@ARTICLE{Chau_Nguyen_Dinh_Rare_2022, author={Chau, Nguyen Dinh and Pieczonka, Jadwiga and Piestrzyński, Adam and Phon, Le Khanh and Hao, Duong Van}, volume={vol. 38}, number={No 1}, journal={Gospodarka Surowcami Mineralnymi - Mineral Resources Management}, pages={17-60}, howpublished={online}, year={2022}, publisher={Komitet Zrównoważonej Gospodarki Surowcami Mineralnymi PAN}, publisher={Instytut Gospodarki Surowcami Mineralnymi i Energią PAN}, abstract={The Sin Quyen deposit is characterized by a high accumulation of rare earth elements (REE). This deposit belongs to the IOCG type copper deposits (Iron Oxide Copper-Gold Deposits). In the deposit, the REE carrier minerals have been identified as follow: allanite, titanite, uraninite, monazite, apatite, chevkinite, aeschynite, bastnäsite, and epidote. In the skarn zone, contents of allanite range from single percentages to 10% in hand-size specimens. Locally, minerals of epidote subgroup which occur in large amounts in the host rocks are important. The studied allanites have concentrations of: REE (14–27 wt%), Ca (9–16 wt%), Al (8–19 wt%), Si (26–34 wt%) and Fe (12–21 wt%). Two populations of allanite are documented, the first is texturally older and probably related to the Ca-K alteration (second stage of crystallization). This population has higher REE concentration ranging from 20 to 27 wt%. The second population is texturally younger and has a lower total REE concentration ranging from 14 to 19.9 wt%, which occur mostly as a rim surrounding the older and likely arose during the K alteration with Cu-Au mineralization (third crystallization). The chemical composition indicates that the studied allanites belong to the Ce-La-ferriallanite family, with low ΣHREE and an average of 0.21 wt.%. A temperature of 355°C which was calculated using a value of δ34S isotopes is interpreted as a temperature of the second crystallization stage of allanite. In the studied deposit, excluding allanite and titanite, the other bearing REE minerals have an insignificant role in the REE balance, since they either have the total content of REE, which is often close to the WDS detection limit (rf. the epidote subgroup), or their only occur at the single points. The content of total REE in accessory uraninites is high and range from 1.311% up to 7.959% with an average value of 4.852%.}, type={Article}, title={Rare earth elements in the Sin Quyen IOCG deposit, North Vietnam}, URL={http://journals.pan.pl/Content/122691/PDF/Chau%20i%20inni.pdf}, doi={10.24425/gsm.2022.140611}, keywords={REE, allanite, ore minerals, IOCG deposit, N-Vietnam}, }