The extracellular polymeric substance (EPS) produced from Rhizobium radiobacter F2, designated as EPSF2, was investigated as a biosorbent for the removal of Pb(II) and Zn(II) from aqueous solution. The optimum biosorption pH values were 5.0 for Pb(II) and 6.0 for Zn(II). Kinetics study revealed that the biosorption followed pseudo-first-order model well, and the equilibrium data fit the Langmuir model better. The adsorbed metal ions could be effectively desorbed by HCl. Desrobed EPSF2 regained 80% of the initial biosorption capacity after five cycles of biosorption-desorption-elution. These results demonstrated that EPSF2 could be a promising alternative for Pb(II) and Zn(II) removal from aqueous solution.
The investigations deal with mass transfer in simulated biomedical systems. The modification of classical diffusion chamber, sequential unit (SU) system, imitated different biomedical setups, boundary conditions. The experiments simulated: diffusion chamber (also with two barriers), transport through the membrane to the blood stream, transport from the stent eluting drug simultaneously to the vessel cells and to the blood stream. The concentrations of substances and the relative mass increases/decreases for SU systems indicate that the order of the curves follows the order of mass transfer resistances. The strong dependence of mass transfer rates versus type of diffusing substance was confirmed. The calculated drug fluxes, diffusion coefficients, permeation coefficients are convergent with literature. Permeation coefficients for complex sequential systems can be estimated as parallel connexion of constituent coefficients. Experiments approved functionality of the SU for investigations in a simulated biomedical system. Obtained data were used for numerical verification.
The main concern of the present paper is to determine which types of linguistic descriptions are fit to properly express a complex reality such as developed in Jaina theory of universals and particulars presented in the Jaina Literature of the Classical Period (5th–10th c. CE) in order to demonstrate a way in which the Jaina theory of universals and particulars has an impact upon the way we describe reality through language. I take into consideration the fact that, according to the Jaina philosophy, reality is not describable in the complete way and that there is always – in any linguistic act of picturing the world – the margin of non-cognizance and non-expressiveness. The Jaina philosophy of language offers the original solutions, different from those given by other Indian thinkers, to the abovementioned problems.
Correctional staff is particularly exposed to occupational stress which in turn can have a negative impact on their job performance. This study attempted to analyse the role of personality, organizational factors, and stress coping strategies in shaping job satisfaction. 163 correctional staff members who were being trained at the Central Training Centre of Correctional Services in Kalisz, Poland, participated in the study. The following tools were used: The Bochum Inventory of Personal Work Features (BIP), the Multiphasic Inventory for Measuring Coping (COPE), and the Satisfaction with Job Scale (SSP).
Staff working directly with inmates scored the lowest in terms of job satisfaction. Social sensibility is a predictor of job satisfaction among each study subgroup and each correctional department and correctional staff as a whole. Correlates of job satisfaction among correctional officers were: Active coping with stressful situations and Seeking social support for emotional and instrumental reasons.
Per- and polyfl uoroalkyl substances (PFASs) are human-invented chemicals that were created in the middle of the 20th century. They were synthesized for the fi rst time in 1949, and because of their exceptional surfactant properties, they have been widely used in many industrial applications and daily life products. The common use of PFASs resulted in their worldwide dissemination in natural environment. PFASs are reported to be ubiquitous in surface and drinking waters, but also may be present in soils, animals, milk and milk-products, plants, food. Contaminated drinking water and food are the most signifi cant exposure sources to these chemicals. Ingested PFASs are bio-accumulative and have adverse eff ect on health of humans as well as animal organisms. This paper reviews the most signifi cant information on the origin, properties, distribution, environmental fate, human exposure, health eff ects, and the environmental regulations on PFASs and summarizes the latest advances in the development of novel methods for the eff ective removal of these chemicals from the aqueous environment. Recognized (reverse osmosis, adsorption on activated carbon) and most promising developing removal methods such as adsorption on biomaterials (plant proteins, chitosan beds), mineral adsorbents (LDHs, hydrotalcite), ionexchange resins, and photocatalytic degradation have been emphasized.
The main goal of the present study was to examine the operating characteristics and mechanisms of membrane fouling in integrated membrane bioreactors (IMBRs) at diff erent temperatures. Two IMBRs, each with identical dimensions and confi gurations, were used in the study using synthetic domestic sewage at a low temperature (10°C) and high temperature (25°C). The results indicated that the removal effi ciency of chemical oxygen demand reached 93–96%, but the membrane contribution rate of IMBR2 (10°C) was higher than that of IMBR1 (25°C). The separation burden of the membrane on organic compounds increased at low temperature, which may have sped up the rate of membrane biofouling. The absolute rate of trans-membrane pressure build-up was faster at low temperature, leading to shorter IMBR operating times. Soluble microbial products (SMPs) and extracellular polymeric substances (EPSs) in the IMBRs signifi cantly increased at low temperature. These substances intensifi ed defl occulation, with an accompanying reduction of fl oc size and the release of EPSs at low temperature, which facilitated the formation of cake foulants on the surface, covering the entire membrane area. The protein and polysaccharide concentrations of SMPs and EPSs in the IMBRs were correlated with the concentration of C8-HSL. It was demonstrated that temperature aff ected the concentration of C8-HSL, which controlled the excretion of EPSs and SMPs and thus the membrane biofouling process.
Construction work on buildings covered by the revitalization program of historic urban development represents a special type of construction project in which, in the execution phase, difficult technical situations and other risk sources are being encountered. An important source of risk is the necessity to preserve a part of the historic substance, which results, among others, from the recommendations of the conservator, legal regulations or from the vision of the architect/investor. The risk is also associated with difficulties and complications in construction works resulting from the location of these objects in dense urban development. The aim of the article is to identify risk factors and reactions of contractors, i.e. applied risk management methods and techniques, based on the example of a complex of buildings constructed in the historic district of Krakow. The elimination of sources of risk, especially of a technical nature, requires the construction management to be highly skilled and experienced, to carefully prepare the construction work and to design additional solutions to ensure safety at work. The experience gained may serve as a basis for risk analysis and identification during the implementation of projects involving the use of an existing building and historic substance in areas subject to revitalization programs.
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