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Abstract

In the case of mining machines, tribocorrosion damage is often observed. This type of consumption is caused by the joint action of mining environment factors such as abrasive and water. The search for methods to counteract tribocorrosion is of great practical importance, but it must be combined with the knowledge of methods of forecasting the value of wear. This paper presents a model of prediction of tribocorrosive wear adapted to corrodible materials – ADI containing Ni and Cu, with the strength class of 800 MPa – and results of a two-stage study on the tribocorrosive wear. Presented results indicate a distinct effect of synergy between friction and corrosion in the total wear of ADI. The tribocorrosion tests confimed the adequacy of the model developed for the ADI.

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Authors and Affiliations

A.N. Wieczorek
A. Stachowiak
W. Zwierzycki
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Abstract

In this paper there are presented some results obtained by open circuit potential and electrochemical impedance spectroscopy measurements from studies performed on the behavior of tribocorrosion on metallic implant biomaterials as: 304L stainless steel, Co/nano-CeO2 nanocomposite layer and Ti6Al4V untreated and oxidized alloy to form a nanoporous TiO2 film. The open circuit potential technique used in measuring the tribocorrosion process provide information on the active or passive behavior of the investigated metallic biomaterial in the biological fluid, before, during friction and after stopping the friction. Thus it clearly show a better behavior of Co/nano-CeO2 nanocomposite coatings as compared with 304L stainless steel to tribocorrosion degradation in Hank solution; as well the better behavior of nanoporous TiO2 film formed annodically on Ti6Al4V alloy surface as compared with untreated alloy to tribocorrosion degradation in artificial saliva Fusayama Meyer. The slight decrease in polarization resistance value resulted from electrochemical impedance spectroscopy measured during friction in the case of the Co/nano-CeO2 nanocomposite layer (four times smaller), compared to 304L stainless steel, whose polarization resistance decreased more than 1000 times during friction shows the higher sensitivity of stainless steel to degradation by tribocorrosion. The same behavior is observed when comparing the polarization resistance of untreated titanium alloy recorded during friction that is about 200 hundred times smaller, while the specific polarization resistance of the oxidized alloy with the nanoporous film of titanium oxide, decreases very little during friction, highlighting the beneficial effect of modifying the titanium alloy by anodic oxidation to increase its resistance to the degradation process by tribocorrosion.
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Authors and Affiliations

L. Benea
1
ORCID: ORCID

  1. Dunarea de Jos University of Galati, Competences Centre: Interfaces-Tribocorrosion and Electrochemical Systems (CC-ITES), 47 Domneasca Street, RO-800008 Galati, Romania

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