@ARTICLE{Klojzy-Karczmarczyk_Beata_The_2021,
 author={Klojzy-Karczmarczyk, Beata and Mazurek, Janusz},
 volume={vol. 37},
 number={No 2},
 journal={Gospodarka Surowcami Mineralnymi - Mineral Resources Management},
 pages={163-178},
 howpublished={online},
 year={2021},
 publisher={Komitet Zrównoważonej Gospodarki Surowcami Mineralnymi PAN},
 publisher={Instytut Gospodarki Surowcami Mineralnymi i Energią PAN},
 abstract={Sixteen samples were designed for analysis (hard coal, aggregate – barren rock, hard coal sludge). The total mercury content and the amount of mercury leaching were determined. The percentage of leachable form in the total content was calculated. The studies were carried out under various pH medium. The leachability under conditions close to neutral was determined in accordance with the PN EN 12457/1-4 standard. The leachability under acidic medium (pH of the solution – approx. 3) was determined in accordance with principles of the TCLP method. The mercury content was determined by means of the AAS method. For hard coal the total mercury content was 0.0384–0.1049 mg/kg. The level of leaching on mean was 2.6%. At the acidic medium the amount of leaching increases to an mean 4.1%. The extractive waste of aggregate type features a higher total mercury content in the finest fraction < 6 mm (up to 0.4564 mg/kg) and a lower content in the fraction 80–120 mm (up to 0.1006 mg/kg). The aggregate shows the percentage of the leachable form on mean from 1.4 to 2.2%. With pH decreasing to approx. 3, the amount of leaching grows up to mean values of 1.7–3.2%. Coal sludge features the total mercury content of 0.1368–0.2178 mg/kg. The percentage of mercury leachable form is approx. 1.8%. With pH decreasing the value increases to mean value of 3.0%. In general, the leachability of mercury from hard coals and extractive waste is low, and the leachability in an acidic medium grows approx. twice. Such factors as the type and origin of samples, their grain composition, and the pH conditions, have basic importance for the process. The time of waste seasoning and its weathering processes have the greatest impact on increasing the leaching of mercury from the extractive waste.},
 type={Article},
 title={The leaching of mercury from hard coal and extractive waste in the acidic medium},
 URL={http://journals.pan.pl/Content/120059/Klojzy-Karczmarczyk-Mazurek.pdf},
 doi={10.24425/gsm.2021.137567},
 keywords={leaching, hard coal, total content, extractive waste, Mercury},
}