@ARTICLE{Yi_Eun-Jeong_Stability_2019, author={Yi, Eun-Jeong and Yoon, Keun-Young and Jung, Hyun-Ah and Hwang, Haejin}, volume={vol. 64}, number={No 2}, journal={Archives of Metallurgy and Materials}, pages={579-583}, howpublished={online}, year={2019}, publisher={Institute of Metallurgy and Materials Science of Polish Academy of Sciences}, publisher={Committee of Materials Engineering and Metallurgy of Polish Academy of Sciences}, abstract={Al and Nb-doped Li7La3Zr2O12 (LLZO) and W-doped LLZO lithium ion conducting electrolyte samples were prepared and their H2O stability was investigated. The LLZO samples were exposed to 50% humidified air for 48 h. After H2O exposure, a cubic to tetragonal transformation occurred and acquired SEM images exhibited the presence of reaction phases at the grain boundaries of Al and Nb-LLZO. As a result, the lithium ion conductivity significantly decreased after H2O exposure. On the contrary, W-LLZO showed good stability against H2O. Although the cubic to tetragonal transformation was also observed in H2O-exposed W-LLZO, the decrease in lithium ion conductivity was found to be modest. No morphological changes of the W-LLZO samples were confirmed in the H2O-exposed W-LLZO samples.}, type={Artykuły / Articles}, title={Stability of Garnet-Type LI7LA3ZR2O12-Based Ceramics for All-Solid-State Batteries}, URL={http://journals.pan.pl/Content/111321/PDF/AMM-2019-2-24-Haejin%20Hwang.pdf}, doi={10.24425/amm.2019.127581}, keywords={All-solid-state batteries, solid electrolytes, garnet type ceramics, ionic conductivity}, }