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Abstract

Samples of active coke, fresh and spent after cleaning flue gases from communal waste incinerators, were studied. The outer layers of both coke particles were separately removed by comminution mechanism in a spouted bed. Analyses included density, mercury porosimetry and adsorption. The remaining cores were examined to determine the degree of consumption of coke by adsorption of hazardous emissions (SO2, HCl, heavy metals) through its bed. The differences in contamination levels within the porous structure of the particles were estimated. The study demonstrated the effectiveness of active coke in the cleaning of flue gases.

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Authors and Affiliations

Bronisław Buczek
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Abstract

For a very long period of time, Polish waste management was based mainly on landfilling at landfills, which had a negative impact on the surrounding environment. The EU requirements for the Member States have led to a revolution in Polish legislation on waste management and local governments have become responsible for creating local waste management systems that will affect the achievement of EU targets. One of the solutions undertaken by several municipalities is the construction and operation of a municipal waste thermal treatment installation, which not only reduced the amount of waste deposited, but also supported the local power industry by generating electricity and heat. The emission standards for installations producing energy from waste, as in the case of conventional power plants and combined heat and power plants, are very strict, therefore, the continuous monitoring of emitted pollutants is carried out, and waste gas treatment systems are developed based on the best available techniques (BAT). The article presents emission standards applicable to waste incineration plants, including duties in the field of the environment, as well as issues related to the installation as a source of energy. In addition, the currently functioning waste incineration plants in Poland have been briefly characterized, and development plans in this area in the country have been described.

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Jagoda Gołek-Schild
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Abstract

Bioleaching research considers both the bio- and anthroposphere in the search for novel ways to recover resources and elements, which is important to the concept of sustainable development. Since the efficient, cost-effective and simple recovery of resources is of increasing importance in the circular economy model, the bioleaching of metals is a method currently gaining interest. The process is also of importance considering the need for the neutralization of waste materials/resources that allow for their safe storage and use. In this study, Acidithiobacillus thiooxidans bacteria, which is commonly found and widely utilized in the bioleaching process due to its high tolerance to heavy metals, was used in a twenty-eight-day experiment. The manner in which bacteria inhabit incineration residues was observed using fluorescence optical microscopy and scanning electron microscopy. The concentration of elements in incineration residues and in the post-reaction solutions was measured using inductively coupled plasma mass spectrometry and the efficiency of element recovery was calculated based on the results. Municipal waste incineration bottom ash and sewage sludge incineration fly ash were considered in the experiment. The extraction rates were far from satisfactory, with the average 20 and 50% for bottom ash and sewage sludge ash, respectively. The obtained results were consistent with microscopic observations where the relative number of bacteria increased only slightly over time in the sewage-sludge fly ash and was barely observed in the bottom ash of municipal- -waste incineration.
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Authors and Affiliations

Monika Kasina
1
ORCID: ORCID
Kinga Jarosz
1
ORCID: ORCID
Klaudiusz Salamon
1
ORCID: ORCID
Adam Wierzbicki
1
ORCID: ORCID
Bartosz Mikoda
1
ORCID: ORCID
Marek Michalik
1
ORCID: ORCID

  1. Jagiellonian University, Kraków, Poland
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Abstract

Municipal waste is a global issue and they are generated in all countries around the world. Both in the European Union and the United States, a common method of non-recyclable waste utilization is thermal incineration with energy recovery. As a result of this treatment, residual waste like bottom ash, air pollution control residues and fly ashes are generated. This research shows that residues from waste incineration can be a potential source of critical raw materials. The analysis of the available literature prove that the residues of municipal waste incinerators contain most of the elements important for the US and EU economies. Material flow analysis has shown that each year, the content of elemental copper in residues may be 29,000 Mg (USA) and 51,000 Mg (EU), and the amount of rare earth elements in residues exceeds their mining in the EU. In the case of other elements, their content may exceed their extraction by even over 300%. The recovery of elements is difficult due to their encapsulation in the aggregate matrix. The heterogeneous nature of residues and the many interactions between different components and incineration techniques can make the process of recovery complicated. Recovery plants should process as much of the residues as possible to make their recovery profitable. However, policy makers from the EU and the US are introducing new legal regulations to increase the availability of critical raw materials. In the EU, new regulations are planned that will require at least 15% of the annual consumption of critical raw materials to come from recycling. Therefore, innovative technologies for recovering critical raw materials from waste have a chance to receive subsidies for research and development.
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Authors and Affiliations

Radosław Jędrusiak
1
ORCID: ORCID
Barbara Bielowicz
2
ORCID: ORCID
Agnieszka Drobniak
3 4
ORCID: ORCID

  1. Krakowski Holding Komunalny Spółka Akcyjna w Krakowie; AGH University of Kraków, Poland
  2. AGH University of Kraków, Poland
  3. University of Silesia in Katowice, Poland
  4. Indiana University, Indiana Geological and Water Survey; United States

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