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Alginate-laccase beads in the decolourization of indigo carmine

Małgorzata Białowąs Beata Kończak Stanisław Chałupnik Joanna Kalka Magdalena Cempa
Archives of Environmental Protection | 2024 | 50 | 1 | DOI: 10.24425/aep.2024.149431
Keywords immobilization; sodium alginate; indigo carmine; decolourization; laccase;
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Abstract

The aim of the study was to assess the feasibility of utilizing sodium alginate biopolymer as animmobilization carrier for laccase in the removal of indigo carmine (IC), an anionic dye. The main goal of this work was to optimize the decolourization process by selecting the appropriate immobilized enzyme dose per 1 mg of dye, as well as the process temperature. The effective immobilization of laccase using sodium alginate as a carrier was confirmed by Raman spectroscopy. An analysis of the size and geometric parameters of the alginate beads was also carried out. Tests of IC decolourization using alginate-laccase beads were conducted. Applying the most effective dose of the enzyme (320 mg of enzyme/1 mg of IC) made it possible to remove 92.5% of the dye over 40 days. The optimal temperature for the IC decolourization process, using laccase immobilized on sodium alginate, was established at 30-40ºC. The obtained results indicate that laccase from Trametes versicolor immobilized on sodium alginate was capable of decolourizing the tested dye primarily based on mechanism of biocatalysis.
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Authors and Affiliations

Małgorzata Białowąs
1
ORCID: ORCID
Beata Kończak
1
Stanisław Chałupnik
1
Joanna Kalka
2
Magdalena Cempa
1
ORCID: ORCID
  1. Central Mining Institute – National Research Institute, Katowice, Poland
  2. Environmental Biotechnology Department, Faculty of Energy and Environmental Engineering,The Silesian University of Technology, Poland

Encapsulation of halloysite with sodium alginate and application in the adsorption of copper from rainwater

Anna Marszałek
Archives of Environmental Protection | 2022 | vol. 48 | No 1 | 75-82 | DOI: 10.24425/aep.2022.140546
Keywords copper adsorption sodium alginate rainwater halloysite
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Abstract

As part of the work, experiments were carried out on a laboratory scale to assess the effectiveness of the use of composite capsules based on halloysite and sodium alginate for the adsorption of copper from rainwater. The halloysite was subjected to acid activation prior to the encapsulation process. The characteristics of the capsules obtained were determined by means of SEM surface imaging, nitrogen adsorption by the BET method and pH PZC measurement by the suspension method. Adsorption was studied using various operational parameters such as adsorbent dose, contact time, pH and concentration of copper ions in the rainwater. A high percentage of copper ions removal was demonstrated, i.e. 72% for halloysite (H), and 83% for activated halloysite (HA) for a dose of 2.0 g/L. Adsorption of Cu (II) was consistent with pseudo-second order kinetics. The adsorbents showed a high adsorption capacity at the level of 11.03 mg/g, determined by the Langmuir isotherm model. This model fit well with the experimental data.
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Authors and Affiliations

Anna Marszałek
1
ORCID: ORCID
  1. Silesian University of Technology, Gliwice, Poland

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