@ARTICLE{Śmiarowska_Joanna_Glass-ceramic_2024, author={Śmiarowska, Joanna and Pawlik, Natalia and Pisarska, Joanna and Pisarski, Wojciech A.}, volume={32}, number={4}, journal={Opto-Electronics Review}, pages={e152680}, howpublished={online}, year={2024}, publisher={Polish Academy of Sciences (under the auspices of the Committee on Electronics and Telecommunication) and Association of Polish Electrical Engineers in cooperation with Military University of Technology}, abstract={In this work, the oxyfluoride glass-ceramic materials containing LaF3 nanocrystals, prepared by using the sol-gel method, were described. The influence of fluoride nanocrystals on the photoluminescence properties of selected lanthanide ions was determined. The experimental results obtained for nano-glass-ceramics were compared to the precursor xerogels. Those Ln3+-doped sol-gel materials with dispersed LaF3 nanocrystals exhibit several visible emission bands. It was observed that heat-treatment process caused the elongation of the lifetimes of the 5D0 state from τ = 0.22 ms to τ1 = 0.79 ms, τ2 = 9.76 ms (for Eu3+-doped materials) and of the 4F9/2 state from τ = 0.027 ms to τ1 = 0.034 ms, τ2 = 1.731 ms (for Dy3+‑doped materials). The performed studies clearly revealed that luminescence behaviour also depends on an activator concentration and a distribution of energy levels of lanthanide ions.}, type={Article}, title={Glass-ceramic materials: influence of fluoride nanocrystals on emission properties of lanthanide ions}, URL={http://journals.pan.pl/Content/133073/PDF-MASTER/OPELRE_2024_32_4_J_Smiarowska.pdf}, doi={10.24425/opelre.2024.152680}, keywords={glass-ceramic materials, lanthanide ions, optical properties, visible emission}, }