Acoustical attenuation spectra in the frequency range 12 kHz - 2 GHz and nonequilibrium time domain measurements are briefly reviewed for aqueous solutions of various mono- and disaccharides as well as alkyl glycosides. Several relaxation regimes emerge with relaxation times between 10-11 s and 103 s. In this paper relaxation terms reflecting conformational changes are discussed, particularly mutarotation (103 s), chair-chair ring inversion (1 μs), two modes of pseudorotation (100 ns, 10 ns), disaccharide ring isomerisation (10 ns), and exocyclic side group rotation (1 ns).
Number of trace compounds (called biomarkers), which occur in human breath, provide an information about individual feature of the body, as well as on the state of its health. In this paper we present the results of experiments about detection of certain biomarkers using laser absorption spectroscopy methods of high sensitivity. For NO, OCS, C2H6, NH3, CH4, CO and CO(CH3)2 an analysis of the absorption spectra was performed. The influence of interferents contained in exhaled air was considered. Optimal wavelengths of the detection were found and the solutions of the sensors, as well as the obtained results were presented. For majority of the compounds mentioned above the detection limits applicable for medicine were achieved. The experiments showed that the selected optoelectronic techniques can be applied for screening devices providing early diseases detection.
The problem of influence of mechanical vibrations on a measurement is well known and analyzed for ground conditions. However, the problem becomes quite essential and difficult to solve in space conditions. The influence of vibrations on accuracy of the measurement was observed on MIPAS – ENVISAT and in PFS Mars Express.
This paper presents an experimental and theoretical investigation on sensitivity to mechanical disturbances of the Fourier-transform infrared spectrometer PFS.
A theoretical analysis has been performed in order to highlight the expected effect of the vibration, then laboratory tests have been designed and carried out for instrument characterization.
The theoretical investigation has been confirmed by experimental tests.
The data were distorted by errors that reflect the influence of vibrations on the instrument and temperature instability of the reference source.
The considerations are a perfect example presenting the scale of vibrations problem and the instability of the reference source in assessing accuracy of the measurement in space.
Widely-tunable, fully-monolithic, mid-infrared (mid-IR) deference frequency generation source (DFG) is presented. By using a custom designed fiber-pigtailed periodically poled lithium niobate (PPLN) crystal module the idler beam was generated with an efficiency of 21%/W, yielding 2.6 mW of optical output power. The proposed all-fiber configuration radically simplified the optical frequency conversion setup, making it robust and easily configurable. The usefulness of the constructed source was verified by performing simultaneous wavelength modulation spectroscopy (WMS) laser trace gas detection of methane, near 2999 cm−1, and ethane, near 2997 cm−1, via two independently generated, tunable idler beams.
The paper reports the consequences of lanthanum modifications of barium bismuth niobiate (BaBi2Nb2O9) ceramics. The discussed materials were prepared by solid state synthesis and a one-step sintering process. The investigations are focused on dielectric aspects of the modification. The presented results reveal that the trivalent lanthanum ions incorporate twovalent barium ions, which is connected with the creation of A-site cationic vacancies as well as oxygen vacancies. Such a scenario results in significant decreasing in grain boundaries resistivity. The activation energy of grain boundaries conductivity is significantly reduced in the case of lanthanum admixture.
The suitability of low-cost impedance sensors for microbiological purposes and biofilm growth monitoring was evaluated. The sensors with interdigitated electrodes were fabricated in PCB and LTCC technologies. The electrodes were golden (LTCC) or gold-plated (PCB) to provide surface stability. The sensors were used for monitoring growth and degradation of the reference ATCC 15442 Pseudomonas aeruginosa strain biofilm in invitro setting. During the experiment, the impedance spectra of the sensors were measured and analysed using electrical equivalent circuit (EEC) modelling. Additionally, the process of adhesion and growth of bacteria on a sensor’s surface was assessed by means of the optical and SEM microscopy. EEC and SEM microscopic analysis revealed that the gold layer on copper electrodes was not tight, making the PCB sensors susceptible to corrosion while the LTCC sensors had good surface stability. It turned out that the LTCC sensors are suitable for monitoring pseudomonal biofilm and the PCB sensors are good detectors of ongoing stages of biofilm formation.
The paper presents the family of three analyzers allowing to measure impedance in the range of 10 Ω<|Zx|<10 GΩ in a wide frequency range from 10 mHz up to 100 kHz. The most important features of the analyzer family are: miniaturization, low power consumption, low production cost, telemetric controlling and the use of an impedance measurement method based on digital signal processing (DSP). The miniaturization and other above-mentioned features of the analyzers were obtained thanks to the use of the newest generation of large-scale integration chips: e.g. “system on a chip” microsystems (AD5933), 32-bit AVR32-family microcontrollers and specialized modules for wireless communication using the ZigBee standard. When comparing metrological parameters, the developed instrumentation can equal portable analyzers offered by top worldwide manufacturers (Gamry, Ivium) but outperforms them on smaller dimensions, weight, a few times lower price and the possibility to work in a distributed telemetric network. All analyzer versions are able to be put into medium-volume production.
Raman spectrometers are devices which enable fast and non-contact identification of examined chemicals. These devices utilize the Raman phenomenon to identify unknown and often illicit chemicals (e.g. drugs, explosives) without the necessity of their preparation. Now, Raman devices can be portable and therefore can be more widely used to improve security at public places. Unfortunately, Raman spectra measurements is a challenge due to noise and interferences present outside the laboratories. The design of a portable Raman spectrometer developed at the Faculty of Electronics, Telecommunications and Informatics, Gdansk University of Technology is presented. The paper outlines sources of interferences present in Raman spectra measurements and signal processing techniques required to reduce their influence (e.g. background removal, spectra smoothing). Finally, the selected algorithms for automated chemicals classification are presented. The algorithms compare the measured Raman spectra with a reference spectra library to identify the sample. Detection efficiency of these algorithms is discussed and directions of further research are outlined.
This paper adopts a fractional calculus perspective to describe a non-linear electrical inductor. First, the electrical impedance spectroscopy technique is used for measuring the impedance of the device. Second, the experimental data is approximated by means of fractional-order models. The results demonstrate that the proposed approach represents the inductor using a limited number of parameters, while highlighting its most relevant characteristics.
Novel FTIR spectrometer for the monitoring of atmosphere is presented. Its design stands out by a compact form allowing the measures in two IR spectral bands 3-5 and 8-12 μm simultaneously. The spectrometer is composed of two Michelson interferometers with the joint sliding mirror. The paper contains the detailed description of the optics and electronics units, preliminary results of the measurement of biological aerosols and calibration methods.
We report on the absorption properties of polarization-insensitive transmissive and reflective metamaterial absorbers based on two planar aluminium periodic structures and SU-8 epoxy resist. These absorbers were investigated using numerical simulation and experimental methods in the terahertz range (below 2 THz). SU-8 is a very promising organic material for dielectric layers in planar metamaterials, because its application simplifies the process of fabricating these structures and significantly reduces the fabrication time. The experimental absorption of the metamaterial absorbers has narrowband characteristics that were consistent with the numerical simulations. Power flow analysis in the transmissive metamaterial unit cell shows that the absorption in the terahertz range occurs primarily in the SU-8 layer of the absorber.
Specimens of Si single crystals with different crystal orientation [100] and [110] were studied by Electro-Ultrasonic Spectroscopy (EUS) and Resonant Ultrasonic Spectroscopy (RUS). A silicon single crystal is an anisotropic crystal, so its properties are different in different directions in the material relative to the crystal orientation. EUS is based on interaction of two signals: an electric AC signal and an ultrasonic signal, which are working on different frequencies. The ultrasonic wave affects the charge carriers' transport in the structures and the intermodulation electrical signal which is created due to the interaction between the ultrasonic wave and charge carriers, is proportional to the density of structural defects. RUS enables to measure natural frequencies of free elastic vibrations of a simply shaped specimen by scanning a selected frequency range including the appropriate resonances of the measured specimens.
The paper presents magnetic fluid as an excellent material platform for producing more complex magnetic drug delivery systems. In addition, the paper discusses the nanoparticle morphological (electron microscopy) and structural (X-ray diffraction) characterizations. M ossbauer spectroscopy and photoacoustic spectroscopy are revisited as key tools in the characterization of the magnetic core and diamagnetic shell of the magnetic nanoparticle, respectively.
This article presents the results of an examination performed on a set of samples of glass-epoxy core rods used in composite insulators with silicone rubber housings. The goal of the examination was to test the aging resistance of the core material when exposed to Direct Current (DC) high voltage. Long term exposure of a glass-epoxy core rod to DC high voltage may lead to the gradual degradation of its mechanical properties due to the ion migrations. Electrolysis of the core material (glass fiber) may cause electrical breakdown of the insulators and consequently lead to a major failure. After being aged for 6000 hours under DC high voltage, the samples were subjected to microscopic analysis. Their chemical composition was also examined using Raman spectroscopy and their dielectric losses and conductance in the broad range of frequencies were tested using dielectric spectroscopy.
Cast magnesium matrix composites reinforced with silicon carbide particles were investigated by using Raman microscopy. 3C, 4H and 6H polytypes of SiC particles were identified in the investigated composites. Additionally, Mg2Si compound was detected by Raman microscopy in the composites microstructure.
In this study, the corrosion properties of Ti-6Mo-6V-5Cr-3Sn-2.5Zr alloy were investigated as a function of the cold rolling ratio and annealing temperature. The annealing treatment was carried out at temperature of 680°C, 730°C, and 780°C. The highest corrosion potential observed in the specimen with a 10% rolling ratio was 179 mV, which was more positive than that of the non-rolled specimen (–0.214 Vssc). The lowest corrosion current density (1.30×10–8 A/cm2) was observed in the non-rolled specimen which suggested that the integrity of its passive oxide layer was superior to that of the cold-rolled specimens. Time-dependent EIS evaluation revealed that the consistency of the passive oxide layer was highly affected by the subjected rolling ratio over time.