tensile splitting strength of RAC decreases rapidly